scholarly journals Time‐Dependent Differential and Integral Quantum Yields for Wavelength‐Dependent [4+4] Photocycloadditions

2019 ◽  
Vol 26 (2) ◽  
pp. 478-484 ◽  
Author(s):  
Anastasia Kislyak ◽  
Hendrik Frisch ◽  
Marvin Gernhardt ◽  
Paul H. M. Van Steenberge ◽  
Dagmar R. D'hooge ◽  
...  
Keyword(s):  
Time Dependent ◽  
Quantum Yields ◽  
Integral Quantum

scholarly journals New yellow/orange-emitting heteroleptic iridium(III) complexes with 5,7-difluoro-2-phenylbenzothiazole ligand

2019 ◽  
Vol 44 (1-2) ◽  
pp. 67-71
Author(s):  
De-Kun Jing ◽  
Han-Ru Xu ◽  
Xiao-Han Yang ◽  
Rui-Lian Yang ◽  
Zhuo Liu ◽  
...  
Keyword(s):  
Density Functional Theory ◽  
Density Functional ◽  
Room Temperature ◽  
Time Dependent ◽  
Quantum Yields ◽  
Functional Theory ◽  
Ligand Charge Transfer ◽  
Yellow Orange ◽  
Absolute Quantum ◽  
Dependent Density

Two new phosphorescent iridium(III) complexes, (dfbt)2Ir(pic) and (dfbt)2Ir(acac) (dfbt = 5,7-difluoro-2-phenylbenzothiazole, pic = picolinate, acac = acetylacetonate), have been synthesized and characterized. Upon photoexcitation, both complexes exhibit strong yellow–orange emission in CH2Cl2 solution at room temperature with absolute quantum yields up to 99.0% and emission lifetimes up to 1.23 μs. The spectroscopic property has been calculated by density functional theory and time-dependent density functional theory, thus suggesting that the lowest absorption and the emission originate from the metal-to-ligand charge transfer/ligand-centered transition.

TIME-DEPENDENT PHENOMENA CAUSED BY THE EC DECAY IN Co2+ [Fe(CN)6]3-

1980 ◽  
Vol 41 (C1) ◽  
pp. C1-239-C1-240 ◽  
Author(s):  
Takayuki Kobayashi ◽  
Tetsuo Kitahara
Keyword(s):  
Time Dependent
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