scholarly journals Molecular Tectonics: A Node‐and‐Linker Building Block Approach to a Family of Hydrogen‐Bonded Frameworks

2019 ◽  
Vol 25 (42) ◽  
pp. 10006-10012 ◽  
Author(s):  
Stephanie A. Boer ◽  
Mahbod Morshedi ◽  
Andrew Tarzia ◽  
Christian J. Doonan ◽  
Nicholas G. White
Keyword(s):  
Building Block ◽  
Molecular Tectonics ◽  
Block Approach ◽  
Hydrogen Bonded

scholarly journals Molecular Tectonics: A Node-and-Linker Building Block Approach to a Family of Hydrogen Bonded Frameworks

2019 ◽  
Author(s):  
Stephanie Boer ◽  
Mahbod Morshedi ◽  
Andrew Tarzia ◽  
Christian Doonan ◽  
Nicholas White
Keyword(s):  
Hydrogen Bonding ◽  
Building Block ◽  
Aqueous Media ◽  
Good Stability ◽  
Prolonged Heating ◽  
Molecular Tectonics ◽  
Block Approach ◽  
Hydrogen Bonded

While numerous hydrogen bonded organic frameworks (HOFs) have been reported, typically these cannot be prepared predictably or in a modular fashion. In this work, we report a family of nine diamondoid crystalline porous frameworks assembled via hydrogen bonding between poly-amidinium and poly-carboxylate tectons in aqueous media. Importantly, both the cationic and anionic components can be varied and additional functionality can be incorporated into the frameworks, which show good stability including to prolonged heating in DMSO or water.

scholarly journals Molecular Tectonics: A Node-and-Linker Building Block Approach to a Family of Hydrogen Bonded Frameworks

2019 ◽  
Author(s):  
Stephanie Boer ◽  
Mahbod Morshedi ◽  
Andrew Tarzia ◽  
Christian Doonan ◽  
Nicholas White
Keyword(s):  
Hydrogen Bonding ◽  
Building Block ◽  
Aqueous Media ◽  
Good Stability ◽  
Prolonged Heating ◽  
Molecular Tectonics ◽  
Block Approach ◽  
Hydrogen Bonded

While numerous hydrogen bonded organic frameworks (HOFs) have been reported, typically these cannot be prepared predictably or in a modular fashion. In this work, we report a family of nine diamondoid crystalline porous frameworks assembled via hydrogen bonding between poly-amidinium and poly-carboxylate tectons in aqueous media. Importantly, both the cationic and anionic components can be varied and additional functionality can be incorporated into the frameworks, which show good stability including to prolonged heating in DMSO or water.

scholarly journals Clustering of Protein Structural Fragments Reveals Modular Building Block Approach of Nature

2004 ◽  
Vol 338 (3) ◽  
pp. 611-629 ◽  
Author(s):  
Ashish V. Tendulkar ◽  
Anand A. Joshi ◽  
Milind A. Sohoni ◽  
Pramod P. Wangikar
Keyword(s):  
Building Block ◽  
Block Approach

Molecular Tectonics. Disruption of Self-Association in Melts Derived from Hydrogen-Bonded Solids

2004 ◽  
Vol 37 (19) ◽  
pp. 7351-7357 ◽  
Author(s):  
Danielle Boils ◽  
Marie-Ève Perron ◽  
Francis Monchamp ◽  
Hugues Duval ◽  
Thierry Maris ◽  
...  
Keyword(s):  
Molecular Tectonics ◽  
Self Association ◽  
Hydrogen Bonded

A ‘Building Block’ Approach To Mixed-Colloid Systems Through Electrostatic Self-Organization

2001 ◽  
Vol 676 ◽  
Author(s):  
Trent H. Galow ◽  
Andrew K. Boal ◽  
Vincent M. Rotello
Keyword(s):  
Particle Size ◽  
Self Assembly ◽  
Building Block ◽  
Acid Base ◽  
Electrostatic Assembly ◽  
Polymer Colloid ◽  
Colloid Systems ◽  
Carboxylic Acid Derivative ◽  
Block Approach ◽  
Shape And Size

ABSTRACTWe have developed a highly modular electrostatically-mediated approach to colloid-colloid and polymer-colloid networks using ‘building block’ and ‘bricks and mortar’ self-assembly methodologies, respectively. The former approach involved functionalization of one type of nanoparticle building block with a primary amine and a counterpart building block with a carboxylic acid derivative. After combining these two systems, acid-base chemistry followed by immediate charge-pairing resulted in the spontaneous formation of electrostatically-bound mixed-nanoparticle constructs. The shape and size of these ensembles were controlled via variation of particle size and stoichiometries. In the ‘bricks and mortar’ approach, a functionalized polymer is combined with complementary nanoparticles to provide mixed polymer-nanoparticle networked structures. A notable feature is the inherent porosity resulting from the electrostatic assembly. The shape and size of these ensembles were controlled via variation of particle size, stoichiometries and the order in which they were added.

The Oxamate Anion:  A Flexible Building Block of Hydrogen-Bonded Architectures for Crystal Engineering

1996 ◽  
Vol 118 (42) ◽  
pp. 10134-10140 ◽  
Author(s):  
Christer B. Aakeröy ◽  
Deirdre P. Hughes ◽  
Mark Nieuwenhuyzen
Keyword(s):  
Crystal Engineering ◽  
Building Block ◽  
Hydrogen Bonded

ChemInform Abstract: Synthesis of Thiapyranoside Precursors Using the Building-Block Approach from a Phosphonodifluorodithioacetate.

ChemInform ◽  
2010 ◽  
Vol 33 (26) ◽  
pp. no-no
Author(s):  
Emmanuel Pfund ◽  
Thierry Lequeux ◽  
Michel Vazeux ◽  
Serge Masson
Keyword(s):  
Building Block ◽  
Block Approach

A Building Block Approach to Monofluorinated Organic Compounds

2008 ◽  
Vol 73 (12) ◽  
pp. 1553-1611 ◽  
Author(s):  
Alexander S. Konev ◽  
Alexander F. Khlebnikov
Keyword(s):  
Organic Compounds ◽  
Building Block ◽  
Building Blocks ◽  
Natural Compounds ◽  
Pericyclic Reactions ◽  
Fluoroacetic Acid ◽  
Phosphorus Containing ◽  
Block Approach

Building blocks for the synthesis of monofluorinated organic compounds are reviewed. The synthetic potential of polyhalomethanes, sulfur- and phosphorus-containing building blocks, difluoroethene, polyhaloethanes, fluoroacetic acid derivatives, and other compounds are described. Pericyclic reactions involving fluorinated compounds and application of the methodology of building blocks to the synthesis of monofluorinated pharmaceuticals and analogs of natural compounds are considered. The review with 317 references covers mainly the literature from 1996 through 2007.

A one building block approach for defect-enhanced conjugated microporous polymers: defect utilization for recyclable and catalytic biomass conversion

2018 ◽  
Vol 6 (32) ◽  
pp. 15553-15557 ◽  
Author(s):  
Kyoungil Cho ◽  
Sang Moon Lee ◽  
Hae Jin Kim ◽  
Yoon-Joo Ko ◽  
Seung Uk Son
Keyword(s):  
Building Block ◽  
Solid Acid ◽  
Biomass Conversion ◽  
Solid Acid Catalysts ◽  
Acid Catalysts ◽  
Microporous Polymers ◽  
Block Approach ◽  
Conjugated Microporous Polymers

A one building block approach for conjugated microporous polymers resulted in enhanced defects which were utilized for the development of solid acid catalysts.

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