scholarly journals Fully sp 2 ‐Carbon‐Linked Crystalline Two‐Dimensional Conjugated Polymers: Insight into 2D Poly(phenylenecyanovinylene) Formation and its Optoelectronic Properties

2019 ◽  
Vol 25 (26) ◽  
pp. 6562-6568 ◽  
Author(s):  
Daniel Becker ◽  
Bishnu P. Biswal ◽  
Paula Kaleńczuk ◽  
Naisa Chandrasekhar ◽  
Lars Giebeler ◽  
...  
Keyword(s):  
Conjugated Polymers ◽  
Optoelectronic Properties ◽  
Two Dimensional ◽  
Insight Into

Optoelectronic Properties and Structural Modification of Conjugated Polymers Based on Benzodithiophene Groups

2019 ◽  
Vol 16 (3) ◽  
pp. 253-260 ◽  
Author(s):  
Jieyun Wu ◽  
Qing Li ◽  
Wen Wang ◽  
Kaixin Chen
Keyword(s):  
Conjugated Polymers ◽  
Molecular Design ◽  
Field Effect Transistors ◽  
Polymer Solar Cells ◽  
Optoelectronic Devices ◽  
Optoelectronic Properties ◽  
Two Dimensional ◽  
Structure Property ◽  
Conjugated Materials ◽  
Organic Optoelectronic

Organic conjugated materials have shown attractive applications due to their good optoelectronic properties, which enable them solution processing techniques in organic optoelectronic devices. Many conjugated materials have been investigated in polymer solar cells and organic field-effect transistors. Among those conjugated materials, Benzo[1,2-b:4,5-b′]dithiophene (BDT) is one of the most employed fused-ring building groups for the synthesis of conjugated materials. The symmetric and planar conjugated structure, tight and regular stacking of BDT can be expected to exhibit the excellent carrier transfer for optoelectronics. In this review, we summarize the recent progress of BDT-based conjugated polymers in optoelectronic devices. BDT-based conjugated materials are classified into onedimensional (1D) and two-dimensional (2D) BDT-based conjugated polymers. Firstly, we introduce the fundamental information of BDT-based conjugated materials and their application in optoelectronic devices. Secondly, the design and synthesis of alkyl, alkoxy and aryl-substituted BDT-based conjugated polymers are discussed, which enables the construction of one-dimensional and two-dimensional BDTbased conjugated system. In the third part, the structure modification, energy level tuning and morphology control and their influences on optoelectronic properties are discussed in detail to reveal the structure- property relationship. Overall, we hope this review can be a good reference for the molecular design of BDT-based semiconductor materials in optoelectronic devices.

Controllable Growth of Centimeter-Scale 2D Crystalline Conjugated Polymers for Photonic Synaptic Transistors

2021 ◽  
Author(s):  
Qing Zhang ◽  
Xin Ye ◽  
Yue Zheng ◽  
Yongshuai Wang ◽  
Lin Li ◽  
...  
Keyword(s):  
Conjugated Polymers ◽  
Optoelectronic Properties ◽  
Two Dimensional ◽  
Neuromorphic Computing ◽  
Controllable Growth ◽  
2D Crystals

Two-dimensional (2D) crystals of conjugated polymers (2DCCPs) have attracted numerous attentions in past few decades due to their superior and intriguing optoelectronic properties. With the rise of brain-inspired neuromorphic computing,...

scholarly journals Design of a Novel Miniaturized Frequency Selective Surface Based on 2.5-Dimensional Jerusalem Cross for 5G Applications

2018 ◽  
Vol 2018 ◽  
pp. 1-6 ◽  
Author(s):  
Peng Zhao ◽  
Yihang Zhang ◽  
Rongrong Sun ◽  
Wen-Sheng Zhao ◽  
Yue Hu ◽  
...  
Keyword(s):  
Resonant Frequency ◽  
Equivalent Circuit ◽  
Equivalent Circuit Model ◽  
Frequency Selective Surface ◽  
Size Reduction ◽  
Two Dimensional ◽  
Physical Insight ◽  
Frequency Selective ◽  
Significant Size ◽  
Insight Into

A compact frequency selective surface (FSS) for 5G applications has been designed based on 2.5-dimensional Jerusalem cross. The proposed element consists of two main parts: the successive segments of the metal traces placed alternately on the two surfaces of the substrate and the vertical vias connecting traces. Compared with previous published two-dimensional miniaturized elements, the transmission curves indicate a significant size reduction (1/26 wavelengths at the resonant frequency) and exhibit good angular and polarization stabilities. Furthermore, a general equivalent circuit model is established to provide direct physical insight into the operating principle of this FSS. A prototype of the proposed FSS has been fabricated and measured, and the results validate this design.

scholarly journals Architectures and Applications of BODIPY-Based Conjugated Polymers

Polymers ◽  
2020 ◽  
Vol 13 (1) ◽  
pp. 75
Author(s):  
Yiqi Fan ◽  
Jinjin Zhang ◽  
Zhouyi Hong ◽  
Huayu Qiu ◽  
Yang Li ◽  
...  
Keyword(s):  
Conjugated Polymers ◽  
Chemical Doping ◽  
Structure Property ◽  
High Quantum Yield ◽  
Conjugated Materials ◽  
Energy Band Gap ◽  
Photoelectric Properties ◽  
Structure Property Relationship ◽  
Insight Into ◽  
High Absorption

Conjugated polymers generally contain conjugated backbone structures with benzene, heterocycle, double bond, or triple bond, so that they have properties similar to semiconductors and even conductors. Their energy band gap is very small and can be adjusted via chemical doping, allowing for excellent photoelectric properties. To obtain prominent conjugated materials, numerous well-designed polymer backbones have been reported, such as polyphenylenevinylene, polyphenylene acetylene, polycarbazole, and polyfluorene. 4,4′-Difluoro-4-bora-3a,4a-diaza-s-indacene (BODIPY)-based conjugated polymers have also been prepared owing to its conjugated structure and intriguing optical properties, including high absorption coefficients, excellent thermal/photochemical stability, and high quantum yield. Most importantly, the properties of BODIPYs can be easily tuned by chemical modification on the dipyrromethene core, which endows the conjugated polymers with multiple functionalities. In this paper, BODIPY-based conjugated polymers are reviewed, focusing on their structures and applications. The forms of BODIPY-based conjugated polymers include linear, coiled, and porous structures, and their structure–property relationship is explored. Also, typical applications in optoelectronic materials, sensors, gas/energy storage, biotherapy, and bioimaging are presented and discussed in detail. Finally, the review provides an insight into the challenges in the development of BODIPY-based conjugated polymers.

scholarly journals Indirect bandgap, optoelectronic properties, and photoelectrochemical characteristics of high-purity Ta3N5 photoelectrodes

2021 ◽  
Vol 9 (36) ◽  
pp. 20653-20663
Author(s):  
Johanna Eichhorn ◽  
Simon P. Lechner ◽  
Chang-Ming Jiang ◽  
Giulia Folchi Heunecke ◽  
Frans Munnik ◽  
...  
Keyword(s):  
Electronic Structure ◽  
Electronic Properties ◽  
High Purity ◽  
Optoelectronic Properties ◽  
Precise Control ◽  
Insight Into

The (opto)electronic properties of Ta3N5 photoelectrodes are often dominated by defects, but precise control of these defects provides new insight into the electronic structure, photocarrier transport, and photoelectrochemical function.

scholarly journals Dynamics with Cattaneo–Christov heat and mass flux theory of bioconvection Oldroyd-B nanofluid

2020 ◽  
Vol 12 (8) ◽  
pp. 168781402093046 ◽  
Author(s):  
Noor Saeed Khan ◽  
Qayyum Shah ◽  
Arif Sohail
Keyword(s):  
Mass Transfer ◽  
Porous Media ◽  
Differential Equations ◽  
Mass Flux ◽  
Homotopy Analysis Method ◽  
Two Dimensional ◽  
Analysis Method ◽  
Homotopy Analysis ◽  
Transfer Flow ◽  
Insight Into

Entropy generation in bioconvection two-dimensional steady incompressible non-Newtonian Oldroyd-B nanofluid with Cattaneo–Christov heat and mass flux theory is investigated. The Darcy–Forchheimer law is used to study heat and mass transfer flow and microorganisms motion in porous media. Using appropriate similarity variables, the partial differential equations are transformed into ordinary differential equations which are then solved by homotopy analysis method. For an insight into the problem, the effects of various parameters on different profiles are shown in different graphs.

Exact analysis of the bending of wide beams by a modified elastica approach

2011 ◽  
Vol 225 (11) ◽  
pp. 2759-2764 ◽  
Author(s):  
L F Campanile ◽  
R Jähne ◽  
A Hasse
Keyword(s):  
Finite Element ◽  
Substantial Reduction ◽  
Short Review ◽  
Computational Effort ◽  
Two Dimensional ◽  
Finite Element Calculations ◽  
Dimensional Finite Element ◽  
Wide Beams ◽  
Insight Into ◽  
Selection Of

Classical beam models do not account for partial restraint of anticlastic bending and are therefore inherently inaccurate. This article proposes a modification of the exact Bernoulli–Euler equation which allows for an exact prediction of the beam's deflection without the need of two-dimensional finite element calculations. This approach offers a substantial reduction in the computational effort, especially when coupled with a fast-solving schema like the circle-arc method. Besides the description of the new method and its validation, this article offers an insight into the somewhat disregarded topic of anticlastic bending by a short review of the published theories and a selection of representative numerical results.

First-principles investigation on the thickness-dependent optoelectronic properties of two-dimensional perovskite BA2SnI4

2021 ◽  
pp. 413070
Author(s):  
Meiping Liu ◽  
Yong Tang ◽  
Xiangli Zhong ◽  
Zheng Li ◽  
Yingtang Zhou ◽  
...  
Keyword(s):  
First Principles ◽  
Optoelectronic Properties ◽  
Two Dimensional
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