Tuning of High Spin Ground State and Slow Magnetic Relaxation within Trimetallic Cyanide‐Bridged {Ni II x Co II 9− x [W V (CN) 8 ] 6 } and {Mn II x Co II 9− x [W V (CN) 8 ] 6 } Clusters

2018 ◽  
Vol 24 (58) ◽  
pp. 15533-15542 ◽  
Author(s):  
Szymon Chorazy ◽  
Anna M. Majcher ◽  
Marcin Kozieł ◽  
Jedrzej Kobylarczyk ◽  
Shin‐ichi Ohkoshi ◽  
...  
Keyword(s):  
High Spin ◽  
Ground State ◽  
Magnetic Relaxation ◽  
Slow Magnetic Relaxation ◽  
Spin Ground State

Field-induced slow magnetic relaxation in an octahedral high-spin Co(II) complex

2019 ◽  
Vol 99 ◽  
pp. 195-198
Author(s):  
Peipei Cen ◽  
Weize Yuan ◽  
Mengyao Tan ◽  
Bingbing Chen ◽  
Weiming Song ◽  
...  
Keyword(s):  
High Spin ◽  
Magnetic Relaxation ◽  
Slow Magnetic Relaxation

scholarly journals Ferrotoroidic ground state in a heterometallic {CrIIIDyIII 6} complex displaying slow magnetic relaxation

2017 ◽  
Vol 8 (1) ◽  
Author(s):  
Kuduva R. Vignesh ◽  
Alessandro Soncini ◽  
Stuart K. Langley ◽  
Wolfgang Wernsdorfer ◽  
Keith S. Murray ◽  
...  
Keyword(s):  
Ground State ◽  
Magnetic Relaxation ◽  
Slow Magnetic Relaxation

Slow magnetic relaxation in structurally similar mononuclear 8-coordinate Fe(ii) and Fe(iii) compounds

2021 ◽  
Author(s):  
Qian-Qian Su ◽  
Qiong Yuan ◽  
Xiao-Fan Wu ◽  
Si-Huai Chen ◽  
Jing Xiang ◽  
...  
Keyword(s):  
High Spin ◽  
Magnetic Relaxation ◽  
Relaxation Behaviour ◽  
Slow Magnetic Relaxation

A pair of structurally-similar and stable 8-coordinate high-spin Fe(ii) and Fe(iii) compounds have been obtained. Both compounds exhibit field-induced slow magnetic relaxation behaviour.

Giant Heterometallic Cu17Mn28Cluster withTdSymmetry and High-Spin Ground State

2007 ◽  
Vol 129 (5) ◽  
pp. 1014-1015 ◽  
Author(s):  
Wen-Guo Wang ◽  
Ai-Ju Zhou ◽  
Wei-Xiong Zhang ◽  
Ming-Liang Tong ◽  
Xiao-Ming Chen ◽  
...  
Keyword(s):  
High Spin ◽  
Ground State ◽  
Spin Ground State

A molecular ferromagnet with Tc = 3.3 K and an high spin ground state in trinuclear oxo-centred mixed-valence carboxylates

Polyhedron ◽  
1996 ◽  
Vol 15 (5-6) ◽  
pp. 1041-1044 ◽  
Author(s):  
Zhang Shi-Wei ◽  
Wei Yong-Ge ◽  
Liu Qun ◽  
Shao Mei-Cheng ◽  
Zhou Wen-Sheng
Keyword(s):  
High Spin ◽  
Ground State ◽  
Mixed Valence ◽  
Spin Ground State

Redox‐Induced Modulation of Exchange Interaction in a High‐Spin Ground‐State Diradical/Triradical System

2020 ◽  
Vol 26 (14) ◽  
pp. 3166-3172 ◽  
Author(s):  
Atsuki Nagata ◽  
Shinsuke Hiraoka ◽  
Shuichi Suzuki ◽  
Masatoshi Kozaki ◽  
Daisuke Shiomi ◽  
...  
Keyword(s):  
Exchange Interaction ◽  
High Spin ◽  
Ground State ◽  
Spin Ground State

scholarly journals Correction: New tetranuclear manganese clusters with [MnII3MnIII] and [MnII2MnIII2] metallic cores exhibiting low and high spin ground state

2017 ◽  
Vol 46 (12) ◽  
pp. 4118-4118
Author(s):  
M. Sobocińska ◽  
M. Antkowiak ◽  
M. Wojciechowski ◽  
G. Kamieniarz ◽  
J. Utko ◽  
...  
Keyword(s):  
High Spin ◽  
Ground State ◽  
Dalton Trans ◽  
Manganese Clusters ◽  
Spin Ground State

Correction for ‘New tetranuclear manganese clusters with [MnII3MnIII] and [MnII2MnIII2] metallic cores exhibiting low and high spin ground state’ by M. Sobocińska et al., Dalton Trans., 2016, 45, 7303–7311.

Enforcement of a high-spin ground state for the first 3d heterometallic 12-metallacrown-4 complex

2014 ◽  
Vol 43 (41) ◽  
pp. 15308-15312 ◽  
Author(s):  
Peter Happ ◽  
Eva Rentschler
Keyword(s):  
Transition Metal ◽  
High Spin ◽  
Ground State ◽  
Spin Ground State

Applying a novel magnetic director approach, we have realized Cu(ii)(DMF)2Cl2[12-MCFe(III)N(Shi)-4](DMF)4·2DMF as the first heterometallic transition metal 12-MC-4 complex in order to provide this type of compound with a high-spin ground state.

Slow magnetic relaxation in Cu(ii)–Eu(iii) and Cu(ii)–La(iii) complexes

2019 ◽  
Vol 43 (32) ◽  
pp. 12698-12701 ◽  
Author(s):  
Malay Dolai ◽  
Mahammad Ali ◽  
Cyril Rajnák ◽  
Ján Titiš ◽  
Roman Boča
Keyword(s):  
Magnetic Field ◽  
External Magnetic Field ◽  
Low Temperature ◽  
Ground State ◽  
Magnetic Relaxation ◽  
Slow Magnetic Relaxation ◽  
Paramagnetic Behaviour

A dinuclear [(H2O)Cu(HLN2O2)Eu(NO3)3] complex exhibits paramagnetic behaviour with S = 1/2 ground state. At low temperature it displays slow magnetic relaxation that is supported by a small external magnetic field.

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