A Highly Stable Two-Dimensional Copper(II) Organic Framework for Proton Conduction and Ammonia Impedance Sensing

2018 ◽  
Vol 24 (42) ◽  
pp. 10829-10839 ◽  
Author(s):  
Zhibing Sun ◽  
Shihang Yu ◽  
Lili Zhao ◽  
Jifeng Wang ◽  
Zifeng Li ◽  
...  
Keyword(s):  
Proton Conduction ◽  
Two Dimensional ◽  
Impedance Sensing ◽  
Organic Framework

Intrinsic proton conduction in 2D sulfonated covalent organic framework through the post-synthetic strategy

CrystEngComm ◽  
2021 ◽  
Author(s):  
Yuwei Zhang ◽  
Chunzhi Li ◽  
Zhaohan Liu ◽  
Yuze Yao ◽  
Md. Mahmudul Hasan ◽  
...  
Keyword(s):  
Proton Conduction ◽  
Two Dimensional ◽  
Covalent Organic Frameworks ◽  
Covalent Organic Framework ◽  
Synthetic Strategy ◽  
Organic Framework

Two-dimensional covalent organic frameworks (2D COFs) have attracted much attentions in proton conduction, owing to their regular pore channels and easy functionalization. However, most of COFs required the loading of...

Proton conduction and impedance sensing of a highly stable copper–organic framework from imidazole dicarboxylate

Polyhedron ◽  
2019 ◽  
Vol 158 ◽  
pp. 377-385 ◽  
Author(s):  
Wanyao Chen ◽  
Chenglin Yang ◽  
Shihang Yu ◽  
Zifeng Li ◽  
Gang Li
Keyword(s):  
Proton Conduction ◽  
Impedance Sensing ◽  
Imidazole Dicarboxylate ◽  
Organic Framework

Synthesis and Structure of a Clathrated Two-Dimensional Metal-Organic Framework: [Cd(4,4'-bpy)2(H2O)2](ClO4)2·(L)2·H2O (L = Bis(1-pyrazinylethylidene)hydrazine)

2008 ◽  
Vol 73 (1) ◽  
pp. 24-31
Author(s):  
Dayu Wu ◽  
Genhua Wu ◽  
Wei Huang ◽  
Zhuqing Wang
Keyword(s):  
Metal Organic Framework ◽  
Channel Structure ◽  
Two Dimensional ◽  
X Ray Diffraction ◽  
Guest Molecules ◽  
X Ray ◽  
Square Planar ◽  
Metal Organic ◽  
Aqueous Meoh ◽  
Organic Framework

The compound [Cd(4,4'-bpy)2(H2O)2](ClO4)2·(L)2 was obtained by the reaction of Cd(ClO4)2, bis(1-pyrazinylethylidene)hydrazine (L) and 4,4'-bipyridine in aqueous MeOH. Single-crystal X-ray diffraction has revealed its two-dimensional metal-organic framework. The 2-D layers superpose on each other, giving a channel structure. The square planar grids consist of two pairs of shared edges with Cd(II) ion and a 4,4'-bipyridine molecule each vertex and side, respectively. The square cavity has a dimension of 11.817 × 11.781 Å. Two guest molecules of bis(1-pyrazinylethylidene)hydrazine are clathrated in every hydrophobic host cavity, being further stabilized by π-π stacking and hydrogen bonding. The results suggest that the hydrazine molecules present in the network serve as structure-directing templates in the formation of crystal structures.

Two-Dimensional Metal–Organic Framework Nanosheets as an Enzyme Inhibitor: Modulation of the α-Chymotrypsin Activity

2017 ◽  
Vol 139 (24) ◽  
pp. 8312-8319 ◽  
Author(s):  
Ming Xu ◽  
Shuai Yuan ◽  
Xin-Yu Chen ◽  
Yu-Jie Chang ◽  
Gregory Day ◽  
...  
Keyword(s):  
Enzyme Inhibitor ◽  
Metal Organic Framework ◽  
Two Dimensional ◽  
Chymotrypsin Activity ◽  
Metal Organic ◽  
Organic Framework

scholarly journals Theoretical hydrogen bonding calculations and proton conduction for Eu(iii)-based metal–organic framework

RSC Advances ◽  
2021 ◽  
Vol 11 (19) ◽  
pp. 11495-11499
Author(s):  
Lu Feng ◽  
Tian-Yu Zeng ◽  
Hao-Bo Hou ◽  
Hong Zhou ◽  
Jian Tian
Keyword(s):  
Hydrogen Bonding ◽  
Theoretical Calculation ◽  
Proton Transport ◽  
Metal Organic Framework ◽  
Proton Conduction ◽  
Transport Channel ◽  
Proton Conducting ◽  
Metal Organic ◽  
Organic Framework

A water-mediated proton-conducting Eu(iii)-MOF has been synthesized, which provides a stable proton transport channel that was confirmed by theoretical calculation.

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