Unconventional Synthesis of a CuI Rotaxane with a Superacceptor Stopper: Ultrafast Excited-State Dynamics and Near-Infrared Luminescence

2018 ◽  
Vol 24 (41) ◽  
pp. 10422-10433 ◽  
Author(s):  
Yann Trolez ◽  
Aaron D. Finke ◽  
Fabio Silvestri ◽  
Filippo Monti ◽  
Barbara Ventura ◽  
...  
2013 ◽  
Vol 1571 ◽  
Author(s):  
Laurent Divay ◽  
Christophe Galindo ◽  
Françoise Soyer ◽  
Evelyne Chastaing ◽  
Renato Bisaro ◽  
...  

AbstractErbium excited state deactivation is studied for two fluorinated complexes based on N-(P,P-ditetrafluorophosphinoyl-P,P-ditetrafluorophenyl phosphinimidates and N-(P,P-dipentafluoro phosphinoyl)-P,P-dipentafluorophenyl phosphinimidates ligands. We show that the substitution of a fluorine atom in para-position by an hydrogen atom on each phenyl ring of the perfluorinated organic ligand results in a decrease in near infrared luminescence lifetimes from 800 µs to 70 µs when measured under vacuum on sublimated powder samples. These experiments show that the introduction of C-H bonds, although outside the first coordination sphere of the erbium ion, can still induce a one order of magnitude decrease in its excited state lifetime. The found lifetime however is still longer than most reported partially fluorinated complexes, which opens the way for new functionalized complexes.


2006 ◽  
Vol 137 (12) ◽  
pp. 678-679
Author(s):  
Marcin Sobczyk ◽  
Janusz Drożdżyński ◽  
Radosław Lisiecki ◽  
Piotr Solarz ◽  
Witold Ryba-Romanowski

2015 ◽  
Vol 5 (1) ◽  
Author(s):  
Jingyi Zhu ◽  
Daria M. Shcherbakova ◽  
Yusaku Hontani ◽  
Vladislav V. Verkhusha ◽  
John T. M. Kennis

2011 ◽  
Vol 13 (9) ◽  
pp. 3782-3787 ◽  
Author(s):  
Itay Gdor ◽  
Jingyi Zhu ◽  
Boris Loevsky ◽  
Elena Smolensky ◽  
Noga Friedman ◽  
...  

2004 ◽  
Vol 79 (7) ◽  
pp. 1747-1751 ◽  
Author(s):  
I.V. Rubtsov ◽  
R.M. Russo ◽  
T. Albers ◽  
P. Deria ◽  
D.E. Luzzi ◽  
...  

2008 ◽  
Vol 130 (30) ◽  
pp. 9773-9784 ◽  
Author(s):  
Timothy V. Duncan ◽  
P. Peter Ghoroghchian ◽  
Igor V. Rubtsov ◽  
Daniel A. Hammer ◽  
Michael J. Therien

2014 ◽  
Vol 118 (6) ◽  
pp. 993-1003 ◽  
Author(s):  
Mary Jane Simpson ◽  
Jesse W. Wilson ◽  
Francisco E. Robles ◽  
Christopher P. Dall ◽  
Keely Glass ◽  
...  

2020 ◽  
Vol 63 (8) ◽  
pp. 1075-1081 ◽  
Author(s):  
Xiaofei Miao ◽  
Haojie Tao ◽  
Wenbo Hu ◽  
Yonghui Pan ◽  
Quli Fan ◽  
...  

2003 ◽  
Vol 107 (40) ◽  
pp. 11216-11223 ◽  
Author(s):  
Emmanouil Papagiannakis ◽  
Ivo H. M. van Stokkum ◽  
Rienk van Grondelle ◽  
Robert A. Niederman ◽  
Donatas Zigmantas ◽  
...  

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