Acquiring High-Performance Deep-Blue OLED Emitters through an Unexpected Blueshift Color-Tuning Effect Induced by Electron-Donating -OMe Substituents

2018 ◽  
Vol 24 (32) ◽  
pp. 8056-8060 ◽  
Author(s):  
Song Peng ◽  
Yihuan Zhao ◽  
Caixia Fu ◽  
Xuemei Pu ◽  
Liang Zhou ◽  
...  
Keyword(s):  
High Performance ◽  
Color Tuning ◽  
Deep Blue

Tetraphenylbenzene-based AIEgens: the Horizontally Oriented Emitters for highly Efficient Non-doped Deep Blue OLEDs and Host for High-Performance Hybrid WOLEDs

2020 ◽  
Author(s):  
Pengbo Han ◽  
Zeng Xu ◽  
Chengwei Lin ◽  
Dongge Ma ◽  
Anjun Qin ◽  
...  
Keyword(s):  
High Performance ◽  
General Strategy ◽  
Flat Panel Displays ◽  
Light Emitting ◽  
Horizontal Orientation ◽  
Deep Blue ◽  
Full Color ◽  
High Emission ◽  
White Oleds ◽  
Low Efficiency

Deep blue organic-emitting fluorophores are crucial for application in white lighting and full color flat-panel displays but emitters with high color quality and efficiency are rare. Herein, novel deep blue AIE luminogens (AIEgens) with various donor units and an acceptor of cyano substituted tetraphenylbenzene (TPB) cores were developed and used to fabricate non-doped deep blue and hybrid white organic light-emitting diodes (OLEDs). Benefiting from its high emission efficiency and high proportion of horizontally oriented dipoles in the film state, the non-doped deep blue device based on CN-TPB-TPA realized a maximum external quantum efficiency 7.27%, with a low efficiency roll-off and CIE coordinates of (0.15, 0.08). Moreover, efficient two-color hybrid warm white OLEDs (CIE<sub>x,y</sub> = 0.43, 0.45) were achieved using CN-TPB-TPA as the blue-emitting layer and phosphor doped host, which realized maximum current, power, external quantum efficiencies 58.0 cd A<sup>-1</sup>, 60.7 lm W<sup>-1</sup> and 19.1%, respectively. This work provides a general strategy to achieve high performance, stable deep blue and hybrid white OLEDs by construction of AIEgens with excellent horizontal orientation

High performance full color OLEDs based on a class of molecules with dual carrier transport channels and small singlet–triplet splitting

2015 ◽  
Vol 51 (53) ◽  
pp. 10632-10635 ◽  
Author(s):  
Chenglong Li ◽  
Shipan Wang ◽  
Weiping Chen ◽  
Jinbei Wei ◽  
Guochun Yang ◽  
...  
Keyword(s):  
High Performance ◽  
Carrier Transport ◽  
Blue Emission ◽  
Deep Blue ◽  
Full Color ◽  
Triplet Splitting ◽  
Transport Channels

The strong deep blue emission, good ambipolar carrier transport and small singlet–triplet splitting characteristics allow PPI-PPITPA and PPI-PPIPCz as emitting materials and hosts to fabricate high performance full color OLEDs.

Recent advances of the emitters for high performance deep-blue organic light-emitting diodes

2015 ◽  
Vol 3 (5) ◽  
pp. 913-944 ◽  
Author(s):  
Xiaolong Yang ◽  
Xianbin Xu ◽  
Guijiang Zhou
Keyword(s):  
High Performance ◽  
Light Emitting Diodes ◽  
Organic Light Emitting Diodes ◽  
Light Emitting ◽  
Deep Blue ◽  
Organic Light ◽  
Recent Advances ◽  
Critical Issues ◽  
Blue Emitters

Recent advances in deep-blue emitters furnishing high performance OLEDs and associated critical issues are discussed and reviewed.

A combinational molecular design to achieve highly efficient deep-blue electrofluorescence

2018 ◽  
Vol 6 (4) ◽  
pp. 745-753 ◽  
Author(s):  
Mengying Bian ◽  
Zifeng Zhao ◽  
Yu Li ◽  
Qing Li ◽  
Zhijian Chen ◽  
...  
Keyword(s):  
High Performance ◽  
Molecular Design ◽  
Highly Efficient ◽  
Deep Blue

A novel high-performance deep-blue emitting material TPEA that combines the merits of AIE and TTF plus HLCT is demonstrated.

scholarly journals Constructing Donor-Resonance-Donor Molecules for Acceptor-Free Bipolar Organic Semiconductors

Research ◽  
2021 ◽  
Vol 2021 ◽  
pp. 1-10
Author(s):  
He Jiang ◽  
Jibiao Jin ◽  
Zijie Wang ◽  
Wuji Wang ◽  
Runfeng Chen ◽  
...  
Keyword(s):  
Organic Semiconductors ◽  
High Performance ◽  
Molecular Design ◽  
Stimuli Responsive ◽  
Light Emitting ◽  
Deep Blue ◽  
Device Structures ◽  
Device Applications ◽  
Donor Acceptor ◽  
Organic Optoelectronic

Organic semiconductors with bipolar transporting character are highly attractive as they offer the possibility to achieve high optoelectronic performance in simple device structures. However, the continual efforts in preparing bipolar materials are focusing on donor-acceptor (D-A) architectures by introducing both electron-donating and electron-withdrawing units into one molecule in static molecular design principles. Here, we report a dynamic approach to construct bipolar materials using only electron-donating carbazoles connected by N-P=X resonance linkages in a donor-resonance-donor (D-r-D) structure. By facilitating the stimuli-responsive resonance variation, these D-r-D molecules exhibit extraordinary bipolar properties by positively charging one donor of carbazole in enantiotropic N+=P-X- canonical forms for electron transport without the involvement of any acceptors. With thus realized efficient and balanced charge transport, blue and deep-blue phosphorescent organic light emitting diodes hosted by these D-r-D molecules show high external quantum efficiencies up to 16.2% and 18.3% in vacuum-deposited and spin-coated devices, respectively. These results via the D-r-D molecular design strategy represent an important concept advance in constructing bipolar organic optoelectronic semiconductors dynamically for high-performance device applications.

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