Frontispiece: Iron(II), Cobalt(II), Nickel(II), and Zinc(II) Silylene Complexes: Reaction of the Silylene [i
PrNC(Ni
Pr2
)Ni
Pr]2
Si with FeBr2
, CoBr2
, NiBr2
⋅MeOCH2
CH2
OMe, ZnCl2
, and ZnBr2

Johannes A. Baus; Felix M. Mück; Heidi Schneider; Reinhold Tacke

doi:10.1002/chem.201780263

Frontispiece: Iron(II), Cobalt(II), Nickel(II), and Zinc(II) Silylene Complexes: Reaction of the Silylene [i PrNC(Ni Pr2 )Ni Pr]2 Si with FeBr2 , CoBr2 , NiBr2 ⋅MeOCH2 CH2 OMe, ZnCl2 , and ZnBr2

Chemistry - A European Journal ◽

10.1002/chem.201780263 ◽

2017 ◽

Vol 23 (2) ◽

Author(s):

Johannes A. Baus ◽

Felix M. Mück ◽

Heidi Schneider ◽

Reinhold Tacke

Keyword(s):

Silylene Complexes

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Synthesis and Characterization of DMAP-Stabilized Aryl(silylene) Complexes and (Arylsilyl)(DMAP) Complexes of Tungsten: Mechanistic Study on the Interconversion between These Complexes via 1,2-Aryl Migration

Organometallics ◽

10.1021/om801140d ◽

2009 ◽

Vol 28 (6) ◽

pp. 1791-1799 ◽

Cited By ~ 19

Author(s):

Eiji Suzuki ◽

Takashi Komuro ◽

Masaaki Okazaki ◽

Hiromi Tobita

Keyword(s):

Synthesis And Characterization ◽

Mechanistic Study ◽

Silylene Complexes

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The First Resonance Hybrid of Silyl–Carbene and Pyridyl–Silylene Complexes: Formation by Aryl C–H Bond Activation of DMAP [4-(Dimethylamino)pyridine] on a Silylene Complex

Chemistry Letters ◽

10.1246/cl.2007.650 ◽

2007 ◽

Vol 36 (5) ◽

pp. 650-651 ◽

Cited By ~ 10

Author(s):

Rockshana Begum ◽

Takashi Komuro ◽

Hiromi Tobita

Keyword(s):

Bond Activation ◽

Silylene Complexes ◽

Resonance Hybrid

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Germylene and Silylene Complexes of Molybdenum via E−H (E = Ge, Si) Bond Activations: Steric Influences on Intramolecular MoH···E Interactions

Inorganic Chemistry ◽

10.1021/ic901168s ◽

2009 ◽

Vol 48 (17) ◽

pp. 8081-8083 ◽

Cited By ~ 22

Author(s):

Akihiro Shinohara ◽

Jennifer McBee ◽

T. Don Tilley

Keyword(s):

Silylene Complexes ◽

Bond Activations

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Structural Similarities in Dinuclear, Tetranuclear, and Pentanuclear Nickel Silyl and Silylene Complexes Obtained via Si–H and Si–C Activation

Organometallics ◽

10.1021/om300120x ◽

2012 ◽

Vol 31 (9) ◽

pp. 3599-3609 ◽

Cited By ~ 44

Author(s):

Robert Beck ◽

Samuel A. Johnson

Keyword(s):

Silylene Complexes

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Silyl(silylene) Complexes of Iron and Ruthenium

Efficient Methods for Preparing Silicon Compounds ◽

10.1016/b978-0-12-803530-6.00028-7 ◽

2016 ◽

pp. 381-384

Author(s):

H. Tobita

Keyword(s):

Silylene Complexes

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Reactivity of Silylene Complexes

ChemInform ◽

10.1002/chin.200344227 ◽

2003 ◽

Vol 34 (44) ◽

Author(s):

Masaaki Okazaki ◽

Hiromi Tobita ◽

Hiroshi Ogino

Keyword(s):

Silylene Complexes

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Synthesis, Structure, and Reactivity of Osmium Silyl and Silylene Complexes Cp(Me3P)2OsSiR2X and [Cp(Me3P)2OsSiR2][B(C6F5)4] (R = Me,iPr; X = Cl, OTf)

Organometallics ◽

10.1021/om0341808 ◽

2004 ◽

Vol 23 (4) ◽

pp. 693-704 ◽

Cited By ~ 39

Author(s):

Paul B. Glaser ◽

Paulus W. Wanandi ◽

T. Don Tilley

Keyword(s):

Silylene Complexes

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Synthesis and Reactivity of Pincer-Type Cobalt Silyl and Silylene Complexes

Organometallics ◽

10.1021/acs.organomet.8b00594 ◽

2018 ◽

Vol 37 (21) ◽

pp. 3956-3962 ◽

Cited By ~ 11

Author(s):

Jia Zhang ◽

Bryan J. Foley ◽

Nattamai Bhuvanesh ◽

Jia Zhou ◽

Daron E. Janzen ◽

...

Keyword(s):

Silylene Complexes

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Reactions of Manganese Silyl and Silylene Complexes with CO2 and C(NiPr)2: Synthesis of Mn(I) Formate and Amidinylsilyl Complexes

Organometallics ◽

10.1021/acs.organomet.0c00654 ◽

2020 ◽

Vol 39 (24) ◽

pp. 4618-4628

Author(s):

Jeffrey S. Price ◽

David J. H. Emslie

Keyword(s):

Silylene Complexes

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Synthesis and Structure of PNP-Supported Iridium Silyl and Silylene Complexes: Catalytic Hydrosilation of Alkenes

Journal of the American Chemical Society ◽

10.1021/ja903737j ◽

2009 ◽

Vol 131 (31) ◽

pp. 11161-11173 ◽

Cited By ~ 88

Author(s):

Elisa Calimano ◽

T. Don Tilley

Keyword(s):

Silylene Complexes

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Frontispiece: Iron(II), Cobalt(II), Nickel(II), and Zinc(II) Silylene Complexes: Reaction of the Silylene [i PrNC(Ni Pr2 )Ni Pr]2 Si with FeBr2 , CoBr2 , NiBr2 ⋅MeOCH2 CH2 OMe, ZnCl2 , and ZnBr2

Synthesis and Characterization of DMAP-Stabilized Aryl(silylene) Complexes and (Arylsilyl)(DMAP) Complexes of Tungsten: Mechanistic Study on the Interconversion between These Complexes via 1,2-Aryl Migration

The First Resonance Hybrid of Silyl–Carbene and Pyridyl–Silylene Complexes: Formation by Aryl C–H Bond Activation of DMAP [4-(Dimethylamino)pyridine] on a Silylene Complex

Germylene and Silylene Complexes of Molybdenum via E−H (E = Ge, Si) Bond Activations: Steric Influences on Intramolecular MoH···E Interactions

Structural Similarities in Dinuclear, Tetranuclear, and Pentanuclear Nickel Silyl and Silylene Complexes Obtained via Si–H and Si–C Activation

Silyl(silylene) Complexes of Iron and Ruthenium

Reactivity of Silylene Complexes

Synthesis, Structure, and Reactivity of Osmium Silyl and Silylene Complexes Cp*(Me3P)2OsSiR2X and [Cp*(Me3P)2OsSiR2][B(C6F5)4] (R = Me,iPr; X = Cl, OTf)

Synthesis and Reactivity of Pincer-Type Cobalt Silyl and Silylene Complexes

Reactions of Manganese Silyl and Silylene Complexes with CO2 and C(NiPr)2: Synthesis of Mn(I) Formate and Amidinylsilyl Complexes

Synthesis and Structure of PNP-Supported Iridium Silyl and Silylene Complexes: Catalytic Hydrosilation of Alkenes

Synthesis, Structure, and Reactivity of Osmium Silyl and Silylene Complexes Cp(Me3P)2OsSiR2X and [Cp(Me3P)2OsSiR2][B(C6F5)4] (R = Me,iPr; X = Cl, OTf)