scholarly journals Electron-Proton Transfer Mechanism of Excited-State Hydrogen Transfer in Phenol-(NH3 ) n (n= 3 and 5)

2017 ◽  
Vol 24 (4) ◽  
pp. 881-890 ◽  
Author(s):  
Mitsuhiko Miyazaki ◽  
Ryuhei Ohara ◽  
Claude Dedonder ◽  
Christophe Jouvet ◽  
Masaaki Fujii
Keyword(s):  
Excited State ◽  
Proton Transfer ◽  
Hydrogen Transfer ◽  
Transfer Mechanism ◽  
Electron Proton Transfer

scholarly journals Revealing the role of excited state proton transfer (ESPT) in excited state hydrogen transfer (ESHT): systematic study in phenol–(NH3)n clusters

2021 ◽  
Author(s):  
Christophe Jouvet ◽  
Mitsuhiko Miyazaki ◽  
Masaaki Fujii
Keyword(s):  
Excited State ◽  
Proton Transfer ◽  
Systematic Study ◽  
General Model ◽  
Hydrogen Transfer ◽  
Excited State Proton Transfer

A general model of excited state hydrogen transfer (ESHT) which unifies ESHT and the excited state proton transfer (ESPT) is presented from experimental and theoretical works on phenol–(NH3)n. The hidden role of ESPT is revealed.

Enantioenrichment of racemic BINOL by way of excited state proton transfer

2019 ◽  
Vol 55 (9) ◽  
pp. 1263-1266 ◽  
Author(s):  
Suliman Ayad ◽  
Victoria Posey ◽  
Anjan Das ◽  
Jason M. Montgomery ◽  
Kenneth Hanson
Keyword(s):  
Excited State ◽  
Proton Transfer ◽  
Transfer Mechanism ◽  
Chiral Auxiliary ◽  
Excited State Proton Transfer

BINOL substituted with a chiral auxiliary group is enantioenriched up to 63% ee via an excited state proton transfer mechanism.

Sign in / Sign up

Export Citation Format

Share Document