scholarly journals Analysis of Magnetic Anisotropy and the Role of Magnetic Dilution in Triggering Single-Molecule Magnet (SMM) Behavior in a Family of CoII YIII Dinuclear Complexes with Easy-Plane Anisotropy

2017 ◽  
Vol 23 (48) ◽  
pp. 11649-11661 ◽  
Author(s):  
María A. Palacios ◽  
Joscha Nehrkorn ◽  
Elizaveta A. Suturina ◽  
Eliseo Ruiz ◽  
Silvia Gómez-Coca ◽  
...  
Keyword(s):  
Magnetic Anisotropy ◽  
Single Molecule ◽  
Easy Plane ◽  
Dinuclear Complexes ◽  
Single Molecule Magnet ◽  
Plane Anisotropy ◽  
Magnetic Dilution

Wheel-type heterometallic ferromagnetic clusters: [Ni7−xMx(HL)6(μ3-OMe)4(μ3-OH)2]Cl2 (M = Zn, Co, Mn; x = 1, 3)

2018 ◽  
Vol 47 (46) ◽  
pp. 16422-16428 ◽  
Author(s):  
Fumiya Kobayashi ◽  
Ryo Ohtani ◽  
Sotaro Kusumoto ◽  
Leonard F. Lindoy ◽  
Shinya Hayami ◽  
...  
Keyword(s):  
Magnetic Anisotropy ◽  
Single Molecule ◽  
Metal Ion ◽  
Heterometallic Clusters ◽  
Single Molecule Magnet ◽  
Ferromagnetic Properties ◽  
Behavior Based

Wheel-type heptanuclear heterometallic clusters display metal ion dependent ferromagnetic properties and express single molecule magnet behavior based on the magnetic anisotropy.

Fine-tuning the type of equatorial donor atom in pentagonal bipyramidal Dy(iii) complexes to enhance single-molecule magnet properties

2019 ◽  
Vol 48 (43) ◽  
pp. 16384-16394 ◽  
Author(s):  
Haipeng Wu ◽  
Min Li ◽  
Bing Yin ◽  
Zhengqiang Xia ◽  
Hongshan Ke ◽  
...  
Keyword(s):  
Magnetic Anisotropy ◽  
Single Molecule ◽  
Electronic Effect ◽  
Fine Tuning ◽  
Donor Atom ◽  
Single Molecule Magnet

Upon fine-tuning an equatorial donor, the electronic effect is implemented to significantly enhance magnetic anisotropy in pentagonal bipyramidal DyIII complexes.

scholarly journals Probing transverse magnetic anisotropy by electronic transport through a single-molecule magnet

2015 ◽  
Vol 91 (3) ◽  
Author(s):  
M. Misiorny ◽  
E. Burzurí ◽  
R. Gaudenzi ◽  
K. Park ◽  
M. Leijnse ◽  
...  
Keyword(s):  
Magnetic Anisotropy ◽  
Single Molecule ◽  
Electronic Transport ◽  
Transverse Magnetic ◽  
Single Molecule Magnet

scholarly journals On Approaching the Limit of Molecular Magnetic Anisotropy: A Near-Perfect Pentagonal Bipyramidal Dysprosium(III) Single-Molecule Magnet

2016 ◽  
Vol 55 (52) ◽  
pp. 16071-16074 ◽  
Author(s):  
You-Song Ding ◽  
Nicholas F. Chilton ◽  
Richard E. P. Winpenny ◽  
Yan-Zhen Zheng
Keyword(s):  
Magnetic Anisotropy ◽  
Single Molecule ◽  
Single Molecule Magnet

Effect of Pressure on the Magnetic Anisotropy in the Single-Molecule Magnet Mn12-Acetate: An Inelastic Neutron Scattering Study

2005 ◽  
Vol 117 (27) ◽  
pp. 4311-4314 ◽  
Author(s):  
Andreas Sieber ◽  
Roland Bircher ◽  
Oliver Waldmann ◽  
Graham Carver ◽  
Grégory Chaboussant ◽  
...  
Keyword(s):  
Magnetic Anisotropy ◽  
Neutron Scattering ◽  
Single Molecule ◽  
Inelastic Neutron Scattering ◽  
Inelastic Neutron ◽  
Single Molecule Magnet ◽  
Effect Of Pressure ◽  
Scattering Study ◽  
Neutron Scattering Study

Determination of magnetic anisotropy in a multinuclear TbIII-based single-molecule magnet

2015 ◽  
Vol 51 (52) ◽  
pp. 10373-10376 ◽  
Author(s):  
Xing-Cai Huang ◽  
Veacheslav Vieru ◽  
Liviu F. Chibotaru ◽  
Wolfgang Wernsdorfer ◽  
Shang-Da Jiang ◽  
...  
Keyword(s):  
Magnetic Anisotropy ◽  
Single Molecule ◽  
Structural Relationship ◽  
Anisotropy Axis ◽  
Single Molecule Magnet

The magnetic anisotropy axis of the Tb3+ ion in a tetranuclear [CuTb]2 SMM was established by magneto-structural relationship investigation.

Role of the Orbitally Degenerate Mn(III) Ions in the Single-Molecule Magnet Behavior of the Cyanide Cluster {[MnII(tmphen)2]3[MnIII(CN)6]2} (tmphen = 3,4,7,8-tetramethyl-1,10-phenanthroline)

2004 ◽  
Vol 126 (51) ◽  
pp. 16860-16867 ◽  
Author(s):  
Andrei V. Palii ◽  
Sergei M. Ostrovsky ◽  
Sophia I. Klokishner ◽  
Boris S. Tsukerblat ◽  
Curtis P. Berlinguette ◽  
...  
Keyword(s):  
Single Molecule ◽  
Single Molecule Magnet

On Approaching the Limit of Molecular Magnetic Anisotropy: A Near-Perfect Pentagonal Bipyramidal Dysprosium(III) Single-Molecule Magnet

2016 ◽  
Vol 128 (52) ◽  
pp. 16305-16308 ◽  
Author(s):  
You-Song Ding ◽  
Nicholas F. Chilton ◽  
Richard E. P. Winpenny ◽  
Yan-Zhen Zheng
Keyword(s):  
Magnetic Anisotropy ◽  
Single Molecule ◽  
Single Molecule Magnet

The role of coordinated solvent on Co(ii) ions in tuning the single molecule magnet properties in a {CoII2DyIII2} system

2017 ◽  
Vol 46 (16) ◽  
pp. 5337-5343 ◽  
Author(s):  
Yan Peng ◽  
Valeriu Mereacre ◽  
Christopher E. Anson ◽  
Annie K. Powell
Keyword(s):  
Single Molecule ◽  
Solvent Molecule ◽  
Coordination Geometry ◽  
Single Molecule Magnet ◽  
System P

The anisotropy of a single DyIII can be steered through subtle changes in the coordination geometry of the CoII ions in CoII2DyIII2 butterfly compounds resulting from changing the coordinated solvent molecule on the CoII ion.

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