High-Loading Crystals of Tetraaryladamantanes and the Uptake and Release of Aromatic Hydrocarbons from the Gas Phase

2017 ◽  
Vol 23 (38) ◽  
pp. 9018-9021 ◽  
Author(s):  
Pierre-Emmanuel Alexandre ◽  
Alexander Schwenger ◽  
Wolfgang Frey ◽  
Clemens Richert
Keyword(s):  
Gas Phase ◽  
Aromatic Hydrocarbons ◽  
High Loading ◽  
Uptake And Release

The gas phase reactivity of the dimethylchloronium ion with alkylbenzenes

1981 ◽  
Vol 59 (15) ◽  
pp. 2412-2416 ◽  
Author(s):  
John A. Stone ◽  
Margaret S. Lin ◽  
Jeffrey Varah
Keyword(s):  
High Pressure ◽  
Gas Phase ◽  
Mass Spectrometer ◽  
Aromatic Hydrocarbons ◽  
Relative Rate ◽  
Ion Source ◽  
Nucleophilic Displacement ◽  
Rate Of Reaction ◽  
Displacement Reactions ◽  
Bonded Complexes

The reactivity of the dimethylchloronium ion with a series of aromatic hydrocarbons has been studied in a high pressure mass spectrometer ion source using the technique of reactant ion monitoring. Benzene is unreactive but all others, from toluene to mesitylene, react by CH3+ transfer to yield σ-bonded complexes. The relative rate of reaction increases with increasing exothermicity in line with current theories of nucleophilic displacement reactions.

scholarly journals Study of passive sampling of polycyclic aromatic hydrocarbons in gas phase using Amberlite XAD resins as filling materials of semipermeable membranes

2013 ◽  
Vol 110 ◽  
pp. 494-500 ◽  
Author(s):  
Luis Gustavo T. dos Reis ◽  
Daniel Gallart-Mateu ◽  
Wagner F. Pacheco ◽  
Agustín Pastor ◽  
Miguel de la Guardia ◽  
...  
Keyword(s):  
Polycyclic Aromatic Hydrocarbons ◽  
Gas Phase ◽  
Aromatic Hydrocarbons ◽  
Passive Sampling ◽  
Semipermeable Membranes ◽  
Filling Materials ◽  
Polycyclic Aromatic ◽  
Xad Resins

scholarly journals Variability of polycyclic aromatic hydrocarbons and their oxidative derivatives in wintertime Beijing, China

2019 ◽  
Vol 19 (13) ◽  
pp. 8741-8758 ◽  
Author(s):  
Atallah Elzein ◽  
Rachel E. Dunmore ◽  
Martyn W. Ward ◽  
Jacqueline F. Hamilton ◽  
Alastair C. Lewis
Keyword(s):  
Polycyclic Aromatic Hydrocarbons ◽  
Gas Phase ◽  
Aromatic Hydrocarbons ◽  
Total Concentration ◽  
Diagnostic Ratios ◽  
Strong Positive Correlation ◽  
Night Time ◽  
Naphthalic Anhydride ◽  
Positive Correlation ◽  
Polycyclic Aromatic

Abstract. Ambient particulate matter (PM) can contain a mix of different toxic species derived from a wide variety of sources. This study quantifies the diurnal variation and nocturnal abundance of 16 polycyclic aromatic hydrocarbons (PAHs), 10 oxygenated PAHs (OPAHs) and 9 nitrated PAHs (NPAHs) in ambient PM in central Beijing during winter. Target compounds were identified and quantified using gas chromatography–time-of-flight mass spectrometry (GC-Q-ToF-MS). The total concentration of PAHs varied between 18 and 297 ng m−3 over 3 h daytime filter samples and from 23 to 165 ng m−3 in 15 h night-time samples. The total concentrations of PAHs over 24 h varied between 37 and 180 ng m−3 (mean: 97±43 ng m−3). The total daytime concentrations during high particulate loading conditions for PAHs, OPAHs and NPAHs were 224, 54 and 2.3 ng m−3, respectively. The most abundant PAHs were fluoranthene (33 ng m−3), chrysene (27 ng m−3), pyrene (27 ng m−3), benzo[a]pyrene (27 ng m−3), benzo[b]fluoranthene (25 ng m−3), benzo[a]anthracene (20 ng m−3) and phenanthrene (18 ng m−3). The most abundant OPAHs were 9,10-anthraquinone (18 ng m−3), 1,8-naphthalic anhydride (14 ng m−3) and 9-fluorenone (12 ng m−3), and the three most abundant NPAHs were 9-nitroanthracene (0.84 ng m−3), 3-nitrofluoranthene (0.78 ng m−3) and 3-nitrodibenzofuran (0.45 ng m−3). ∑PAHs and ∑OPAHs showed a strong positive correlation with the gas-phase abundance of NO, CO, SO2 and HONO, indicating that PAHs and OPAHs can be associated with both local and regional emissions. Diagnostic ratios suggested emissions from traffic road and coal combustion were the predominant sources of PAHs in Beijing and also revealed the main source of NPAHs to be secondary photochemical formation rather than primary emissions. PM2.5 and NPAHs showed a strong correlation with gas-phase HONO. 9-Nitroanthracene appeared to undergo a photodegradation during the daytime and showed a strong positive correlation with ambient HONO (R=0.90, P < 0.001). The lifetime excess lung cancer risk for those species that have available toxicological data (16 PAHs, 1 OPAH and 6 NPAHs) was calculated to be in the range 10−5 to 10−3 (risk per million people ranges from 26 to 2053 cases per year).

Gas phase adiabatic electron affinities of cyclopenta-fused polycyclic aromatic hydrocarbons

2008 ◽  
Vol 454 (1-3) ◽  
pp. 30-35 ◽  
Author(s):  
Petar D. Todorov ◽  
Carola Koper ◽  
Joop H. van Lenthe ◽  
Leonardus W. Jenneskens
Keyword(s):  
Polycyclic Aromatic Hydrocarbons ◽  
Gas Phase ◽  
Aromatic Hydrocarbons ◽  
Electron Affinities ◽  
Polycyclic Aromatic

Synthesis of benzothiophenes in gas phase from aromatic hydrocarbons and carbon disulfide

1986 ◽  
Vol 30 (1) ◽  
pp. 157-163 ◽  
Author(s):  
S. Esteban ◽  
J. M. Marinas ◽  
M. P. Martinez-Alcazar ◽  
M. Martinez ◽  
A. R. Agarrabeitia
Keyword(s):  
Gas Phase ◽  
Carbon Disulfide ◽  
Aromatic Hydrocarbons
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