Back Cover: Anatase TiO 2 Mesocrystals: Green Synthesis, In Situ Conversion to Porous Single Crystals, and Self‐Doping Ti 3+ for Enhanced Visible Light Driven Photocatalytic Removal of NO (Chem. Eur. J. 23/2017)

2017 ◽  
Vol 23 (23) ◽  
pp. 5626-5626
Author(s):  
Biying Tan ◽  
Xuehao Zhang ◽  
Yongjun Li ◽  
Hao Chen ◽  
Xiaozhou Ye ◽  
...  
Nanomaterials ◽  
2019 ◽  
Vol 9 (11) ◽  
pp. 1571 ◽  
Author(s):  
Shijie Li ◽  
Bing Xue ◽  
Chunchun Wang ◽  
Wei Jiang ◽  
Shiwei Hu ◽  
...  

Novel heterojunction photocatalysts with remarkable photocatalytic capabilities and durability for degrading recalcitrant contaminants are extremely desired; however, their development still remains quite challenging. In this study, a series of flower-like BiOI/BiOCOOH p–n heterojunctions were fabricated via a controlled in situ anion-exchange process. During the process, BiOI formation and even deposition on BiOCOOH microspheres with tight interfacial contact were realized. As expected, BiOI/BiOCOOH heterojunctions revealed remarkable enhancements in photocatalytic antibiotic degradation capacities under visible light irradiation compared with pristine BiOI and BiOCOOH. The best-performing BiOI/BiOCOOH heterojunction (i.e., IBOCH-2) showed much improved photocatalytic CIP degradation efficiency of approximately 81- and 3.9-fold greater than those of bare BiOI and BiOCOOH, respectively. The eminent photocatalytic performances were due not only to the enhanced capability in harvesting photon energies in visible light regions, but also the accelerated separation of electrons and holes boosted by the p–n heterojunction. Active species trapping tests demonstrated that superoxide free radicals (•O2−) and photo-generated holes (h+) were major active species for CIP degradation. Recycling experiments verified the good durability of BIBO-2 over four runs. The facile in situ synthesis route and excellent performance endow flower-like BiOI/BiOCOOH heterojunctions with a promising potential for actual environmental remediation.


2018 ◽  
Vol 9 ◽  
pp. 2297-2305 ◽  
Author(s):  
Shijie Li ◽  
Wei Jiang ◽  
Shiwei Hu ◽  
Yu Liu ◽  
Yanping Liu ◽  
...  

Developing highly active and durable visible-light-driven photocatalysts for the degradation of toxic pollutants is of vital significance. Herein, Ag2CO3 nanoparticles were in situ formed on Bi2MoO6 microflowers to produce Ag2CO3/Bi2MoO6 heterostructures via a facile procedure. The morphologies, phases, chemical compositions, and optical properties of Ag2CO3/Bi2MoO6 were examined by multiple characterization techniques. The Ag2CO3/Bi2MoO6 heterostructures exhibited substantially improved performance in the removal of industrial dyes (rhodamine B (RhB), methyl orange (MO), and methyl blue (MB)), and the antibiotic tetracycline hydrochloride (TC), compared with bare Bi2MoO6 and Ag2CO3 under visible-light irradiation. The enhancement of activity was attributed to the high charge-separation capacity, which results from the matched band alignment of the two components. The cycling experiments showed a good durability of Ag2CO3/Bi2MoO6. Holes were found to be the dominant active species accounting for the pollutant degradation. This compound is a promising candidate for wastewater treatment.


2021 ◽  
Author(s):  
Luqiu Li ◽  
Dongguang Yin ◽  
Xiandi Guo

Covalent organic frameworks (COFs) representing an emerging class of porous crystalline material have shown promising visible-light-driven hydrogen evolution activity. However, they have a high recombination ratio of charge carriers and...


2019 ◽  
Vol 45 (5) ◽  
pp. 6340-6349 ◽  
Author(s):  
Wenjing Xue ◽  
Zhiwei Peng ◽  
Danlian Huang ◽  
Guangming Zeng ◽  
Xiaoju Wen ◽  
...  

2016 ◽  
Vol 191 ◽  
pp. 228-234 ◽  
Author(s):  
Dongbo Xu ◽  
Weidong Shi ◽  
Chengjie Song ◽  
Min Chen ◽  
Songbo Yang ◽  
...  

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