Synthesis and Oxidation of a Paddlewheel-Shaped Rhodium/Antimony Complex Featuring Pyridine-2-Thiolate Ligands

2017 ◽  
Vol 23 (14) ◽  
pp. 3447-3454 ◽  
Author(s):  
Erik Wächtler ◽  
Luis A. Oro ◽  
Manuel Iglesias ◽  
Birgit Gerke ◽  
Rainer Pöttgen ◽  
...  
Keyword(s):  
Thiolate Ligands ◽  
Antimony Complex

Highly Fluorescent Au25-xAgx Nanoclusters Protected with Poly(ethylene glycol) - and Zwitterion-Modified Thiolate Ligands

2018 ◽  
Author(s):  
Dinesh Mishra ◽  
Sisi Wang ◽  
Zhicheng Jin ◽  
Eric Lochner ◽  
Hedi Mattoussi
Keyword(s):  
Quantum Yield ◽  
Near Infrared ◽  
Small Diameter ◽  
Binding Energies ◽  
Thiolate Ligands ◽  
Nir Emission ◽  
Thiolate Complexes ◽  
Long Lifetime ◽  
Poly Ethylene

<p>We describe the growth and characterization of highly fluorescing, near-infrared-emitting nanoclusters made of bimetallic Au<sub>25-x</sub>Ag<sub>x</sub> cores, prepared using various monothiol-appended hydrophobic and hydrophilic ligands. The reaction uses well-defined triphenylphosphine-protected Au<sub>11</sub> clusters (as precursors), which are reacted with Ag(I)-thiolate complexes. The prepared nanoclusters are small (diameter < 2nm, as characterized by TEM) with emission peak at 760 nm and long lifetime (~12 µs). The quantum yield measured for these materials was 0.3 - 0.4 depending on the ligand. XPS measurements show the presence of both metal atoms in the core, with measured binding energies that agree with reported values for nanocluster materials. The NIR emission combined with high quantum yield, small size and ease of surface functionalization afforded by the coating, make these materials suitable to implement investigations that address fundamental questions and potentially useful for biological sensing and imaging applications.<br></p>

Size-Dependent Dissociation pH of Thiolate Ligands from Cadmium Chalcogenide Nanocrystals

2005 ◽  
Vol 127 (8) ◽  
pp. 2496-2504 ◽  
Author(s):  
Jose Aldana ◽  
Natasha Lavelle ◽  
Yunjun Wang ◽  
Xiaogang Peng
Keyword(s):  
Size Dependent ◽  
Thiolate Ligands ◽  
Cadmium Chalcogenide

Mixed-Valence Manganese Carbonyl Complexes with Supersilyl Thiolate Ligands: [(OC)4Mn(μ-SSitBu3)2Mn(THF)X] (X = Br, SSitBu3) and Na(THF)6[(OC)3Mn(μ-SSitBu3)3MnSSitBu3]

2008 ◽  
Vol 27 (13) ◽  
pp. 3272-3278 ◽  
Author(s):  
Theresa I. Kückmann ◽  
Frauke Schödel ◽  
Inge Sänger ◽  
Michael Bolte ◽  
Matthias Wagner ◽  
...  
Keyword(s):  
Mixed Valence ◽  
Carbonyl Complexes ◽  
Thiolate Ligands ◽  
Manganese Carbonyl

On the stability of noble-metal nanoclusters protected with thiolate ligands

2017 ◽  
Vol 119 (5) ◽  
pp. 56002 ◽  
Author(s):  
Cercis Morera-Boado ◽  
Francisco Hidalgo ◽  
Cecilia Noguez
Keyword(s):  
Noble Metal ◽  
Metal Nanoclusters ◽  
Thiolate Ligands ◽  
The Stability ◽  
Noble Metal Nanoclusters

Complexes of molybdenum with novel sterically-hindered thiolate ligands

1989 ◽  
Vol 36 (3-4) ◽  
pp. 179
Author(s):  
Eric Block ◽  
Hyunkyu Kang ◽  
Gabriel Ofori-Okai ◽  
Jun Zubieta
Keyword(s):  
Thiolate Ligands ◽  
Sterically Hindered

Phosphido-bridged dimolybdenum complexes with sulfide and thiolate ligands as precursors to mixed-metal clusters

1997 ◽  
Vol 542 (1) ◽  
pp. 131-140 ◽  
Author(s):  
H. Adams ◽  
N.A. Bailey ◽  
M.N. Bancroft ◽  
A.P. Bisson ◽  
M.J. Morris
Keyword(s):  
Metal Clusters ◽  
Mixed Metal ◽  
Thiolate Ligands ◽  
Mixed Metal Clusters

CdS nanoclusters stabilized by thiolate ligands: A mini-review

1996 ◽  
Vol 7 (3) ◽  
pp. 341-350 ◽  
Author(s):  
Catherine J. Murphy
Keyword(s):  
Thiolate Ligands
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