scholarly journals In Situ Solid-State Reactions Monitored by X-ray Absorption Spectroscopy: Temperature-Induced Proton Transfer Leads to Chemical Shifts

2016 ◽  
Vol 22 (44) ◽  
pp. 15600-15604 ◽  
Author(s):  
Joanna S. Stevens ◽  
Monika Walczak ◽  
Cherno Jaye ◽  
Daniel A. Fischer
Keyword(s):  
Solid State ◽  
Proton Transfer ◽  
Absorption Spectroscopy ◽  
Chemical Shifts ◽  
Solid State Reactions ◽  
X Ray ◽  
X Ray Absorption

In Situ X-ray Absorption Spectroscopy in the Soft Energy Range: Novel Prospects for the Chemical Characterization of Solid State Surfaces at High Pressure And High Temperature

2001 ◽  
Vol 678 ◽  
Author(s):  
Th. Schedel-Niedrig ◽  
M. Hävecker ◽  
A. Knop-Gericke ◽  
P. Reinke ◽  
R. Schlögl ◽  
...  
Keyword(s):  
Solid State ◽  
Absorption Spectroscopy ◽  
Material Science ◽  
Chemical Characterization ◽  
Total Electron ◽  
Diamond Surfaces ◽  
X Ray ◽  
Surface Electronic Structure ◽  
X Ray Absorption

AbstractAn instrument equipped with total electron yield detectors was designed and constructed for in situ X-ray absorption spectroscopy (XAS) investigations in the soft X-ray range (100 eV ≤ hν ≤ 1000 eV) at elevated pressures (mbar range) and sample temperatures (T ≤ 1000 K) [1]. This allows, for the first time, XAS studies in a surface-sensitive mode of the light elements (Z = 3-15). Furthermore, the gas phase XAS and the surface-related XAS of the solid state phase can be collected simultaneously in order to correlate the gas/solid reaction rate with the surface electronic structure under working conditions in a flow-through mode.The novel experimental tool represents a contribution to the experimental overcoming of the “pressure gap” in material science. In this work examples are presented belonging to the field of heterogeneous catalysis [2-4] and to the reactivity of diamond surfaces [5]. Additionally, prospects for in situ studies in material science will be given.

Application of In Situ X-ray Absorption Spectroscopy to Study Dilute Chromium Ions in a Molten Chloride Salt

2019 ◽  
Author(s):  
Jisue Moon ◽  
Carter Abney ◽  
Dmitriy Dolzhnikov ◽  
James M. Kurley ◽  
Kevin A. Beyer ◽  
...  
Keyword(s):  
Absorption Spectroscopy ◽  
Local Structure ◽  
Chloride Salt ◽  
X Ray ◽  
Molten Chloride ◽  
Stable Species ◽  
Higher Temperature ◽  
Cr Concentration ◽  
X Ray Absorption

The local structure of dilute CrCl<sub>3</sub> in a molten MgCl<sub>2</sub>:KCl salt was investigated by <i>in situ</i> x-ray absorption spectroscopy (XAS) at temperatures from room temperature to 800<sup>o</sup>C. This constitutes the first experiment where dilute Cr speciation is explored in a molten chloride salt, ostensibly due to the compounding challenges arising from a low Cr concentration in a matrix of heavy absorbers at extreme temperatures. CrCl<sub>3</sub> was confirmed to be the stable species between 200 and 500<sup>o</sup>C, while mobility of metal ions at higher temperature (>700<sup>o</sup>C) prevented confirmation of the local structure.

Revealing the structural transformation of rutile RuO2via in situ X-ray absorption spectroscopy during the oxygen evolution reaction

2019 ◽  
Vol 48 (21) ◽  
pp. 7122-7129 ◽  
Author(s):  
Chia-Jui Chang ◽  
You-Chiuan Chu ◽  
Hao-Yu Yan ◽  
Yen-Fa Liao ◽  
Hao Ming Chen
Keyword(s):  
Oxygen Evolution ◽  
Structural Transformation ◽  
Absorption Spectroscopy ◽  
Oxygen Evolution Reaction ◽  
The State ◽  
X Ray ◽  
Alkaline Conditions ◽  
X Ray Absorption ◽  
State Of Art

The state-of-art RuO2 catalyst for the oxygen evolution reaction (OER) is measured by using in situ X-ray absorption spectroscopy (XAS) to elucidate the structural transformation during catalyzing the reaction in acidic and alkaline conditions.

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