X-Ray Diffraction and Mössbauer Spectroscopy Studies of Pressure-Induced Phase Transitions in a Mixed-Valence Trinuclear Iron Complex

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Solveig R. Madsen ◽  
Haraldur P. Gunnlaugsson ◽  
Stephen A. Moggach ◽  
Espen Eikeland ◽  
Lai-Chin Wu ◽  
...  
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K.A Azez ◽  
S.H Mahmood ◽  
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Lawrence H. Bowen ◽  
Sheila W. Hedges ◽  
Robert D. Bereman ◽  
Charles T. Vance

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2015 ◽  
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Elżbieta Jartych ◽  
Ludmila M. Kubalova ◽  
Victoria I. Fadeeva

Abstract In this work, the process of formation of metastable phases was investigated for the Fe75B25 composition. Mechanical synthesis was performed in a MAPF-2M high-energy planetary ball mill under an argon atmosphere. X-ray diffraction (XRD), differential scanning calorimetry (DSC), and Mössbauer spectroscopy (MS) were applied to recognize the phases. After 6 h of milling, the material consisted of two phases, that is, metastable tetragonal t-Fe2B and amorphous phases. During further thermal processing, the metastable phase was transformed into the stable Fe2B phase.


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