A Luminescent Metal-Organic Framework Thermometer with Intrinsic Dual Emission from Organic Lumophores

2016 ◽  
Vol 22 (13) ◽  
pp. 4460-4468 ◽  
Author(s):  
Hao Zhang ◽  
Chensheng Lin ◽  
Tianlu Sheng ◽  
Shengmin Hu ◽  
Chao Zhuo ◽  
...  
2021 ◽  
Author(s):  
Kang Wang ◽  
Yuhan Duan ◽  
Jiajing Chen ◽  
Haiying Wang ◽  
Hui-Yan Liu

Self-assembly of two Zn-MOFs, [Zn2L(DMF)3]•H2O•5DMF (1) and [Zn2L(H2O)2]•4H2O•3DMF (2) were achieved with an amide-functionalized tetracarboxylate ligand under similar conditions. Incorporated amide groups make the tetratopic linkers exhibit different configurations, tetrahedron...


RSC Advances ◽  
2020 ◽  
Vol 10 (42) ◽  
pp. 24764-24771
Author(s):  
Yu Wei ◽  
Yan Xia

A dual emission metal–organic framework (IRMOF-10-Eu) was prepared and used as a ratiometric fluorescent sensor for CO32− detection.


2012 ◽  
Vol 24 (10) ◽  
pp. 1954-1960 ◽  
Author(s):  
Yu Liu ◽  
Mei Pan ◽  
Qing-Yuan Yang ◽  
Lei Fu ◽  
Kang Li ◽  
...  

2020 ◽  
Vol 49 (25) ◽  
pp. 8684-8692 ◽  
Author(s):  
Rana Dalapati ◽  
Soutick Nandi ◽  
Shyam Biswas

A post-synthetically modified chemodosimeter grafted MOF is presented for the selective, visual and fluorogenic detection of cyanide via dual emission.


2011 ◽  
Vol 40 (26) ◽  
pp. 6952 ◽  
Author(s):  
Rupam Sen ◽  
Subratanath Koner ◽  
Ashis Bhattacharjee ◽  
Joachim Kusz ◽  
Yoshitaro Miyashita ◽  
...  

Molecules ◽  
2020 ◽  
Vol 25 (3) ◽  
pp. 523 ◽  
Author(s):  
Despoina Andriotou ◽  
Stavros A. Diamantis ◽  
Anna Zacharia ◽  
Grigorios Itskos ◽  
Nikos Panagiotou ◽  
...  

In this study, we report the luminescence color tuning in the lanthanide metal-organic framework (LnMOF) ([La(bpdc)Cl(DMF)] (1); bpdc2− = [1,1′-biphenyl]-4,4′-dicarboxylate, DMF = N,N-dimethylformamide) by introducing dual emission properties in a La3+ MOF scaffold through doping with the blue fluorescent 2,2′-diamino-[1,1′-biphenyl]-4,4′-dicarboxylate (dabpdc2−) and the red emissive Eu3+. With a careful adjustment of the relative doping levels of the lanthanide ions and bridging ligands, the color of the luminescence was modulated, while at the same time the photophysical characteristics of the two chromophores were retained. In addition, the photophysical properties of the parent MOF (1) and its doped counterparts with various dabpdc2−/bpdc2− and Eu3+/La3+ ratios and the photoinduced energy transfer pathways that are possible within these materials are discussed. Finally, the temperature dependence study on the emission profile of a doped analogue containing 10% dabpdc2− and 2.5% Eu3+ (7) is presented, highlighting the potential of this family of materials to behave as temperature sensors.


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