Unmasking the Action of Phosphinous Acid Ligands in Nitrile Hydration Reactions Catalyzed by Arene-Ruthenium(II) Complexes

2015 ◽  
Vol 21 (47) ◽  
pp. 16874-16886 ◽  
Author(s):  
Eder Tomás-Mendivil ◽  
Victorio Cadierno ◽  
María I. Menéndez ◽  
Ramón López
Keyword(s):  
Phosphinous Acid ◽  
Nitrile Hydration

Bis(allyl)-ruthenium(iv) complexes with phosphinous acid ligands as catalysts for nitrile hydration reactions

2016 ◽  
Vol 45 (34) ◽  
pp. 13590-13603 ◽  
Author(s):  
Eder Tomás-Mendivil ◽  
Javier Francos ◽  
Rebeca González-Fernández ◽  
Pedro J. González-Liste ◽  
Javier Borge ◽  
...  
Keyword(s):  
Phosphinous Acid ◽  
Nitrile Hydration

The preparation of bis(allyl)-Ru(iv) complexes with phosphinous acid ligands is presented, as well as their application as catalysts in the base-free hydration of organonitriles in water.

scholarly journals Arene-Osmium(II) Complexes in Homogeneous Catalysis

Inorganics ◽  
2021 ◽  
Vol 9 (7) ◽  
pp. 55
Author(s):  
Pascale Crochet ◽  
Victorio Cadierno
Keyword(s):  
Homogeneous Catalysis ◽  
Review Article ◽  
Transfer Hydrogenation ◽  
Nitrile Hydration ◽  
Bond Forming ◽  
Catalytic Applications

Although the application of arene-osmium(II) complexes in homogeneous catalysis has been much less studied than that of their ruthenium analogues, different works have shown that, in some instances, a comparable or even superior effectiveness can be achieved with this particular class of compounds. This review article focuses on the catalytic applications of arene-osmium(II) complexes. Among others, transfer hydrogenation, hydrogenation, oxidation, and nitrile hydration reactions, as well as different C-C bond forming processes, are comprehensively discussed.

Nitrile Hydration by Co(III) Complex with Oxygenated S Atoms Inserted into Mesoporous Silica

2011 ◽  
Vol 50 ◽  
pp. 01AJ04 ◽  
Author(s):  
Tomohiro Ozawa ◽  
Tomonori Shibayama ◽  
Takuma Yano ◽  
Yasuhiro Funahashi ◽  
Hideki Masuda
Keyword(s):  
Mesoporous Silica ◽  
Nitrile Hydration

Arene−Ruthenium(II) Complexes Containing Amino−Phosphine Ligands as Catalysts for Nitrile Hydration Reactions

2010 ◽  
Vol 29 (17) ◽  
pp. 3955-3965 ◽  
Author(s):  
Rocío García-Álvarez ◽  
Josefina Díez ◽  
Pascale Crochet ◽  
Victorio Cadierno
Keyword(s):  
Phosphine Ligands ◽  
Nitrile Hydration
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