Synthesis of Silaphenalenes by Ruthenium-Catalyzed Annulation between 1-Naphthylsilanes and Internal Alkynes through CH Bond Cleavage

2015 ◽  
Vol 21 (38) ◽  
pp. 13229-13232 ◽  
Author(s):  
Yuichiro Tokoro ◽  
Kengo Sugita ◽  
Shin-ichi Fukuzawa
Keyword(s):  
Bond Cleavage ◽  
Internal Alkynes

ChemInform Abstract: Copper(II)-Catalyzed Carbon-Carbon Triple Bond Cleavage of Internal Alkynes for the Synthesis of Annulated Indolizines.

ChemInform ◽  
2014 ◽  
Vol 45 (39) ◽  
pp. no-no
Author(s):  
Jinwei Sun ◽  
Fuyao Wang ◽  
Huayou Hu ◽  
Xiangshan Wang ◽  
Hui Wu ◽  
...  
Keyword(s):  
Triple Bond ◽  
Bond Cleavage ◽  
Internal Alkynes

Rhodium-catalyzed oxidative coupling of aromatic imines with internal alkynes via regioselective C–H bond cleavage

2009 ◽  
pp. 5141 ◽  
Author(s):  
Tatsuya Fukutani ◽  
Nobuyoshi Umeda ◽  
Koji Hirano ◽  
Tetsuya Satoh ◽  
Masahiro Miura
Keyword(s):  
Oxidative Coupling ◽  
Bond Cleavage ◽  
Internal Alkynes ◽  
Aromatic Imines

Copper(II)-Catalyzed Carbon–Carbon Triple Bond Cleavage of Internal Alkynes for the Synthesis of Annulated Indolizines

2014 ◽  
Vol 79 (9) ◽  
pp. 3992-3998 ◽  
Author(s):  
Jinwei Sun ◽  
Fuyao Wang ◽  
Huayou Hu ◽  
Xiangshan Wang ◽  
Hui Wu ◽  
...  
Keyword(s):  
Triple Bond ◽  
Bond Cleavage ◽  
Internal Alkynes

Multifunctional P-ligand-controlled “silicon-centered” selectivity in Rh/Cu-catalyzed Si–C bond cleavage of silacyclobutanes

2021 ◽  
Author(s):  
Xu Wang ◽  
Shuai-Shuai Huang ◽  
Feng-Jiao Zhang ◽  
Jia-Le Xie ◽  
Zhao Li ◽  
...  
Keyword(s):  
Bond Cleavage ◽  
Internal Alkynes ◽  
Cyclohexene Derivatives

A newly developed Ar-BINMOL-Phos-controlled Rh/Cu-catalyzed (4+2) annulation of silacylcobutanes with arylpropiolate-type internal alkynes gave silicon-stereogenic 1-sila-2-cyclohexene derivatives with good ee and excellent chemoselectivity.

ChemInform Abstract: Rhodium-Catalyzed Oxidative Coupling of Aromatic Imines with Internal Alkynes via Regioselective C—H Bond Cleavage.

ChemInform ◽  
2010 ◽  
Vol 41 (2) ◽  
Author(s):  
Tatsuya Fukutani ◽  
Nobuyoshi Umeda ◽  
Koji Hirano ◽  
Tetsuya Satoh ◽  
Masahiro Miura
Keyword(s):  
Oxidative Coupling ◽  
Bond Cleavage ◽  
Internal Alkynes ◽  
Aromatic Imines
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