Diacetylenes with Ionic-Liquid-Like Substituents: Associating a Polymerizing Cation with a Polymerizing Anion in a Single Precursor for the Synthesis of N-Doped Carbon Materials

2015 ◽  
Vol 22 (5) ◽  
pp. 1682-1695 ◽  
Author(s):  
Karim Fahsi ◽  
Xavier Dumail ◽  
Sylvain G. Dutremez ◽  
Arie van der Lee ◽  
André Vioux ◽  
...  
2020 ◽  
Vol 7 (21) ◽  
pp. 4440-4440
Author(s):  
Janine Carvalho Padilha ◽  
Jean‐Marc Noël ◽  
Jean‐Franҫois Bergamini ◽  
Joёlle Rault‐Berthelot ◽  
Corinne Lagrost

2016 ◽  
Vol 163 (7) ◽  
pp. A1317-A1325 ◽  
Author(s):  
E. Tee ◽  
I. Tallo ◽  
T. Thomberg ◽  
A. Jänes ◽  
E. Lust

2017 ◽  
Vol 189 ◽  
pp. 107-109 ◽  
Author(s):  
Li Sun ◽  
Hua Zhou ◽  
Yonghong Li ◽  
Fang Yu ◽  
Chengli Zhang ◽  
...  

2010 ◽  
Vol 20 (32) ◽  
pp. 6746 ◽  
Author(s):  
Jens Peter Paraknowitsch ◽  
Arne Thomas ◽  
Markus Antonietti

Catalysts ◽  
2019 ◽  
Vol 9 (12) ◽  
pp. 973 ◽  
Author(s):  
Mónica Rufete-Beneite ◽  
M. Carmen Román-Martínez

Monitoring hydrogen consumption has allowed studying the progress of the liquid phase hydrogenation of cyclohexene in toluene with Rh SILP (supported ionic liquid phase) catalysts prepared by the immobilization of the [{RhCl(cod)}2] complex on different carbon materials. An excess of hydrogen consumption with respect to the required amount for cyclohexene hydrogenation was registered and related with the solvent (toluene) hydrogenation. The study carried out led to unraveling the extent of toluene hydrogenation and to determining if the rate of this reaction is affected by the properties of the carbon material used as support. The results revealed that the Rh SILP catalysts we prepared showed acceptable toluene conversion, with 100% selectivity to the total hydrogenated product, and that the effect of the carbon support is the same as for cyclohexene hydrogenation.


2012 ◽  
Vol 213 (10-11) ◽  
pp. 1132-1145 ◽  
Author(s):  
Jens Peter Paraknowitsch ◽  
Arne Thomas

2017 ◽  
Vol 53 (36) ◽  
pp. 4915-4918 ◽  
Author(s):  
Xili Cui ◽  
Qiwei Yang ◽  
Yijun Xiong ◽  
Zongbi Bao ◽  
Huabin Xing ◽  
...  

A facile and efficient method for the synthesis of carbon materials with uniform channels and a high-nitrogen-content coating layer was successfully developed through a polymer–ionic liquid assembly strategy.


2018 ◽  
Author(s):  
Trinidad Mendez-Morales ◽  
Nidhal Ganfoud ◽  
Zhujie Li ◽  
Matthieu Haefele ◽  
Benjamin Rotenberg ◽  
...  

Over the past decades, the specific surface area and the pore size distribution have been identified as the main structural features that govern the performance of carbon-based supercapacitors. As a consequence, graphene nanostructures have been identified as strong candidates for maximizing their capacitance. However, this hypothesis could not be thoroughly tested so far due to the difficulty of synthesizing perfect materials with high pore accesibility and a sufficiently large density. Here we perform molecular simulations of a series of perforated graphene electrodes with single pore sizes ranging from 7 to 10 Angstroms in contact with an adsorbed ionic liquid, and compare the capacitances (using various metrics) to the one obtained with a typical disordered nanoporous carbon. The latter displays better performances, an observation that we explain by analyzing the structure of the liquid inside the pores. It appears that although the smaller pores are responsible for the largest surface charges, larger ones are also necessary to store the counter-ions and avoid the formation of detrimental opposite charges on the carbon. These results rationalize the need for disordered or activated carbon materials to design efficient supercapacitors.


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