Water Oxidation Catalysis by Synthetic Manganese Oxides with Different Structural Motifs: A Comparative Study

2015 ◽  
Vol 21 (42) ◽  
pp. 14958-14968 ◽  
Author(s):  
Carolin E. Frey ◽  
Philipp Kurz
2016 ◽  
Vol 4 (22) ◽  
pp. 8812-8821 ◽  
Author(s):  
Gökhan Elmacı ◽  
Carolin E. Frey ◽  
Philipp Kurz ◽  
Birgül Zümreoğlu-Karan

A first comparative study on 1D-, 2D- and 3D-manganese oxides supported by iron oxide nanoparticles for use as water oxidation catalysts is presented.


2014 ◽  
Vol 7 (7) ◽  
pp. 2203 ◽  
Author(s):  
M. Wiechen ◽  
M. M. Najafpour ◽  
S. I. Allakhverdiev ◽  
L. Spiccia

Author(s):  
Ravneet K. Bhullar ◽  
Michael J. Zdilla ◽  
Michael L. Klein ◽  
Richard C. Remsing

Reacting out of frustration: unlike buserite, the nanoconfined interlayer of birnessite results in geometric frustration of water molecules, which decreases the Marcus reorganization energy of electron transfer and enhances water oxidation catalysis.


2016 ◽  
Vol 9 (7) ◽  
pp. 2433-2443 ◽  
Author(s):  
I. Zaharieva ◽  
D. González-Flores ◽  
B. Asfari ◽  
C. Pasquini ◽  
M. R. Mohammadi ◽  
...  

Water oxidation is pivotal in biological photosynthesis, where it is catalyzed by a protein-bound metal complex with a Mn4Ca-oxide core; related synthetic catalysts may become key components in non-fossil fuel technologies.


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