scholarly journals β-Hydrogen Elimination Reactions of Nickel and Palladium Methoxides Stabilised by PCP Pincer Ligands

2015 ◽  
Vol 21 (27) ◽  
pp. 9833-9849 ◽  
Author(s):  
Luis M. Martínez-Prieto ◽  
Elena Ávila ◽  
Pilar Palma ◽  
Eleuterio Álvarez ◽  
Juan Cámpora
Keyword(s):  
Pincer Ligands ◽  
Hydrogen Elimination ◽  
Elimination Reactions ◽  
Pcp Pincer

Successive hydrogen-elimination reactions with low activation energies in thea-Si:H formation process: Anab initiomolecular-orbital study

1992 ◽  
Vol 46 (3) ◽  
pp. 1913-1916 ◽  
Author(s):  
Kota Sato ◽  
Yoko Sugiyama ◽  
Akihiko Uchiyama ◽  
Susumu Iwabuchi ◽  
Tsuneo Hirano ◽  
...  
Keyword(s):  
Formation Process ◽  
Activation Energies ◽  
Hydrogen Elimination ◽  
Orbital Study ◽  
Elimination Reactions

scholarly journals Development of the First P-Stereogenic PCP Pincer Ligands, Their Metallation by Palladium and Platinum, and Preliminary Catalysis

2001 ◽  
Vol 84 (11) ◽  
pp. 3519-3530 ◽  
Author(s):  
B. Scott Williams ◽  
Paulo Dani ◽  
Martin Lutz ◽  
Anthony L. Spek ◽  
Gerard van Koten
Keyword(s):  
Pincer Ligands ◽  
Pcp Pincer

Hydrogen elimination reactions in the thermal decomposition of alcohols on Si(100) surfaces

2003 ◽  
Vol 21 (3) ◽  
pp. 740-744 ◽  
Author(s):  
Won J. Yoon ◽  
Jae P. Lee ◽  
Gyoosoon Park ◽  
Chan R. Park ◽  
Hyon T. Kwak ◽  
...  
Keyword(s):  
Thermal Decomposition ◽  
Hydrogen Elimination ◽  
Elimination Reactions

Missing link: PCP pincer ligands containing P–N bonds and their Pd complexes

2006 ◽  
Vol 691 (22) ◽  
pp. 4802-4806 ◽  
Author(s):  
Oleg V. Ozerov ◽  
Chengyun Guo ◽  
Bruce M. Foxman
Keyword(s):  
Pincer Ligands ◽  
Missing Link ◽  
Pcp Pincer ◽  
Pd Complexes

Synthesis and Catalytic Properties of Di- and Trinuclear Palladium Complexes with PCP-Pincer Ligands

2003 ◽  
Vol 39 (9) ◽  
pp. 1268-1281 ◽  
Author(s):  
I. P. Beletskaya ◽  
A. V. Chuchuryukin ◽  
G. van Koten ◽  
H. P. Dijkstra ◽  
G. P. M. van Klink ◽  
...  
Keyword(s):  
Catalytic Properties ◽  
Palladium Complexes ◽  
Pincer Ligands ◽  
Pcp Pincer

Structure and Reactivity of Rhodium(I) Complexes Based on Electron-Withdrawing Pyrrolyl-PCP-Pincer Ligands

2009 ◽  
Vol 28 (2) ◽  
pp. 523-533 ◽  
Author(s):  
Elizaveta Kossoy ◽  
Boris Rybtchinski ◽  
Yael Diskin-Posner ◽  
Linda J. W. Shimon ◽  
Gregory Leitus ◽  
...  
Keyword(s):  
Pincer Ligands ◽  
Pcp Pincer

Photolysis (A = 185 nm) of Liquid Acetaldehyde Dimethyl Acetal

1977 ◽  
Vol 32 (2) ◽  
pp. 205-208 ◽  
Author(s):  
Heinz-Peter Schuchmann ◽  
Clemens Von Sonntag
Keyword(s):  
Vinyl Ether ◽  
Methyl Ether ◽  
Methyl Formate ◽  
Dimethyl Acetal ◽  
Quantum Yields ◽  
Methyl Vinyl ◽  
Ethyl Methyl ◽  
Hydrogen Elimination ◽  
Elimination Reactions ◽  
Methyl Vinyl Ether

Deaerated liquid acetaldehyde dimethyl acetal has been photolyzed at λ = 185 nm, and 28 products have been determined. The major ones with their quantum yields are: methanol (0.59), methane (0.26), ethyl methyl ether (0.17), methyl vinyl ether (0.16), methyl formate (0.14), ketene dimethyl acetal (0.1), ethane (0.06), hydrogen (0.06), and acetaldehyde (0.06).The major primary processes are suggested to be the scission of the C-OCH3 bonds (homolytic and molecular) and of the O-CH3 bonds (homolytic). Minor processes are hydrogen elimination reactions and the scission of the C-CH3 bond.

Novel unsymmetrical PCP′ pincer ligands and their palladium(II) complexes

2003 ◽  
Vol 687 (1) ◽  
pp. 185-189 ◽  
Author(s):  
Michael R Eberhard ◽  
Shiro Matsukawa ◽  
Yohsuke Yamamoto ◽  
Craig M Jensen
Keyword(s):  
Pincer Ligands ◽  
Pcp Pincer
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