Photochemically Engineering the Metal-Semiconductor Interface for Room-Temperature Transfer Hydrogenation of Nitroarenes with Formic Acid

2014 ◽  
Vol 20 (50) ◽  
pp. 16732-16737 ◽  
Author(s):  
Xin-Hao Li ◽  
Yi-Yu Cai ◽  
Ling-Hong Gong ◽  
Wei Fu ◽  
Kai-Xue Wang ◽  
...  
Keyword(s):  
Formic Acid ◽  
Room Temperature ◽  
Transfer Hydrogenation ◽  
Semiconductor Interface

High catalytic activity of a bimetallic AgPd alloy supported on UiO-66 derived porous carbon for transfer hydrogenation of nitroarenes using formic acid-formate as the hydrogen source

2017 ◽  
Vol 41 (18) ◽  
pp. 9857-9865 ◽  
Author(s):  
Saisai Cheng ◽  
Ningzhao Shang ◽  
Xin Zhou ◽  
Cheng Feng ◽  
Shutao Gao ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Formic Acid ◽  
Porous Carbon ◽  
Room Temperature ◽  
Transfer Hydrogenation ◽  
High Catalytic Activity

The Ag1Pd9@NPC-UiO-66 catalyst was fabricated and exhibited extraordinary catalytic activity toward the hydrogenation of nitroarenes to anilines at room temperature.

Room-temperature transfer hydrogenation and fast separation of unsaturated compounds over heterogeneous catalysts in an aqueous solution of formic acid

2014 ◽  
Vol 16 (8) ◽  
pp. 3746-3751 ◽  
Author(s):  
Ling-Hong Gong ◽  
Yi-Yu Cai ◽  
Xin-Hao Li ◽  
Ya-Nan Zhang ◽  
Juan Su ◽  
...  
Keyword(s):  
Aqueous Solution ◽  
Formic Acid ◽  
Room Temperature ◽  
Heterogeneous Catalysts ◽  
Transfer Hydrogenation ◽  
Unsaturated Compounds ◽  
Fast Separation

Transfer hydrogenation of unsaturated compounds can be conducted over Pd/CN catalysts at room temperature in an aqueous solution of formic acid.

scholarly journals A Process for Hydrogen Production from the Catalytic Decomposition of Formic Acid over Iridium—Palladium Nanoparticles

Materials ◽  
2021 ◽  
Vol 14 (12) ◽  
pp. 3258
Author(s):  
Hamed M. Alshammari ◽  
Mohammad Hayal Alotaibi ◽  
Obaid F. Aldosari ◽  
Abdulellah S. Alsolami ◽  
Nuha A. Alotaibi ◽  
...  
Keyword(s):  
Hydrogen Production ◽  
Formic Acid ◽  
Activated Charcoal ◽  
Palladium Nanoparticles ◽  
Room Temperature ◽  
Catalytic Decomposition ◽  
Conversion Yield ◽  
Production Of Hydrogen ◽  
Commercial Applications

The present study investigates a process for the selective production of hydrogen from the catalytic decomposition of formic acid in the presence of iridium and iridium–palladium nanoparticles under various conditions. It was found that a loading of 1 wt.% of 2% palladium in the presence of 1% iridium over activated charcoal led to a 43% conversion of formic acid to hydrogen at room temperature after 4 h. Increasing the temperature to 60 °C led to further decomposition and an improvement in conversion yield to 63%. Dilution of formic acid from 0.5 to 0.2 M improved the decomposition, reaching conversion to 81%. The reported process could potentially be used in commercial applications.

Sustainable Isomerization of α‐Pinene Oxide to trans ‐Carveol using Formic Acid/Aniline System at Room Temperature

2021 ◽  
pp. 2000212
Author(s):  
Krishnan Ravi ◽  
Dhanaji R. Naikwadi ◽  
Balasaheb D. Bankar ◽  
Ankush V. Biradar
Keyword(s):  
Formic Acid ◽  
Room Temperature

A Ag–Pd alloy supported on an amine-functionalized UiO-66 as an efficient synergetic catalyst for the dehydrogenation of formic acid at room temperature

2016 ◽  
Vol 6 (3) ◽  
pp. 869-874 ◽  
Author(s):  
Shu-Tao Gao ◽  
Weihua Liu ◽  
Cheng Feng ◽  
Ning-Zhao Shang ◽  
Chun Wang
Keyword(s):  
Catalytic Activity ◽  
Formic Acid ◽  
Room Temperature ◽  
High Catalytic Activity ◽  
Amine Functionalized ◽  
Pd Alloy

Ag–Pd alloys deposited on an amine-functionalized UiO-66(NH2–UiO-66) have been successfully prepared via a pre-coordination method and used as a AgPd@NH2–UiO-66 catalyst with 100% H2 selectivity and a high catalytic activity.

scholarly journals Correction: Room temperature iron catalyzed transfer hydrogenation using n-butanol and poly(methylhydrosiloxane)

2021 ◽  
Author(s):  
Thomas G. Linford-Wood ◽  
Nathan T. Coles ◽  
Ruth L. Webster
Keyword(s):  
Room Temperature ◽  
Transfer Hydrogenation

Correction for ‘Room temperature iron catalyzed transfer hydrogenation using n-butanol and poly(methylhydrosiloxane)’ by Thomas G. Linford-Wood et al., Green Chem., 2021, 23, 2703–2709, DOI: 10.1039/D0GC04175K.

Versatile Rh- and Ir-Based Catalysts for CO2 Hydrogenation, Formic Acid Dehydrogenation, and Transfer Hydrogenation of Quinolines

2018 ◽  
Vol 57 (22) ◽  
pp. 14186-14198 ◽  
Author(s):  
Jairo Fidalgo ◽  
Margarita Ruiz-Castañeda ◽  
Gabriel García-Herbosa ◽  
Arancha Carbayo ◽  
Félix A. Jalón ◽  
...  
Keyword(s):  
Formic Acid ◽  
Co2 Hydrogenation ◽  
Transfer Hydrogenation ◽  
Formic Acid Dehydrogenation

Hydrogen production from formic acid decomposition at room temperature using a Ag–Pd core–shell nanocatalyst

2011 ◽  
Vol 6 (5) ◽  
pp. 302-307 ◽  
Author(s):  
Karaked Tedsree ◽  
Tong Li ◽  
Simon Jones ◽  
Chun Wong Aaron Chan ◽  
Kai Man Kerry Yu ◽  
...  
Keyword(s):  
Hydrogen Production ◽  
Formic Acid ◽  
Room Temperature ◽  
Core Shell ◽  
Acid Decomposition ◽  
Formic Acid Decomposition
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