scholarly journals The First One-Pot Synthesis of Metal-Organic Frameworks Functionalised with Two Transition-Metal Complexes

2014 ◽  
Vol 21 (2) ◽  
pp. 861-866 ◽  
Author(s):  
Ana E. Platero-Prats ◽  
Antonio Bermejo Gómez ◽  
Louise Samain ◽  
Xiaodong Zou ◽  
Belén Martín-Matute
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Metal Organic Frameworks ◽  
One Pot ◽  
One Pot Synthesis ◽  
Metal Organic

scholarly journals X-ray crystallographic insights into post-synthetic metalation products in a metal–organic framework

2017 ◽  
Vol 375 (2084) ◽  
pp. 20160028 ◽  
Author(s):  
Michael T. Huxley ◽  
Campbell J. Coghlan ◽  
Witold M. Bloch ◽  
Alexandre Burgun ◽  
Christian J. Doonan ◽  
...  
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Coordination Sphere ◽  
Metal Organic Frameworks ◽  
Void Space ◽  
X Ray ◽  
X Ray Crystallography ◽  
Metal Nitrates ◽  
Metal Organic

Post-synthetic modification of metal–organic frameworks (MOFs) facilitates a strategic transformation of potentially inert frameworks into functionalized materials, tailoring them for specific applications. In particular, the post-synthetic incorporation of transition-metal complexes within MOFs, a process known as ‘metalation’, is a particularly promising avenue towards functionalizing MOFs. Herein, we describe the post-synthetic metalation of a microporous MOF with various transition-metal nitrates. The parent framework, 1 , contains free-nitrogen donor chelation sites, which readily coordinate metal complexes in a single-crystal to single-crystal transformation which, remarkably, can be readily monitored by X-ray crystallography. The presence of an open void surrounding the chelation site in 1 prompted us to investigate the effect of the MOF pore environment on included metal complexes, particularly examining whether void space would induce changes in the coordination sphere of chelated complexes reminiscent of those found in the solution state. To test this hypothesis, we systematically metalated 1 with first-row transition-metal nitrates and elucidated the coordination environment of the respective transition-metal complexes using X-ray crystallography. Comparison of the coordination sphere parameters of coordinated transition-metal complexes in 1 against equivalent solid- and solution-state species suggests that the void space in 1 does not markedly influence the coordination sphere of chelated species but we show notably different post-synthetic metalation outcomes when different solvents are used. This article is part of the themed issue ‘Coordination polymers and metal–organic frameworks: materials by design’.

scholarly journals One-pot Synthesis of Dihydropyrimidinones Using Polyoxometalate Tri-supported Transition Metal Complexes

2011 ◽  
Vol 55 (4) ◽  
pp. 666-672
Author(s):  
Razieh Fazaeli ◽  
Hamid Aliyan ◽  
Foroogh Mohammadifar ◽  
Amir Abbas Zamani ◽  
Mohammad Javad Bagi
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
One Pot ◽  
One Pot Synthesis

One-pot synthesis of binary metal organic frameworks (HKUST-1 and UiO-66) for enhanced adsorptive removal of water contaminants

2017 ◽  
Vol 490 ◽  
pp. 685-694 ◽  
Author(s):  
Muhammad Rizwan Azhar ◽  
Hussein Rasool Abid ◽  
Hongqi Sun ◽  
Vijay Periasamy ◽  
Moses O. Tadé ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
One Pot ◽  
Water Contaminants ◽  
Adsorptive Removal ◽  
Binary Metal ◽  
One Pot Synthesis ◽  
Metal Organic

One-pot synthesis of hierarchical-pore metal–organic frameworks for drug delivery and fluorescent imaging

CrystEngComm ◽  
2018 ◽  
Vol 20 (8) ◽  
pp. 1087-1093 ◽  
Author(s):  
Xuechuan Gao ◽  
Yuewu Wang ◽  
Guanfeng Ji ◽  
Ruixue Cui ◽  
Zhiliang Liu
Keyword(s):  
Drug Delivery ◽  
Metal Organic Frameworks ◽  
Fluorescent Imaging ◽  
One Pot ◽  
One Pot Synthesis ◽  
Drug Molecules ◽  
Metal Organic ◽  
Hierarchical Pore

A one-pot process has been developed for the synthesis of hierarchical-pore metal–organic frameworks, aimed at loading large and small drug molecules simultaneously.

One-pot synthesis of Cu-based metal-organic frameworks for environmental applications

2019 ◽  
Author(s):  
Monika Nehra ◽  
Deepak Kedia ◽  
Neeraj Dilbaghi ◽  
Ashraf Aly Hassan ◽  
Sandeep Kumar
Keyword(s):  
Metal Organic Frameworks ◽  
Environmental Applications ◽  
One Pot ◽  
One Pot Synthesis ◽  
Metal Organic

scholarly journals Cu-metal organic frameworks (Cu-MOF) as an environment-friendly and economical catalyst for one pot synthesis of tacrine derivatives

RSC Advances ◽  
2020 ◽  
Vol 10 (4) ◽  
pp. 1995-2003 ◽  
Author(s):  
Hoda Mollabagher ◽  
Salman Taheri ◽  
Mohammad majid Mojtahedi ◽  
SeyedAmirhossein Seyedmousavi
Keyword(s):  
Catalytic Activity ◽  
Metal Organic Frameworks ◽  
One Pot ◽  
Environment Friendly ◽  
One Pot Synthesis ◽  
Metal Organic ◽  
The One

The present work describes the catalytic activity of Cu-MOF for the one-pot synthesis of tacrine derivatives via a four-component reaction of 2-hydroxynaphthalene-1,4-dione, aldehydes, malononitrile and cycloketones in the presence of AlCl3.

scholarly journals Upcycling a plastic cup: one-pot synthesis of lactate containing metal organic frameworks from polylactic acid

2019 ◽  
Vol 55 (51) ◽  
pp. 7319-7322 ◽  
Author(s):  
Benjamin Slater ◽  
So-On Wong ◽  
Andrew Duckworth ◽  
Andrew J. P. White ◽  
Matthew R. Hill ◽  
...  
Keyword(s):  
Polylactic Acid ◽  
Visual Representation ◽  
Metal Organic Frameworks ◽  
One Pot ◽  
One Pot Synthesis ◽  
Metal Organic

A visual representation of waste PLA being upcycled to a lactate containing MOF, ZnBLD–dPLA.

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