A Systematic Study on the Stability of Porous Coordination Polymers against Ammonia

2014 ◽  
Vol 20 (47) ◽  
pp. 15611-15617 ◽  
Author(s):  
Takashi Kajiwara ◽  
Masakazu Higuchi ◽  
Daisuke Watanabe ◽  
Hideyuki Higashimura ◽  
Teppei Yamada ◽  
...  
2013 ◽  
Vol 3 (2) ◽  
pp. 144-160 ◽  
Author(s):  
Sergey Kolotilov ◽  
Mikhail Kiskin ◽  
Igor Eremenko ◽  
Vladimir Novotortsev

2021 ◽  
Author(s):  
Meng-Hua Li ◽  
Ming-Hua You ◽  
Mei-Jin Lin

The incorporation of photochromic moieties into porous coordination polymers is of particular interest due to it can endow them various switchable functions in the electrical conductivity, luminescence, and magnetism. In...


2021 ◽  
Author(s):  
Yifan Gu ◽  
Jia‐Jia Zheng ◽  
Ken‐ichi Otake ◽  
Mohana Shivanna ◽  
Shigeyoshi Sakaki ◽  
...  

Inorganics ◽  
2021 ◽  
Vol 9 (3) ◽  
pp. 20
Author(s):  
Antonio A. García-Valdivia ◽  
Estitxu Echenique-Errandonea ◽  
Gloria B. Ramírez-Rodríguez ◽  
José M. Delgado-López ◽  
Belén Fernández ◽  
...  

Two new coordination polymers (CPs) based on Zn(II) and Cd(II) and 1H-indazole-6-carboxylic acid (H2L) of general formulae [Zn(L)(H2O)]n (1) and [Cd2(HL)4]n (2) have been synthesized and fully characterized by elemental analyses, Fourier transformed infrared spectroscopy and single crystal X-ray diffraction. The results indicate that compound 1 possesses double chains in its structure whereas 2 exhibits a 3D network. The intermolecular interactions, including hydrogen bonds, C–H···π and π···π stacking interactions, stabilize both crystal structures. Photoluminescence (PL) properties have shown that compounds 1 and 2 present similar emission spectra compared to the free-ligand. The emission spectra are also studied from the theoretical point of view by means of time-dependent density-functional theory (TD-DFT) calculations to confirm that ligand-centred π-π* electronic transitions govern emission of compound 1 and 2. Finally, the PL properties are also studied in aqueous solution to explore the stability and emission capacity of the compounds.


EnergyChem ◽  
2021 ◽  
pp. 100067
Author(s):  
Nibedita Behera ◽  
Jingui Duan ◽  
Wanqin Jin ◽  
Susumu Kitagawa

2015 ◽  
Vol 2 (5) ◽  
pp. 473-476 ◽  
Author(s):  
Yu-ichi Fujiwara ◽  
Satoshi Horike ◽  
Kanokwan Kongpatpanich ◽  
Takashi Sugiyama ◽  
Norio Tobori ◽  
...  

Control of pore distribution of porous carbons from porous coordination polymers.


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