Well-Defined Iron Complexes as Efficient Catalysts for “Green” Atom-Transfer Radical Polymerization of Styrene, Methyl Methacrylate, and Butyl Acrylate with Low Catalyst Loadings and Catalyst Recycling

2014 ◽  
Vol 20 (19) ◽  
pp. 5802-5814 ◽  
Author(s):  
So-ichiro Nakanishi ◽  
Mitsunobu Kawamura ◽  
Hidetomo Kai ◽  
Ren-Hua Jin ◽  
Yusuke Sunada ◽  
...  
Keyword(s):  
Methyl Methacrylate ◽  
Atom Transfer Radical Polymerization ◽  
Radical Polymerization ◽  
Butyl Acrylate ◽  
Iron Complexes ◽  
Atom Transfer ◽  
Catalyst Recycling

The synthesis of bottlebrush cellulose-graft-diblock copolymer elastomers via atom transfer radical polymerization utilizing a halide exchange technique

2019 ◽  
Vol 55 (92) ◽  
pp. 13904-13907 ◽  
Author(s):  
Juan Zhang ◽  
Zhongkai Wang ◽  
Xuehui Wang ◽  
Zhigang Wang
Keyword(s):  
Methyl Methacrylate ◽  
Atom Transfer Radical Polymerization ◽  
Radical Polymerization ◽  
Diblock Copolymer ◽  
Butyl Acrylate ◽  
Atom Transfer ◽  
Backbone Chain ◽  
Halide Exchange ◽  
Copolymer Brushes ◽  
Exchange Technique

A novel kind of bottlebrush cellulose-graft-diblock copolymer elastomer (Cell-g-PBA-b-PMMA) was made with cellulose as the backbone chain and poly(n-butyl acrylate)-block-poly(methyl methacrylate) (PBA-b-PMMA) as the diblock copolymer brushes.

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