Unraveling the Mechanism of Water Oxidation Catalyzed by Nonheme Iron Complexes

2014 ◽  
Vol 20 (19) ◽  
pp. 5696-5707 ◽  
Author(s):  
Ferran Acuña-Parés ◽  
Zoel Codolà ◽  
Miquel Costas ◽  
Josep M. Luis ◽  
Julio Lloret-Fillol
Keyword(s):  
Water Oxidation ◽  
Iron Complexes ◽  
Nonheme Iron

Water Oxidation Catalysis with Nonheme Iron Complexes under Acidic and Basic Conditions: Homogeneous or Heterogeneous?

2013 ◽  
Vol 52 (16) ◽  
pp. 9522-9531 ◽  
Author(s):  
Dachao Hong ◽  
Sukanta Mandal ◽  
Yusuke Yamada ◽  
Yong-Min Lee ◽  
Wonwoo Nam ◽  
...  
Keyword(s):  
Water Oxidation ◽  
Iron Complexes ◽  
Nonheme Iron ◽  
Oxidation Catalysis ◽  
Water Oxidation Catalysis

scholarly journals A Facially Coordinating Tris-Benzimidazole Ligand for Nonheme Iron Enzyme Models

2020 ◽  
Author(s):  
David Lacy ◽  
Parami Gunasekera ◽  
Preshit Abhyankar ◽  
Samantha N. Macmillan
Keyword(s):  
Structural Models ◽  
Iron Complexes ◽  
Nonheme Iron ◽  
Synthesis And Characterization ◽  
Enzyme Models

This work describes the synthesis and characterization of new ligands and iron complexes for mononuclear nonheme iron oxygenase structural models.

Alkane hydroxylation catalyzed by a series of mononuclear nonheme iron complexes containing 4-nitropyridine ligands

2008 ◽  
Vol 288 (1-2) ◽  
pp. 83-86 ◽  
Author(s):  
Yutaka Hitomi ◽  
Shinya Furukawa ◽  
Masakazu Higuchi ◽  
Tetsuya Shishido ◽  
Tsunehiro Tanaka
Keyword(s):  
Iron Complexes ◽  
Nonheme Iron ◽  
Alkane Hydroxylation

Tracking the FeIV(O) intermediate and O–O bond formation of a nonheme iron catalyst for water oxidation

2017 ◽  
Vol 53 (65) ◽  
pp. 9063-9066 ◽  
Author(s):  
Bing Yang ◽  
Qing-Qing Yang ◽  
Xin Jiang ◽  
Bin Chen ◽  
Chen-Ho Tung ◽  
...  
Keyword(s):  
Oxygen Evolution ◽  
Water Oxidation ◽  
Iron Catalyst ◽  
Bond Formation ◽  
Nonheme Iron ◽  
High Valent

We describe here a new complex 1 by subtle modulation of the TPA ligand and succeed in capturing the high-valent FeIV(O) species, which is responsible for the O–O bond formation and oxygen evolution with higher efficiency.

Mononuclear Iron Complexes with Tetraazadentate Ligands as Water Oxidation Catalysts

2016 ◽  
Vol 2016 (20) ◽  
pp. 3262-3268 ◽  
Author(s):  
Gayatri Panchbhai ◽  
Wangkheimayum Marjit Singh ◽  
Biswanath Das ◽  
Reuben T. Jane ◽  
Anders Thapper
Keyword(s):  
Water Oxidation ◽  
Iron Complexes ◽  
Oxidation Catalysts ◽  
Mononuclear Iron

Computational analysis of site differences in selective aliphatic C–H hydroxylation by nonheme iron–oxo complexes

2017 ◽  
Vol 19 (21) ◽  
pp. 13924-13930 ◽  
Author(s):  
Jian Wang ◽  
Yuan-yuan Zhao ◽  
Po-Heng Lee
Keyword(s):  
Computational Analysis ◽  
Iron Complexes ◽  
Nonheme Iron ◽  
Oxo Complexes

The CH3CN-solvent influences selective C–H hydroxylation by nonheme iron complexes due to interactions in the H-bonding formation in H-abstraction.

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