Aggregation and Cooperative Effects in the Aldol Reactions of Lithium Enolates

Olatz Larrañaga; Abel de Cózar; F. Matthias Bickelhaupt; Ronen Zangi; Fernando P. Cossío

doi:10.1002/chem.201301597

Aggregation and Cooperative Effects in the Aldol Reactions of Lithium Enolates

Chemistry - A European Journal ◽

10.1002/chem.201301597 ◽

2013 ◽

Vol 19 (41) ◽

pp. 13761-13773 ◽

Cited By ~ 14

Author(s):

Olatz Larrañaga ◽

Abel de Cózar ◽

F. Matthias Bickelhaupt ◽

Ronen Zangi ◽

Fernando P. Cossío

Keyword(s):

Aldol Reactions ◽

Cooperative Effects ◽

Lithium Enolates

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Double stereodifferentiating aldol reactions of (E) and (Z) lithium enolates. Model reactions for polypropionate assemblage

Tetrahedron Letters ◽

10.1016/0040-4039(96)00178-5 ◽

1996 ◽

Vol 37 (12) ◽

pp. 1957-1960 ◽

Cited By ~ 17

Author(s):

David A. Evans ◽

Michael G. Yang ◽

Michael J. Dart ◽

Joseph L. Duffy

Keyword(s):

Aldol Reactions ◽

Lithium Enolates ◽

Model Reactions

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Experimental Evidence for Chair-Like Transition States in Aldol Reactions of Methyl Ketone Lithium Enolates: Stereoselective Synthesis and Utilization of a Deuterium-Labeled Enolate as a Probe of Reaction Stereochemistry

Journal of the American Chemical Society ◽

10.1021/ja050730c ◽

2005 ◽

Vol 127 (16) ◽

pp. 5770-5771 ◽

Cited By ~ 14

Author(s):

Christopher M. Liu ◽

William J. Smith ◽

Darin J. Gustin ◽

William R. Roush

Keyword(s):

Experimental Evidence ◽

Methyl Ketone ◽

Stereoselective Synthesis ◽

Transition States ◽

Aldol Reactions ◽

Lithium Enolates

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α′-Benzoyloxy and α′-methoxymethoxy lithium enolates giving opposite diastereofacial selectivities in aldol reactions. Use of (probable) extended chelation for reversal of stereoselectivities

Tetrahedron Letters ◽

10.1016/s0040-4039(00)77578-2 ◽

1993 ◽

Vol 34 (14) ◽

pp. 2221-2224 ◽

Cited By ~ 16

Author(s):

Anusuya Choudhury ◽

Edward R. Thornton

Keyword(s):

Aldol Reactions ◽

Lithium Enolates

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Faculty Opinions recommendation of Molecular basis for redox-Bohr and cooperative effects in cytochrome c3 from Desulfovibrio desulfuricans ATCC 27774: crystallographic and modeling studies of oxidized and reduced high-resolution structures at pH 7.6.

Faculty Opinions – Post-Publication Peer Review of the Biomedical Literature ◽

10.3410/f.1016825.201421 ◽

2003 ◽

Author(s):

Tjerk P. Straatsma

Keyword(s):

High Resolution ◽

Molecular Basis ◽

Desulfovibrio Desulfuricans ◽

Cytochrome C3 ◽

Cooperative Effects ◽

Modeling Studies

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Faculty Opinions recommendation of Catalytic enantio- and diastereoselective aldol reactions of glycine-derived silicon enolate with aldehydes: an efficient approach to the asymmetric synthesis of anti-beta-hydroxy-alpha-amino acid derivatives.

Faculty Opinions – Post-Publication Peer Review of the Biomedical Literature ◽

10.3410/f.1020519.232639 ◽

2004 ◽

Author(s):

Carlos F Barbas

Keyword(s):

Amino Acid ◽

Asymmetric Synthesis ◽

Aldol Reactions ◽

Amino Acid Derivatives ◽

Efficient Approach ◽

Alpha Amino Acid

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Faculty Opinions recommendation of Enantioselective direct intermolecular aldol reactions with enantiotopic group selectivity and dynamic kinetic resolution.

Faculty Opinions – Post-Publication Peer Review of the Biomedical Literature ◽

10.3410/f.1024886.292907 ◽

2005 ◽

Author(s):

Carlos F Barbas

Keyword(s):

Kinetic Resolution ◽

Aldol Reactions ◽

Dynamic Kinetic Resolution

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(S)-5-prolylamide-triazole Organocatalyst for Direct Asymmetric Aldol Reactions

Current Organic Chemistry ◽

10.2174/1385272811317140011 ◽

2013 ◽

Vol 17 (14) ◽

pp. 1563-1568 ◽

Cited By ~ 4

Author(s):

Ling Liu ◽

Min-Na Gao ◽

Yang Li ◽

Zhen Li ◽

Liping Song ◽

...

Keyword(s):

Aldol Reactions ◽

Asymmetric Aldol

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Re-Examination of Proline-Catalyzed Intermolecular Aldol Reactions: An Ab Initio Kinetic Modelling Study

Topics in Catalysis ◽

10.1007/s11244-021-01501-5 ◽

2021 ◽

Author(s):

Li-Juan Yu ◽

Mitchell T. Blyth ◽

Michelle L. Coote

Keyword(s):

Ab Initio ◽

Kinetic Modelling ◽

Aldol Reactions ◽

Modelling Study

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Direct and Enantioselective Aldol Reactions Catalyzed by Chiral Nickel(II) Complexes

Angewandte Chemie International Edition ◽

10.1002/anie.202104352 ◽

2021 ◽

Author(s):

Pedro Romea ◽

Felix Urpi ◽

Gabriel Aullón ◽

Stuart C. D. Kennington ◽

Saul F. Teloxa ◽

...

Keyword(s):

Aldol Reactions

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Cooperative Effects in Switchable Catalysis: Enhancing Double‐Click Reaction Yield of Symmetrical Rotaxanes

Angewandte Chemie International Edition ◽

10.1002/anie.202108269 ◽

2021 ◽

Author(s):

Michael Schmittel ◽

Amit Ghosh ◽

Indrajit Paul

Keyword(s):

Click Reaction ◽

Reaction Yield ◽

Cooperative Effects

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