Atomic Contributions from Spin-Orbit Coupling to29Si NMR Chemical Shifts in Metallasilatrane Complexes

2012 ◽  
Vol 18 (40) ◽  
pp. 12803-12813 ◽  
Author(s):  
Jochen Autschbach ◽  
Kiplangat Sutter ◽  
Lionel A. Truflandier ◽  
Erica Brendler ◽  
Jörg Wagler
Keyword(s):  
Chemical Shifts ◽  
Orbit Coupling ◽  
Spin Orbit Coupling ◽  
Spin Orbit ◽  
Nmr Chemical Shifts

scholarly journals Corrigendum: Atomic Contributions from Spin-Orbit Coupling to29Si NMR Chemical Shifts in Metallasilatrane Complexes

2012 ◽  
Vol 18 (50) ◽  
pp. 15903-15903 ◽  
Author(s):  
Jochen Autschbach ◽  
Kiplangat Sutter ◽  
Lionel A. Truflandier ◽  
Erica Brendler ◽  
Jörg Wagler
Keyword(s):  
Chemical Shifts ◽  
Orbit Coupling ◽  
Spin Orbit Coupling ◽  
Spin Orbit ◽  
Nmr Chemical Shifts

Internuclear distance dependence of the spin–orbit coupling contributions to proton NMR chemical shifts

1998 ◽  
Vol 295 (5-6) ◽  
pp. 455-461 ◽  
Author(s):  
Boris Minaev ◽  
Juha Vaara ◽  
Kenneth Ruud ◽  
Olav Vahtras ◽  
Hans Ågren
Keyword(s):  
Internuclear Distance ◽  
Chemical Shifts ◽  
Proton Nmr ◽  
Orbit Coupling ◽  
Spin Orbit Coupling ◽  
Spin Orbit ◽  
Nmr Chemical Shifts ◽  
Distance Dependence

scholarly journals Observation of chiral surface excitons in a topological insulator Bi2Se3

2019 ◽  
Vol 116 (10) ◽  
pp. 4006-4011 ◽  
Author(s):  
H.-H. Kung ◽  
A. P. Goyal ◽  
D. L. Maslov ◽  
X. Wang ◽  
A. Lee ◽  
...  
Keyword(s):  
Polarized Light ◽  
Orbit Coupling ◽  
Experimental Investigations ◽  
Composite Particles ◽  
Spin Orbit Coupling ◽  
Spin Orbit ◽  
Excitation Energies ◽  
Circularly Polarized Light ◽  
Pl Emission ◽  
Strong Spin

The protected electron states at the boundaries or on the surfaces of topological insulators (TIs) have been the subject of intense theoretical and experimental investigations. Such states are enforced by very strong spin–orbit interaction in solids composed of heavy elements. Here, we study the composite particles—chiral excitons—formed by the Coulomb attraction between electrons and holes residing on the surface of an archetypical 3D TI,Bi2Se3. Photoluminescence (PL) emission arising due to recombination of excitons in conventional semiconductors is usually unpolarized because of scattering by phonons and other degrees of freedom during exciton thermalization. On the contrary, we observe almost perfectly polarization-preserving PL emission from chiral excitons. We demonstrate that the chiral excitons can be optically oriented with circularly polarized light in a broad range of excitation energies, even when the latter deviate from the (apparent) optical band gap by hundreds of millielectronvolts, and that the orientation remains preserved even at room temperature. Based on the dependences of the PL spectra on the energy and polarization of incident photons, we propose that chiral excitons are made from massive holes and massless (Dirac) electrons, both with chiral spin textures enforced by strong spin–orbit coupling. A theoretical model based on this proposal describes quantitatively the experimental observations. The optical orientation of composite particles, the chiral excitons, emerges as a general result of strong spin–orbit coupling in a 2D electron system. Our findings can potentially expand applications of TIs in photonics and optoelectronics.

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