Synthesis of Fe3O4@Phenol Formaldehyde Resin Core-Shell Nanospheres Loaded with Au Nanoparticles as Magnetic FRET Nanoprobes for Detection of Thiols in Living Cells

2011 ◽  
Vol 18 (4) ◽  
pp. 1154-1160 ◽  
Author(s):  
Ping Yang ◽  
Qi-Zhi Xu ◽  
Sheng-Yu Jin ◽  
Yang Zhao ◽  
Yang Lu ◽  
...  
Keyword(s):  
Au Nanoparticles ◽  
Phenol Formaldehyde ◽  
Living Cells ◽  
Phenol Formaldehyde Resin ◽  
Formaldehyde Resin ◽  
Core Shell ◽  
Resin Core

Influence of synthetic conditions on the performance of melamine–phenol–formaldehyde resin microcapsules

2018 ◽  
Vol 31 (2) ◽  
pp. 197-210 ◽  
Author(s):  
Zun-Xiang Hu ◽  
Xiang-Ming Hu ◽  
Wei-Min Cheng ◽  
Wei Lu
Keyword(s):  
Particle Size ◽  
Epoxy Resin ◽  
Phenol Formaldehyde ◽  
Phenol Formaldehyde Resin ◽  
Formaldehyde Resin ◽  
Average Particle ◽  
Mass Ratio ◽  
Shell Mass ◽  
The Core ◽  
Resin Core

Melamine (M), phenol (P) and formaldehyde (F) were used as raw materials to synthesize a melamine–phenol–formaldehyde resin (MPF) which was used as shell material to prepare a self-healing microcapsule with E-51 epoxy resin as the core, via in situ polymerization. Fourier transform infrared spectroscopy, environmental scanning electron microscopy and laser particle size analysis were used to characterize the surface morphology, structure and properties of the microcapsule. The influence of the reaction conditions on the properties of the microcapsule was investigated by orthogonal testing. The mass ratio between the MPF shell and the epoxy resin core was found to be 1.2:1.0, optimum pH for shell formation was found to be 3, the emulsification speed was 800 r/min, the acidification speed was 400 r/min and the acidification temperature was 60°C. Under these conditions, the prepared microcapsules are regular and spherical with a smooth, dense surface and uniform particle size with a normal distribution. The microcapsules remained well dispersed and did not aggregate. The orthogonal test revealed that the average particle size and yield of the microcapsules are mainly determined by the core/shell mass ratio, whereas the reaction temperature had a greater impact on the core content of the microcapsules. Although the best microcapsule samples showed poor anti-permeability in ethanol, they exhibited good thermal, isothermal and storage stabilities. This indicates that they may be stored at a constant temperature.

Purification of water contaminated with heavy metals by example of lead as promising material based on graphene nanostructures

2020 ◽  
pp. 34-43
Author(s):  
N. R. Memetov ◽  
◽  
A. V. Gerasimova ◽  
A. E. Kucherova ◽  
◽  
...  
Keyword(s):  
Adsorption Process ◽  
Phenol Formaldehyde ◽  
Phenol Formaldehyde Resin ◽  
Formaldehyde Resin ◽  
Parameter Estimates ◽  
Maximum Adsorption Capacity ◽  
Ecological Situation ◽  
Characteristic Parameters ◽  
Purification Of Water ◽  
Graphene Nanostructures

The paper evaluates the effectiveness of the use of graphene nanostructures in the purification of lead (II) ions to improve the ecological situation of water bodies. The mechanisms and characteristic parameters of the adsorption process were analyzed using empirical models of isotherms at temperatures of 298, 303, 313 and 323 K, which correspond to the following order (based on the correlation coefficient): Langmuir (0.99) > Temkin (0.97) > Dubinin – Radushkevich (0.90). The maximum adsorption capacity of the material corresponds to the range from 230 to 260 mg/g. We research the equilibrium at the level of thermodynamic parameter estimates, which indicates the spontaneity of the process, the endothermic nature and structure change of graphene modified with phenol-formaldehyde resin during the adsorption of lead (II) ions, leading to an increase in the disorder of the system.

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