Simultaneous End-On/Side-On Coordination Modes of a Diphosphorus Tetrahedral Complex Imposed by Pre-organization of Oligometallic CuI Acceptors

2011 ◽  
Vol 17 (33) ◽  
pp. 9130-9141 ◽  
Author(s):  
Stefan Welsch ◽  
Christophe Lescop ◽  
Gabor Balazs ◽  
Régis Réau ◽  
Manfred Scheer
Keyword(s):  
Tetrahedral Complex ◽  
Coordination Modes

The structure of [Cu(bipy)3][Cu(bipy)(ala)(ClO4)2]ClO4 � a Compound with Two Different Coordination Modes in the same Complex

2008 ◽  
Vol 59 (11) ◽  
Author(s):  
Mircea Braban ◽  
Ionel Haiduc
Keyword(s):  
Solid State ◽  
Chelate Ring ◽  
Octahedral Complex ◽  
State Structure ◽  
Complex Species ◽  
Solid State Structure ◽  
Coordination Modes ◽  
Coordination Center ◽  
Self Assembled ◽  
Chelate Rings

The paper describes the solid state structure of a compound of composition [Cu(bipy)3][Cu(bipy)(ala) (ClO4)2]ClO4, in which both the cation and anion are octahedral complex species with copper(II) as coordination center. The cation contains three chelate rings formed by bipy; the anion contains in the quatorial plane a CuONC2 chelate ring formed by the alaninato ligand and a CuN2C2 chelate ring formed by bipy, with two monodentate perchorato ligands in axial positions completing the six-coordination. In the crystal p-p stackings lead to a supramolecular self-assembled structure.

The versatile coordination chemistry of 1,3-benzenedicarboxylate in the last 20 years: An investigation from the coordination modes to spectroscopic insights

Polyhedron ◽  
2021 ◽  
Vol 198 ◽  
pp. 115068
Author(s):  
Isabelle K.V. Gonçalves ◽  
Willian X.C. Oliveira ◽  
Filipe B. de Almeida ◽  
Maria Vanda Marinho ◽  
Walace D. do Pim ◽  
...  
Keyword(s):  
Coordination Chemistry ◽  
Coordination Modes

Endo- and exohedral chloro-fulleride as η5 ligands: A DFT study on the first-row transition metal complexes

2021 ◽  
Author(s):  
Sebastian Anila ◽  
Cherumuttathu Hariharan Suresh
Keyword(s):  
Transition Metal ◽  
Transition Metals ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Dft Study ◽  
C60 Fullerene ◽  
Ring Fusion ◽  
Coordination Modes

C60 fullerene coordinates to transition metals in η2-fashion through its C-C bond at [6,6] ring fusion whereas other coordination modes η3, η4, η5 and η6 are rarely observed. The coordination...

scholarly journals Copper(ii) complexes of N-propargyl cyclam ligands reveal a range of coordination modes and colours, and unexpected reactivity

2021 ◽  
Author(s):  
Andrew J. Counsell ◽  
Mingfeng Yu ◽  
Mengying Shi ◽  
Angus T. Jones ◽  
James M. Batten ◽  
...  
Keyword(s):  
Enol Ether ◽  
Coordination Modes

Copper(ii) complexes of cyclam ligands with 1, 2, 3 or 4 pendant alkynes have been prepared and characterised crystallographically and spectroscopically. An unexpected hydroalkoxylation reaction is observed, affording an enol ether from the alkyne.

scholarly journals An exhibition of different coordination modes displayed by 2-vinylpyrazine and 2-vinylpyridine at triosmium centres

2017 ◽  
Vol 849-850 ◽  
pp. 80-87 ◽  
Author(s):  
Md. Rafique Al-Mamun ◽  
Shishir Ghosh ◽  
Shariff E. Kabir ◽  
Graeme Hogarth
Keyword(s):  
Coordination Modes

A Range of Nitrato Coordination Modes in NiIIComplexes with the Versatile Ligand 1,8-Bis(2-pyridyl)-3,6-dithiaoctane: Structural, Spectroscopic, Electrochemical, and Theoretical Studies

2015 ◽  
Vol 2015 (20) ◽  
pp. 3307-3316 ◽  
Author(s):  
Vanessa Ramírez-Delgado ◽  
Luis Felipe Hernández-Ayala ◽  
Juan Carlos García-Ramos ◽  
Marcos Flores-Alamo ◽  
Rodrigo Galindo-Murillo ◽  
...  
Keyword(s):  
Theoretical Studies ◽  
Coordination Modes
Sign in / Sign up

Export Citation Format

Share Document