(1-Alkynyl)dicarbonylcyclopentadienyliron Complexes as Electron-Rich Alkynes in Organic Synthesis: BF3-Mediated [2+2] Cycloaddition/Ring-Opening Providing (2-Alkenyl-1-imino)iron Complexes

2011 ◽  
Vol 17 (31) ◽  
pp. 8559-8561 ◽  
Author(s):  
Ryotaro Nakaya ◽  
Shigeo Yasuda ◽  
Hideki Yorimitsu ◽  
Koichiro Oshima
Keyword(s):  
Organic Synthesis ◽  
Ring Opening ◽  
Iron Complexes

Stereospecific Ring‐Opening Metathesis Polymerization of Norbornene Catalyzed by Iron Complexes

2020 ◽  
Author(s):  
Dmitry S. Belov ◽  
Logesh Mathivathanan ◽  
Melanie J. Beazley ◽  
William Blake Martin ◽  
Konstantin V. Bukhryakov
Keyword(s):  
Ring Opening ◽  
Iron Complexes ◽  
Ring Opening Metathesis Polymerization ◽  
Metathesis Polymerization

scholarly journals Cobalt-Catalyzed Multisubstituted Allylation of Chelation-Assisted C-H bond of (Hetero)arenes with Cyclopropenes

2021 ◽  
Author(s):  
Kuppan Ramachandran ◽  
Pazhamalai Anbarasan
Keyword(s):  
Organic Synthesis ◽  
Ring Opening ◽  
Highly Strained

Cyclopropenes are highly strained three-membered carbocycle, which offers unique reactivity in organic synthesis. Herein, Cp*CoIII-catalyzed ring-opening isomerization of cyclopropenes to cobalt vinylcarbene has been utilized for the synthesis of multisubstituted...

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