Cycloheptatrienyl Zirconium Sandwich Complexes with Lewis Basic Phospholyl Ligands (Phosphatrozircenes): Synthesis, Structure, Bonding and Coordination Chemistry

2011 ◽  
Vol 17 (22) ◽  
pp. 6118-6128 ◽  
Author(s):  
Andreas Glöckner ◽  
Thomas Bannenberg ◽  
Susanne Büschel ◽  
Constantin G. Daniliuc ◽  
Peter G. Jones ◽  
...  
Keyword(s):  
Coordination Chemistry ◽  
Sandwich Complexes

scholarly journals Coordination Chemistry of Anticrowns. Synthesis and Structures of Double-Decker Sandwich Complexes of the Three-Mercury Anticrown (o-C6F4Hg)3 with Halide Anions Containing and Not Containing Coordinated Dibromomethane Molecules

2016 ◽  
Vol 35 (13) ◽  
pp. 2197-2206 ◽  
Author(s):  
Kirill I. Tugashov ◽  
Dmitry A. Gribanyov ◽  
Fedor M. Dolgushin ◽  
Alexander F. Smol’yakov ◽  
Alexander S. Peregudov ◽  
...  
Keyword(s):  
Coordination Chemistry ◽  
Sandwich Complexes ◽  
Halide Anions ◽  
Double Decker

Coordination chemistry of mixed M(benzene)(cyclopendadienyl) sandwich complexes: electronic properties and bonding analysis

2016 ◽  
Vol 40 (3) ◽  
pp. 2554-2564 ◽  
Author(s):  
Saber-Mustapha Zendaoui ◽  
Bachir Zouchoune
Keyword(s):  
Coordination Chemistry ◽  
Electronic Properties ◽  
Spin State ◽  
Sandwich Complexes ◽  
Coordination Modes ◽  
Bonding Analysis ◽  
Iron Metal

Various coordination modes are adopted by the benzene and the cyclopentadienyl ring depending on the electron count of the iron metal and the spin state of the complex.

Fine-Tuning Electronic Properties of Luminescent Pt(II) Complexes via Vertex-Differentiated Coordination of Sterically Invariant Carborane-Based Ligands

2018 ◽  
Author(s):  
Kent O. Kirlikovali ◽  
Jonathan C. Axtell ◽  
Kierstyn Anderson ◽  
Peter I. Djurovich ◽  
Arnold L. Rheingold ◽  
...  
Keyword(s):  
Coordination Chemistry ◽  
Metal Complexes ◽  
Electronic Properties ◽  
Fine Tuning ◽  
Fine Tune

We report the synthesis of two isomeric Pt(II) complexes ligated by doubly deprotonated 1,1′-bis(<i>o</i>-carborane) (<b>bc</b>). This work provides a potential route to fine-tune the electronic properties of luminescent metal complexes by virtue of vertex-differentiated coordination chemistry of carborane-based ligands.

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