Solution-Processable Flower-Shaped Hierarchical Structures: Self-Assembly, Formation, and State Transition of Biomimetic Superhydrophobic Surfaces

2010 ◽  
Vol 16 (24) ◽  
pp. 7309-7318 ◽  
Author(s):  
Jie Yin ◽  
Jing Yan ◽  
Min He ◽  
Yanlin Song ◽  
Xiaoguang Xu ◽  
...  
Keyword(s):  
Self Assembly ◽  
State Transition ◽  
Hierarchical Structures ◽  
Superhydrophobic Surfaces ◽  
Solution Processable

Biomimetic materials: An introduction

1992 ◽  
Vol 50 (2) ◽  
pp. 1020-1021 ◽  
Author(s):  
M. Sarikaya ◽  
J. T. Staley ◽  
I. A. Aksay
Keyword(s):  
Self Assembly ◽  
Structural Control ◽  
Hierarchical Structures ◽  
Ceramic Composites ◽  
Advanced Materials ◽  
Length Scale ◽  
Spider Webs ◽  
Biomimetic Materials ◽  
Synthetic Materials ◽  
All Ceramic

Biomimetics is an area of research in which the analysis of structures and functions of natural materials provide a source of inspiration for design and processing concepts for novel synthetic materials. Through biomimetics, it may be possible to establish structural control on a continuous length scale, resulting in superior structures able to withstand the requirements placed upon advanced materials. It is well recognized that biological systems efficiently produce complex and hierarchical structures on the molecular, micrometer, and macro scales with unique properties, and with greater structural control than is possible with synthetic materials. The dynamism of these systems allows the collection and transport of constituents; the nucleation, configuration, and growth of new structures by self-assembly; and the repair and replacement of old and damaged components. These materials include all-organic components such as spider webs and insect cuticles (Fig. 1); inorganic-organic composites, such as seashells (Fig. 2) and bones; all-ceramic composites, such as sea urchin teeth, spines, and other skeletal units (Fig. 3); and inorganic ultrafine magnetic and semiconducting particles produced by bacteria and algae, respectively (Fig. 4).

scholarly journals Metal Oxide-Related Dendritic Structures: Self-Assembly and Applications for Sensor, Catalysis, Energy Conversion and Beyond

Nanomaterials ◽  
2021 ◽  
Vol 11 (7) ◽  
pp. 1686
Author(s):  
Ruohong Sui ◽  
Paul A. Charpentier ◽  
Robert A. Marriott
Keyword(s):  
Metal Oxide ◽  
Energy Conversion ◽  
Self Assembly ◽  
Hierarchical Structures ◽  
The Self ◽  
Assembly Process ◽  
Electronic Noses ◽  
Dendritic Nanostructures ◽  
Energy Conversion And Storage ◽  
The Aesthetic

In the past two decades, we have learned a great deal about self-assembly of dendritic metal oxide structures, partially inspired by the nanostructures mimicking the aesthetic hierarchical structures of ferns and corals. The self-assembly process involves either anisotropic polycondensation or molecular recognition mechanisms. The major driving force for research in this field is due to the wide variety of applications in addition to the unique structures and properties of these dendritic nanostructures. Our purpose of this minireview is twofold: (1) to showcase what we have learned so far about how the self-assembly process occurs; and (2) to encourage people to use this type of material for drug delivery, renewable energy conversion and storage, biomaterials, and electronic noses.

scholarly journals Polymer cyclization for the emergence of hierarchical nanostructures

2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Chaojian Chen ◽  
Manjesh Kumar Singh ◽  
Katrin Wunderlich ◽  
Sean Harvey ◽  
Colette J. Whitfield ◽  
...  
Keyword(s):  
Self Assembly ◽  
Three Dimensional ◽  
Hierarchical Structures ◽  
Structural Similarity ◽  
Vital Role ◽  
Nanomaterial Synthesis ◽  
Wide Range ◽  
Linear Poly ◽  
Polymer Folding ◽  
Dynamics Simulations

AbstractThe creation of synthetic polymer nanoobjects with well-defined hierarchical structures is important for a wide range of applications such as nanomaterial synthesis, catalysis, and therapeutics. Inspired by the programmability and precise three-dimensional architectures of biomolecules, here we demonstrate the strategy of fabricating controlled hierarchical structures through self-assembly of folded synthetic polymers. Linear poly(2-hydroxyethyl methacrylate) of different lengths are folded into cyclic polymers and their self-assembly into hierarchical structures is elucidated by various experimental techniques and molecular dynamics simulations. Based on their structural similarity, macrocyclic brush polymers with amphiphilic block side chains are synthesized, which can self-assemble into wormlike and higher-ordered structures. Our work points out the vital role of polymer folding in macromolecular self-assembly and establishes a versatile approach for constructing biomimetic hierarchical assemblies.

scholarly journals Preparation of superhydrophobic surfaces with micro/nano alumina molds

RSC Advances ◽  
2018 ◽  
Vol 8 (64) ◽  
pp. 36697-36704 ◽  
Author(s):  
Takashi Yanagishita ◽  
Kaito Murakoshi ◽  
Toshiaki Kondo ◽  
Hideki Masuda
Keyword(s):  
Superhydrophobic Surface ◽  
Porous Alumina ◽  
Hierarchical Structures ◽  
Superhydrophobic Surfaces ◽  
Anodic Porous Alumina ◽  
Nano Alumina

Superhydrophobic surface with hierarchical structures prepared by nanoimprinting using anodic porous alumina molds.

Wetting and Dewetting Transitions on Submerged Superhydrophobic Surfaces with Hierarchical Structures

Langmuir ◽  
2016 ◽  
Vol 33 (1) ◽  
pp. 407-416 ◽  
Author(s):  
Huaping Wu ◽  
Zhe Yang ◽  
Binbin Cao ◽  
Zheng Zhang ◽  
Kai Zhu ◽  
...  
Keyword(s):  
Hierarchical Structures ◽  
Superhydrophobic Surfaces

scholarly journals Concentration-driven phase transition and self-assembly in drying droplets of diluting whole blood

2020 ◽  
Vol 10 (1) ◽  
Author(s):  
Anusuya Pal ◽  
Amalesh Gope ◽  
John D. Obayemi ◽  
Germano S. Iannacchione
Keyword(s):  
Phase Transition ◽  
Self Assembly ◽  
Whole Blood ◽  
Morphological Analysis ◽  
Hierarchical Structures ◽  
Contact Angle Measurement ◽  
Angle Measurement ◽  
Colloidal Systems ◽  
Functional Complexity ◽  
Sharp Phase Transition

Abstract Multi-colloidal systems exhibit a variety of structural and functional complexity owing to their ability to interact amongst different components into self-assembled structures. This paper presents experimental confirmations that reveal an interesting sharp phase transition during the drying state and in the dried film as a function of diluting concentrations ranging from 100% (undiluted whole blood) to 12.5% (diluted concentrations). An additional complementary contact angle measurement exhibits a monotonic decrease with a peak as a function of drying. This peak is related to a change in visco-elasticity that decreases with dilution, and disappears at the dilution concentration for the observed phase transition equivalent to 62% (v/v). This unique behavior is clearly commensurate with the optical image statistics and morphological analysis; and it is driven by the decrease in the interactions between various components within this bio-colloid. The implications of these phenomenal systems may address many open-ended questions of complex hierarchical structures.

scholarly journals Homopolymer self-assembly of poly(propylene sulfone) hydrogels via dynamic noncovalent sulfone–sulfone bonding

2020 ◽  
Vol 11 (1) ◽  
Author(s):  
Fanfan Du ◽  
Baofu Qiao ◽  
Trung Dac Nguyen ◽  
Michael P. Vincent ◽  
Sharan Bobbala ◽  
...  
Keyword(s):  
Small Molecules ◽  
Self Assembly ◽  
Encapsulation Efficiency ◽  
Dynamic Network ◽  
Hierarchical Structures ◽  
Solvent Polarity ◽  
High Affinity ◽  
Wide Range ◽  
Poly Propylene ◽  
Water Ratio

Abstract Natural biomolecules such as peptides and DNA can dynamically self-organize into diverse hierarchical structures. Mimicry of this homopolymer self-assembly using synthetic systems has remained limited but would be advantageous for the design of adaptive bio/nanomaterials. Here, we report both experiments and simulations on the dynamic network self-assembly and subsequent collapse of the synthetic homopolymer poly(propylene sulfone). The assembly is directed by dynamic noncovalent sulfone–sulfone bonds that are susceptible to solvent polarity. The hydration history, specified by the stepwise increase in water ratio within lower polarity water-miscible solvents like dimethylsulfoxide, controls the homopolymer assembly into crystalline frameworks or uniform nanostructured hydrogels of spherical, vesicular, or cylindrical morphologies. These electrostatic hydrogels have a high affinity for a wide range of organic solutes, achieving >95% encapsulation efficiency for hydrophilic small molecules and biologics. This system validates sulfone–sulfone bonding for dynamic self-assembly, presenting a robust platform for controllable gelation, nanofabrication, and molecular encapsulation.

Superhydrophobic Surfaces by Anomalous Fluoroalkylsilane Self-Assembly on Silica Nanosphere Arrays

Langmuir ◽  
2010 ◽  
Vol 26 (15) ◽  
pp. 12962-12972 ◽  
Author(s):  
Muhammad Akram Raza ◽  
E. Stefan Kooij ◽  
Arend van Silfhout ◽  
Bene Poelsema
Keyword(s):  
Self Assembly ◽  
Superhydrophobic Surfaces ◽  
Silica Nanosphere
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