Heteroaromatic Tosylates as Electrophiles in Regioselective Mizoroki-Heck-Coupling Reactions with Electron-Rich Olefins

2009 ◽  
Vol 15 (24) ◽  
pp. 5950-5955 ◽  
Author(s):  
Thomas M. Gøgsig ◽  
Anders T. Lindhardt ◽  
Mouloud Dekhane ◽  
Julie Grouleff ◽  
Troels Skrydstrup
Keyword(s):  
Coupling Reactions ◽  
Heck Coupling

scholarly journals MM quadruply bonded complexes supported by vinylbenzoate ligands: synthesis, characterization, photophysical properties and application as synthons

2015 ◽  
Vol 6 (3) ◽  
pp. 1780-1791 ◽  
Author(s):  
Samantha E. Brown-Xu ◽  
Malcolm H. Chisholm ◽  
Christopher B. Durr ◽  
Thomas F. Spilker ◽  
Philip J. Young
Keyword(s):  
Photophysical Properties ◽  
Higher Order ◽  
Coupling Reactions ◽  
Heck Coupling ◽  
Bonded Complexes ◽  
Quadruply Bonded Complexes

MM complexes as potential synthons for the development of higher order extended structures via Heck coupling reactions, exhibiting interesting photophysical properties.

Application of N,N-Bis(diphenylphosphino)aniline Palladium(II) Complexes as Precatalysts in Heck Coupling Reactions.

ChemInform ◽  
2007 ◽  
Vol 38 (47) ◽  
Author(s):  
Bahattin Guemguem ◽  
Nermin Biricik ◽  
Feyyaz Durap ◽  
Ismail Oezdemir ◽  
Nevin Guerbuez ◽  
...  
Keyword(s):  
Coupling Reactions ◽  
Heck Coupling

Invited Review. A Combinatorial Approach to the Development of Environmentally Benign Organic Chemical Preparations

1999 ◽  
Vol 52 (2) ◽  
pp. 83 ◽  
Author(s):  
Christopher R. Strauss
Keyword(s):  
Hydrogen Transfer ◽  
Aldol Condensation ◽  
Aqueous Media ◽  
Environmentally Benign ◽  
Organic Chemical ◽  
Coupling Reactions ◽  
Heck Coupling ◽  
Solvent Free Conditions ◽  
Microwave Reactors ◽  
One Step

Enabling technologies and methodologies were established and combined to afford various environmentally benign processes for laboratory-scale organic synthesis and for the production of fine chemicals, intermediates and pharmaceuticals. The technologies comprised continuous and batch microwave reactors and catalytic membranes. The methodologies included solvent-free conditions, catalysed or uncatalysed processes, the use of aqueous media at high temperature and non-extractive techniques for product isolation. Applications included Hofmann eliminations, Willgerodt and Jacobs–Gould reactions, indole transformations, aldol condensation, Rupe and Meyer–Schuster rearrangements and C–C coupling reactions (including a tandem Heck coupling–dehydrogenation). New processes for catalytic etherification, uncatalysed hydrogen transfer and a one-step arylamidation were also developed. Typical products were N-(4-hydroxyphenyl)acetamide, carvacrol, a-phenylacetamide, cinnamaldehyde, cinnamyl alcohol, acetophenone, indole, 3-hydroxy-1,2-dimethyl-4-pyridone, di(2-phenylethyl) ether, di(cyclopropylmethyl) ether, 3-methylcyclopent-2-enone and a synthetic precursor of nalidixic acid.

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