Biodegradable Naphthenic Acid Ionic Liquids: Synthesis, Characterization, and Quantitative Structure-Biodegradation Relationship

2008 ◽  
Vol 14 (35) ◽  
pp. 11174-11182 ◽  
Author(s):  
Yinghao Yu ◽  
Xingmei Lu ◽  
Qing Zhou ◽  
Kun Dong ◽  
Hongwei Yao ◽  
...  
ACS Omega ◽  
2021 ◽  
Vol 6 (14) ◽  
pp. 9629-9637
Author(s):  
Sakinah Khaidzir ◽  
Asiah Nusaibah Masri ◽  
Muhammad Syafiq Hazwan Ruslan ◽  
Mohamed Ibrahim Abdul Mutalib

2006 ◽  
Vol 61 (11-12) ◽  
pp. 827-832 ◽  
Author(s):  
Tomasz Bączek ◽  
Barbara Sparzak

Abstract A novel analytical approach involving the addition of an ionic liquid into the mobile phase of the thin-layer chromatography (TLC) system during the optimization of chromatographic separation of peptides was demonstrated. Different behavior of peptides in the TLC sytem was observed after the addition of 1,3-dimethylimidazolium methyl sulfate to the eluent in comparison to the system without the ionic liquid. The objective of the work was to study the effect of the addition of different contents of ionic liquid to the mobile phase comprising mostly water and to observe the behavior of peptides’ retention. The potential usefulness of environmentally friendly ionic liquids for the optimization of separation of peptides was demonstrated. An increase of Rf values was observed with increasing the ionic liquid content in the mobile phase. The benefits of the used approach were related to the separation achieved. Finally, quantitative structure-retention relationships (QSRR) were used for the studies on the predictions of peptides’ retention in the TLC systems with the addition of ionic liquid in terms of the predictions performed recently in HPLC systems.


2021 ◽  
Vol 287 ◽  
pp. 03007
Author(s):  
Muhammad Ishaq Khan ◽  
Dzulkarnain Zaini ◽  
Azmi Mohd Shariff

The natural environment has been affected by human activities to fulfil daily life needs. Abundance and hazardousness of the chemicals including ionic liquids is one of the most challenging aspect to be handled by human as well as for the natural environment. Due to ionic structure, ionic liquids are very good choice for a variety of applications. The natural environment might be affected by the ionic liquids which can be toxic. Therefore, there is a need to address this problem by studying the ecotoxicological behaviour of these ionic liquids. The main objective of current research is to model the toxicity ecotoxicological behaviour is studied by quantitative structure activity relationship (QSAR). QSARs predicts the toxicity of ionic liquids. In current research a relationship between polarizability and toxicity for imidazolium ionic liquids with different alky chain length having NTF2 anion has been modelled. The success of current research will be very helpful to protect the nature by minimizing the killing of testing animals as well as ensuring the safety of biotic components of the ecosystem.


2014 ◽  
Vol 29 (1) ◽  
pp. 106-111 ◽  
Author(s):  
Syed Nasir Shah ◽  
M. Ibrahim. A. Mutalib ◽  
Rashidah Binti Mohd Pilus ◽  
Kallidanthiyil Chellappan Lethesh

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