o-DPPB-Directed Copper-Mediated and -Catalyzed Allylic Substitution with Grignard Reagents

2006 ◽  
Vol 12 (25) ◽  
pp. 6669-6683 ◽  
Author(s):  
Peter Demel ◽  
Manfred Keller ◽  
Bernhard Breit
Keyword(s):  
Grignard Reagents ◽  
Allylic Substitution

Sequential Copper-Catalyzed Rearrangement-Allylic Substitution of Bicyclic Hydrazines with Grignard Reagents

2009 ◽  
Vol 351 (6) ◽  
pp. 869-873 ◽  
Author(s):  
Stefano Crotti ◽  
Ferruccio Bertolini ◽  
Franco Macchia ◽  
Mauro Pineschi
Keyword(s):  
Grignard Reagents ◽  
Allylic Substitution

scholarly journals Allylic Substitution Reactions with Grignard Reagents Catalyzed by Imidazolium and 4,5-Dihydroimidazolium Carbene—CuCl Complexes.

ChemInform ◽  
2006 ◽  
Vol 37 (29) ◽  
Author(s):  
Sentaro Okamoto ◽  
Satoshi Tominaga ◽  
Naoko Saino ◽  
Kouki Kase ◽  
Kentaro Shimoda
Keyword(s):  
Grignard Reagents ◽  
Allylic Substitution ◽  
Substitution Reactions

Iron-Catalyzed Grignard Cross-Couplings with Allylic Methyl Ethers or Allylic Trimethylsilyl Ethers

Synlett ◽  
2018 ◽  
Vol 29 (09) ◽  
pp. 1211-1214 ◽  
Author(s):  
Chika Seto ◽  
Takeshi Otsuka ◽  
Yoshiki Takeuchi ◽  
Daichi Tabuchi ◽  
Takashi Nagano
Keyword(s):  
Cross Coupling ◽  
Grignard Reagents ◽  
Allylic Substitution ◽  
Trimethylsilyl Ethers

We have found that cross-coupling between aryl Grignard reagents and allylic methyl ethers proceeded well in the presence of a catalytic amounts of Fe(acac)3 to afford the corresponding allylic substitution products in good yields. Under the same conditions, allylic trimethylsilyl ethers also reacted with Grignard reagents to give the corresponding cross-coupling products.

New General Method for Regio- and Stereoselective Allylic Substitution with Aryl and Alkenyl Coppers Derived from Grignard Reagents

2009 ◽  
Vol 74 (5) ◽  
pp. 1939-1951 ◽  
Author(s):  
Yohei Kiyotsuka ◽  
Yuji Katayama ◽  
Hukum P. Acharya ◽  
Tomonori Hyodo ◽  
Yuichi Kobayashi
Keyword(s):  
Grignard Reagents ◽  
Allylic Substitution ◽  
General Method

Allylic Substitution of 4-Cyclopentene-1,3-diol Monoacetate with Copper Reagents Derived from Functionalized Aryl Grignard Reagents

Synlett ◽  
2010 ◽  
Vol 2010 (02) ◽  
pp. 325-328 ◽  
Author(s):  
Yuichi Kobayashi ◽  
Yukio Tani ◽  
Kenya Nakata ◽  
Yuki Kaneko
Keyword(s):  
Grignard Reagents ◽  
Allylic Substitution

scholarly journals Iron-catalyzed allylic substitution reactions of allylic ethers with Grignard reagents

2016 ◽  
Vol 57 (20) ◽  
pp. 2211-2214 ◽  
Author(s):  
Longying Qi ◽  
Enlu Ma ◽  
Fan Jia ◽  
Zhiping Li
Keyword(s):  
Grignard Reagents ◽  
Allylic Substitution ◽  
Substitution Reactions ◽  
Allylic Ethers
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