scholarly journals Nitrogen and Oxygen Functionalization of Multi‐walled Carbon Nanotubes for Tuning the Bifunctional Oxygen Reduction/Oxygen Evolution Performance of Supported FeCo Oxide Nanoparticles

2021 ◽  
Author(s):  
Mariya A. Kazakova ◽  
Adarsh Koul ◽  
Georgiy V. Golubtsov ◽  
Alexander G. Selyutin ◽  
Arcady V. Ishchenko ◽  
...  
Keyword(s):  
Carbon Nanotubes ◽  
Oxygen Reduction ◽  
Oxygen Evolution ◽  
Oxide Nanoparticles ◽  
Multi Walled Carbon Nanotubes ◽  
Walled Carbon Nanotubes

scholarly journals The sum is more than its parts: stability of MnFe oxide nanoparticles supported on oxygen-functionalized multi-walled carbon nanotubes at alternating oxygen reduction reaction and oxygen evolution reaction conditions

2020 ◽  
Vol 24 (11-12) ◽  
pp. 2901-2906
Author(s):  
Dulce M. Morales ◽  
Mariya A. Kazakova ◽  
Maximilian Purcel ◽  
Justus Masa ◽  
Wolfgang Schuhmann
Keyword(s):  
Carbon Nanotubes ◽  
Oxygen Reduction ◽  
Oxygen Evolution ◽  
Active Sites ◽  
Reduction Reaction ◽  
Operating Conditions ◽  
Active Components ◽  
Successful Design ◽  
Multi Walled Carbon Nanotubes ◽  
Walled Carbon Nanotubes

Abstract Successful design of reversible oxygen electrocatalysts does not only require to consider their activity towards the oxygen reduction (ORR) and the oxygen evolution reactions (OER), but also their electrochemical stability at alternating ORR and OER operating conditions, which is important for potential applications in reversible electrolyzers/fuel cells or metal/air batteries. We show that the combination of catalyst materials containing stable ORR active sites with those containing stable OER active sites may result in a stable ORR/OER catalyst if each of the active components can satisfy the current demand of their respective reaction. We compare the ORR/OER performances of oxides of Mn (stable ORR active sites), Fe (stable OER active sites), and bimetallic Mn0.5Fe0.5 (reversible ORR/OER catalyst) supported on oxidized multi-walled carbon nanotubes. Despite the instability of Mn and Fe oxide for the OER and the ORR, respectively, Mn0.5Fe0.5 exhibits high stability for both reactions.

One-step synthesis of multi-walled carbon nanotubes/ultra-thin Ni(OH)2 nanoplate composite as efficient catalysts for water oxidation

2014 ◽  
Vol 2 (30) ◽  
pp. 11799-11806 ◽  
Author(s):  
Xuemei Zhou ◽  
Zhaoming Xia ◽  
Zhiyun Zhang ◽  
Yuanyuan Ma ◽  
Yongquan Qu
Keyword(s):  
Carbon Nanotubes ◽  
Hydrothermal Synthesis ◽  
Oxygen Evolution ◽  
Oxygen Evolution Reaction ◽  
Water Oxidation ◽  
Highly Efficient ◽  
Multi Walled Carbon Nanotubes ◽  
One Step ◽  
Walled Carbon Nanotubes

One-step hydrothermal synthesis of ultra-thin β-Ni(OH)2 nanoplates (1.5–3.0 nm thickness) and their composite with multi-walled carbon nanotubes in the absence of surfactants function as highly efficient and stable electrocatalysts for oxygen evolution reaction.

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