Stabilization of a 4.7 V high‐voltage Ni‐rich layered oxide cathode for lithium‐ion batteries through boron‐based surface residual lithium‐tuned interface modification engineering

2021 ◽  
Author(s):  
Wenzhi Wang ◽  
Langyuan Wu ◽  
Zhiwei Li ◽  
Kangsheng Huang ◽  
Ziyang Chen ◽  
...  
Keyword(s):  
Lithium Ion Batteries ◽  
High Voltage ◽  
Lithium Ion ◽  
Interface Modification ◽  
Layered Oxide ◽  
Oxide Cathode

Tris(2,2,2-trifluoroethyl) phosphite as an electrolyte additive for high-voltage lithium-ion batteries using lithium-rich layered oxide cathode

2015 ◽  
Vol 296 ◽  
pp. 413-425 ◽  
Author(s):  
Julie Pires ◽  
Aurore Castets ◽  
Laure Timperman ◽  
Jesùs Santos-Peña ◽  
Erwan Dumont ◽  
...  
Keyword(s):  
Lithium Ion Batteries ◽  
High Voltage ◽  
Lithium Ion ◽  
Electrolyte Additive ◽  
Layered Oxide ◽  
Oxide Cathode

Electrolyte Regulating toward Stabilization of Cobalt-Free Ultrahigh-Nickel Layered Oxide Cathode in Lithium-Ion Batteries

2021 ◽  
pp. 1324-1332
Author(s):  
Xianhui Zhang ◽  
Hao Jia ◽  
Lianfeng Zou ◽  
Yaobin Xu ◽  
Linqin Mu ◽  
...  
Keyword(s):  
Lithium Ion Batteries ◽  
Lithium Ion ◽  
Layered Oxide ◽  
Oxide Cathode

Boosting Cycling Stability of Ni-rich Layered Oxide Cathode by Dry Coating of Ultrastable Li3V2(PO4)3 Nanoparticles

Nanoscale ◽  
2021 ◽  
Author(s):  
Dongdong Wang ◽  
Qizhang Yan ◽  
Mingqian Li ◽  
Hongpeng Gao ◽  
Jianhua Tian ◽  
...  
Keyword(s):  
Lithium Ion Batteries ◽  
Cathode Materials ◽  
Lithium Ion ◽  
High Energy ◽  
Cycling Stability ◽  
Next Generation ◽  
Layered Oxides ◽  
Dry Coating ◽  
Layered Oxide ◽  
Oxide Cathode

Nickel (Ni)-rich layered oxides such as LiNi0.6Co0.2Mn0.2O2 (NCM622) represent one of the most promising candidates for the next-generation high-energy lithium-ion batteries (LIBs). However, the pristine Ni-rich cathode materials usually suffer...

New Insight into Microstructure Engineering of Ni‐Rich Layered Oxide Cathode for High Performance Lithium Ion Batteries

2021 ◽  
pp. 2010095
Author(s):  
Chul‐Ho Jung ◽  
Do‐Hoon Kim ◽  
Donggun Eum ◽  
Kyeong‐Ho Kim ◽  
Jonghyun Choi ◽  
...  
Keyword(s):  
Lithium Ion Batteries ◽  
High Performance ◽  
Lithium Ion ◽  
Layered Oxide ◽  
Oxide Cathode ◽  
Insight Into

scholarly journals Effect of Different Composition on Voltage Attenuation of Li-Rich Cathode Material for Lithium-Ion Batteries

Materials ◽  
2019 ◽  
Vol 13 (1) ◽  
pp. 40 ◽  
Author(s):  
Jun Liu ◽  
Qiming Liu ◽  
Huali Zhu ◽  
Feng Lin ◽  
Yan Ji ◽  
...  
Keyword(s):  
Cathode Material ◽  
Lithium Ion Batteries ◽  
Cathode Materials ◽  
Nickel Content ◽  
Lithium Ion ◽  
Commercial Application ◽  
Operating Voltage ◽  
Layered Oxide ◽  
Oxide Cathode ◽  
Voltage Attenuation

Li-rich layered oxide cathode materials have become one of the most promising cathode materials for high specific energy lithium-ion batteries owning to its high theoretical specific capacity, low cost, high operating voltage and environmental friendliness. Yet they suffer from severe capacity and voltage attenuation during prolong cycling, which blocks their commercial application. To clarify these causes, we synthesize Li1.5Mn0.55Ni0.4Co0.05O2.5 (Li1.2Mn0.44Ni0.32Co0.04O2) with high-nickel-content cathode material by a solid-sate complexation method, and it manifests a lot slower capacity and voltage attenuation during prolong cycling compared to Li1.5Mn0.66Ni0.17Co0.17O2.5 (Li1.2Mn0.54Ni0.13Co0.13O2) and Li1.5Mn0.65Ni0.25Co0.1O2.5 (Li1.2Mn0.52Ni0.2Co0.08O2) cathode materials. The capacity retention at 1 C after 100 cycles reaches to 87.5% and the voltage attenuation after 100 cycles is only 0.460 V. Combining X-ray diffraction (XRD), scanning electron microscope (SEM), and transmission electron microscopy (TEM), it indicates that increasing the nickel content not only stabilizes the structure but also alleviates the attenuation of capacity and voltage. Therefore, it provides a new idea for designing of Li-rich layered oxide cathode materials that suppress voltage and capacity attenuation.

An electrolyte-phobic carbon nanotube current collector for high-voltage foldable lithium-ion batteries

2020 ◽  
Vol 8 (37) ◽  
pp. 19444-19453 ◽  
Author(s):  
Ke Wen Mu ◽  
Kai Xi Liu ◽  
Zhi Yong Wang ◽  
Shahid Zanman ◽  
Yan Hong Yin ◽  
...  
Keyword(s):  
Carbon Nanotube ◽  
Lithium Ion Batteries ◽  
High Voltage ◽  
Lithium Ion ◽  
Current Collector ◽  
Ion Diffusion ◽  
Interface Modification ◽  
Lithium Ion Diffusion

Surface/interface modification is developed to tune the electrolyte wettability of a carbon nanotube current collector for controlling the lithium ion diffusion and achieving high voltage foldable lithium-ion batteries.

Site-Selective In Situ Electrochemical Doping for Mn-Rich Layered Oxide Cathode Materials in Lithium-Ion Batteries

2017 ◽  
Vol 8 (11) ◽  
pp. 1702514 ◽  
Author(s):  
Aram Choi ◽  
Jungwoo Lim ◽  
Hyung-Jin Kim ◽  
Sung Chul Jung ◽  
Hyung-Woo Lim ◽  
...  
Keyword(s):  
Lithium Ion Batteries ◽  
Cathode Materials ◽  
Lithium Ion ◽  
Layered Oxide ◽  
Electrochemical Doping ◽  
Oxide Cathode ◽  
Site Selective

A novel strategy to significantly enhance the initial voltage and suppress voltage fading of a Li- and Mn-rich layered oxide cathode material for lithium-ion batteries

2018 ◽  
Vol 6 (8) ◽  
pp. 3610-3624 ◽  
Author(s):  
Shiming Zhang ◽  
Jian Chen ◽  
Tian Tang ◽  
Yinzhu Jiang ◽  
Gairong Chen ◽  
...  
Keyword(s):  
Cathode Material ◽  
Lithium Ion Batteries ◽  
Lithium Ion ◽  
Composite Cathode ◽  
Surface Phase ◽  
Layered Oxide ◽  
Initial Voltage ◽  
Oxide Cathode ◽  
Novel Strategy

A Li[Li0.2Ni0.13Co0.13Mn0.54]O2–xLiNiO2 composite cathode with a Ni-rich bulk phase and in situ precipitated Ni-rich spinel-like surface phase has been built to enhance the initial voltage and suppress voltage fading during cycling.

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