Double‐Pulse Electrodeposition of CuGaS 2 Photovoltaic Thin Film

2019 ◽  
Vol 6 (12) ◽  
pp. 2998-3001
Author(s):  
Marcos A. S. Andrade ◽  
Murilo F. Gromboni ◽  
Leandro L. Soares ◽  
Lucia H. Mascaro
2013 ◽  
Vol 160 (10) ◽  
pp. D459-D464 ◽  
Author(s):  
Minghao Wang ◽  
Sui Yang ◽  
Hongxing Li ◽  
Jie Yi ◽  
Mingwei Li ◽  
...  

2019 ◽  
Vol 6 (12) ◽  
pp. 2966-2966
Author(s):  
Marcos A. S. Andrade ◽  
Murilo F. Gromboni ◽  
Leandro L. Soares ◽  
Lucia H. Mascaro

Author(s):  
Etsuji Ohmura ◽  
Tomohiro Okamoto ◽  
Seiji Fujiwara ◽  
Tomokazu Sano ◽  
Isamu Miyamoto

Coatings ◽  
2020 ◽  
Vol 10 (4) ◽  
pp. 332 ◽  
Author(s):  
Wen Ge ◽  
Taisong He ◽  
Meijiao Wang ◽  
Jiamei Li

Functional gradient materials (FGM) have many excellent properties, and high-performance gradient coating exhibits good prospective application. In this paper, the nano-grain Ni/ZrO2 gradient coating was prepared by double pulse electrodeposition (BP). The surface morphology, crystal structure and electrochemical corrosion resistance of the nano-grain Ni/ZrO2 coating and Ni coating, annealed at different temperatures (400–800 °C), have been compared. In the vertical direction to the substrate surface, the content of ZrO2 increases from 0% to 34.99%. X-ray diffraction (XRD) revealed that the average crystal size of Ni/ZrO2 gradient coating gradually increases from 13.75 to 27.75 nm, and the crystal structure is a face-centered cubic (FCC). The main crystal orientation faces are (111) and (200), while the (200) face exhibited a stronger preferred orientation. Compared with the Ni coating by scanning electron microscopy, the surface morphology of double pulse fabricated Ni/ZrO2 gradient coating was revealed as being smoother, denser, and having fewer pores, and the crystal particle size distribution became narrow. X-ray photoelectron spectroscopy (XPS) shows that the chemical binding states of elements Ni and Zr have been altered. The binding energies of 2p3/2 and 2p1/2 for Ni have been increased, resulting in a higher electron donor state of Ni. The binding energy of 3d5/2 and 3d3/2 of Zr4+ in ZrO2 is decreased, thus becoming better electron acceptors. Chemical bonding has been formed at the Ni/ZrO2 interface. This study demonstrated that double pulse electrodeposition is a promising fabrication method for functional gradient coatings for high temperature applications.


2019 ◽  
Vol 1 (34) ◽  
pp. 13-18
Author(s):  
Kiran Jain ◽  
N. Karar ◽  
H. Chandra ◽  
Rashmi Rashmi

Author(s):  
Etsuji Ohmura ◽  
Tomohiro Okamoto ◽  
Seiji Fujiwara ◽  
Tomokazu Sano ◽  
Isamu Miyamoto

Coatings ◽  
2021 ◽  
Vol 11 (9) ◽  
pp. 1068
Author(s):  
Dongai Wang ◽  
Meihua Liu ◽  
Yuanmin Zhu ◽  
Feihui Li

In this study, using 45# carbon steel as the substrate, a first experimental analysis was carried out on the polarisation behaviour of different component wattage plating solutions in order to determine the reasonable content of nanodiamond particles in a nickel/nanodiamond composite plating solution. Secondly, the effect of double-pulse forward and reverse duty cycle and reverse working time on the performance of nickel/nanodiamond composite plating was then investigated by testing the thickness, hardness and surface roughness of the composite plating and observing the surface micromorphology. The experimental results show that, when the content of nanodiamond particles in the plating solution is 5 g/L, the anti-pulse working time, forward and reverse pulse duty cycle of the double-pulse plating parameters are 20, 0.3 and 0.2 ms, respectively, and the composite plating layer prepared by double pulse has good comprehensive performance. This research work provides technical support for the optimisation of process parameters for the preparation of nickel/nanodiamond composite coatings by double-pulse electrodeposition.


2020 ◽  
Vol 117 (8) ◽  
pp. 082407
Author(s):  
Makoto Okano ◽  
Tomohiro Takahashi ◽  
Shinichi Watanabe

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