Cobalt−Iron Pyrophosphate Porous Nanosheets as Highly Active Electrocatalysts for the Oxygen Evolution Reaction

2017 ◽  
Vol 5 (1) ◽  
pp. 36-43 ◽  
Author(s):  
Miaomiao Liu ◽  
Zhengyi Qu ◽  
Deqin Yin ◽  
Xiaojuan Chen ◽  
Yajie Zhang ◽  
...  
2017 ◽  
Vol 5 (1) ◽  
pp. 3-3
Author(s):  
Miaomiao Liu ◽  
Zhengyi Qu ◽  
Deqin Yin ◽  
Xiaojuan Chen ◽  
Yajie Zhang ◽  
...  

2019 ◽  
Author(s):  
Lichen Bai ◽  
Chia-Shuo Hsu ◽  
Duncan Alexander ◽  
Hao Ming Chen ◽  
Xile Hu

Single atom catalysts exhibit well-defined active sites and potentially maximum atomic efficiency. However, they are unsuitable for reactions that benefit from bimetallic promotion such as the oxygen evolution reaction (OER) in alkaline medium. Here we show that a single atom Co precatalyst can be in-situ transformed into a Co-Fe double atom catalyst for OER. This catalyst exhibits one of the highest turnover frequencies among metal oxides. Electrochemical, microscopic, and spectroscopic data including those from operando X-ray absorption spectroscopy, reveal a dimeric Co-Fe moiety as the active site of the catalyst. This work demonstrates double-atom catalysis as a promising approach for the developed of defined and highly active OER catalysts.


2019 ◽  
Author(s):  
Lichen Bai ◽  
Chia-Shuo Hsu ◽  
Duncan Alexander ◽  
Hao Ming Chen ◽  
Xile Hu

Single atom catalysts exhibit well-defined active sites and potentially maximum atomic efficiency. However, they are unsuitable for reactions that benefit from bimetallic promotion such as the oxygen evolution reaction (OER) in alkaline medium. Here we show that a single atom Co precatalyst can be in-situ transformed into a Co-Fe double atom catalyst for OER. This catalyst exhibits one of the highest turnover frequencies among metal oxides. Electrochemical, microscopic, and spectroscopic data including those from operando X-ray absorption spectroscopy, reveal a dimeric Co-Fe moiety as the active site of the catalyst. This work demonstrates double-atom catalysis as a promising approach for the developed of defined and highly active OER catalysts.


Author(s):  
Shuya Zhao ◽  
Yurui Xue ◽  
Zhongqiang Wang ◽  
Zhiqiang Zheng ◽  
Xiaoyu Luan ◽  
...  

Developing highly active, stable and low-cost electrocatalysts capable of an efficient oxygen evolution reaction (OER) is urgent and challenging.


Author(s):  
Yoo Sei Park ◽  
Jooyoung Lee ◽  
Myeong-Je Jang ◽  
Juchan Yang ◽  
Jae Hoon Jeong ◽  
...  

Seawater electrolysis is a promising technology for the production of hydrogen energy and seawater desalination. To produce hydrogen energy through seawater electrolysis, highly active electrocatalysts for the oxygen evolution reaction...


2021 ◽  
Vol 33 (14) ◽  
pp. 2007523
Author(s):  
Lin Zhang ◽  
Chengjie Lu ◽  
Fei Ye ◽  
Ruilvjing Pang ◽  
Yang Liu ◽  
...  

Author(s):  
Kaiyao Wu ◽  
Fei Chu ◽  
Yuying Meng ◽  
Kaveh Edalati ◽  
Qingsheng Gao ◽  
...  

Transition metal-based amorphous alloys have attracted increasing attention as precious-metal-free electrocatalysts for oxygen evolution reaction (OER) of water splitting due to their high macro-conductivity and abundant surface active sites. However,...


2019 ◽  
Vol 806 ◽  
pp. 1097-1104 ◽  
Author(s):  
Suhang Xun ◽  
Yan Xu ◽  
Jingjing He ◽  
Deli Jiang ◽  
Rong Yang ◽  
...  

2015 ◽  
Vol 3 (4) ◽  
pp. 1500252 ◽  
Author(s):  
Jongsik Park ◽  
Jongchan Kim ◽  
Yoojin Yang ◽  
Donghwan Yoon ◽  
Hionsuck Baik ◽  
...  

2016 ◽  
Vol 4 (2) ◽  
pp. 620-631 ◽  
Author(s):  
Islam M. Mosa ◽  
Sourav Biswas ◽  
Abdelhamid M. El-Sawy ◽  
Venkatesh Botu ◽  
Curtis Guild ◽  
...  

Understanding the origin of manganese oxide activity for oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) is a key step towards rationally designing of highly active catalysts capable of competing with the widely used, state-of-art noble metal catalysts.


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