Improved Cycling Stability of Lithium-Metal Anode with Concentrated Electrolytes Based on Lithium (Fluorosulfonyl)(trifluoromethanesulfonyl)imide

2016 ◽  
Vol 3 (4) ◽  
pp. 531-536 ◽  
Author(s):  
Qiang Ma ◽  
Zheng Fang ◽  
Pin Liu ◽  
Jie Ma ◽  
Xingguo Qi ◽  
...  
Keyword(s):  
Cycling Stability ◽  
Lithium Metal ◽  
Metal Anode ◽  
Lithium Metal Anode ◽  
Concentrated Electrolytes

Impact of Anionic Structure of Lithium Salt on the Cycling Stability of Lithium-Metal Anode in Li-S Batteries

2016 ◽  
Vol 163 (8) ◽  
pp. A1776-A1783 ◽  
Author(s):  
Qiang Ma ◽  
Bo Tong ◽  
Zheng Fang ◽  
Xingguo Qi ◽  
Wenfang Feng ◽  
...  
Keyword(s):  
Lithium Salt ◽  
Cycling Stability ◽  
Lithium Metal ◽  
Metal Anode ◽  
Lithium Metal Anode

scholarly journals Stretchable Lithium Metal Anode with Improved Mechanical and Electrochemical Cycling Stability

Joule ◽  
2018 ◽  
Vol 2 (9) ◽  
pp. 1857-1865 ◽  
Author(s):  
Kai Liu ◽  
Biao Kong ◽  
Wei Liu ◽  
Yongming Sun ◽  
Min-Sang Song ◽  
...  
Keyword(s):  
Cycling Stability ◽  
Lithium Metal ◽  
Metal Anode ◽  
Lithium Metal Anode ◽  
Electrochemical Cycling

Stability of polymeric separators in lithium metal batteries in a low voltage environment

2018 ◽  
Vol 6 (12) ◽  
pp. 5006-5015 ◽  
Author(s):  
Xing Li ◽  
Jinhui Tao ◽  
Dehong Hu ◽  
Mark H. Engelhard ◽  
Wengao Zhao ◽  
...  
Keyword(s):  
Low Voltage ◽  
Coulombic Efficiency ◽  
Cycling Stability ◽  
Lithium Metal ◽  
Metal Anode ◽  
Lithium Metal Batteries ◽  
Lithium Metal Anode

Separators can largely affect the coulombic efficiency and cycling stability of lithium metal anode, especially when using the LiPF6 electrolyte.

Porous insulating matrix for lithium metal anode with long cycling stability and high power

2019 ◽  
Vol 17 ◽  
pp. 31-37 ◽  
Author(s):  
Bingqing Xu ◽  
Haowei Zhai ◽  
Xiangbiao Liao ◽  
Boyu Qie ◽  
Jyotirmoy Mandal ◽  
...  
Keyword(s):  
High Power ◽  
Cycling Stability ◽  
Lithium Metal ◽  
Metal Anode ◽  
Lithium Metal Anode

High Li+ Ionic Flux Separator Enhancing Cycling Stability of Lithium Metal Anode

2018 ◽  
Vol 6 (3) ◽  
pp. 2961-2968 ◽  
Author(s):  
Rui Jin ◽  
Lixin Fu ◽  
Hualan Zhou ◽  
Zhuyi Wang ◽  
Zhengfu Qiu ◽  
...  
Keyword(s):  
Cycling Stability ◽  
Lithium Metal ◽  
Ionic Flux ◽  
Metal Anode ◽  
Lithium Metal Anode

A Protective Layer for Lithium Metal Anode: Why and How

Small Methods ◽  
2021 ◽  
pp. 2001035
Author(s):  
Zhiyuan Han ◽  
Chen Zhang ◽  
Qiaowei Lin ◽  
Yunbo Zhang ◽  
Yaqian Deng ◽  
...  
Keyword(s):  
Protective Layer ◽  
Lithium Metal ◽  
Metal Anode ◽  
Lithium Metal Anode

scholarly journals Artificial dual solid-electrolyte interfaces based on in situ organothiol transformation in lithium sulfur battery

2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Wei Guo ◽  
Wanying Zhang ◽  
Yubing Si ◽  
Donghai Wang ◽  
Yongzhu Fu ◽  
...  
Keyword(s):  
Solid Electrolyte ◽  
Interface Reaction ◽  
Interfacial Instability ◽  
Anode Surface ◽  
Commercial Application ◽  
Lithium Metal ◽  
Metal Anode ◽  
Lithium Metal Anode ◽  
Lithium Sulfur

AbstractThe interfacial instability of the lithium-metal anode and shuttling of lithium polysulfides in lithium-sulfur (Li-S) batteries hinder the commercial application. Herein, we report a bifunctional electrolyte additive, i.e., 1,3,5-benzenetrithiol (BTT), which is used to construct solid-electrolyte interfaces (SEIs) on both electrodes from in situ organothiol transformation. BTT reacts with lithium metal to form lithium 1,3,5-benzenetrithiolate depositing on the anode surface, enabling reversible lithium deposition/stripping. BTT also reacts with sulfur to form an oligomer/polymer SEI covering the cathode surface, reducing the dissolution and shuttling of lithium polysulfides. The Li–S cell with BTT delivers a specific discharge capacity of 1,239 mAh g−1 (based on sulfur), and high cycling stability of over 300 cycles at 1C rate. A Li–S pouch cell with BTT is also evaluated to prove the concept. This study constructs an ingenious interface reaction based on bond chemistry, aiming to solve the inherent problems of Li–S batteries.

Sign in / Sign up

Export Citation Format

Share Document