Multielectron, Multistep Molecular Catalysis of Electrochemical Reactions: Benchmarking of Homogeneous Catalysts

2014 ◽  
Vol 1 (7) ◽  
pp. 1226-1236 ◽  
Author(s):  
Cyrille Costentin ◽  
Jean-Michel Savéant
Keyword(s):  
Electrochemical Reactions ◽  
Homogeneous Catalysts ◽  
Molecular Catalysis

Molecular catalysis of electrochemical reactions

2017 ◽  
Vol 2 (1) ◽  
pp. 26-31 ◽  
Author(s):  
Cyrille Costentin ◽  
Marc Robert ◽  
Jean-Michel Savéant
Keyword(s):  
Electrochemical Reactions ◽  
Molecular Catalysis

scholarly journals Multielectron, multisubstrate molecular catalysis of electrochemical reactions: Formal kinetic analysis in the total catalysis regime

2017 ◽  
Vol 114 (43) ◽  
pp. 11303-11308 ◽  
Author(s):  
Cyrille Costentin ◽  
Daniel G. Nocera ◽  
Casey N. Brodsky
Keyword(s):  
Cyclic Voltammetry ◽  
Small Molecule ◽  
Rate Constants ◽  
Electrochemical Reactions ◽  
Cyclic Voltammograms ◽  
Experimental Systems ◽  
Kinetic Information ◽  
Formal Kinetic ◽  
Molecular Catalysis

Cyclic voltammetry responses are derived for two-electron, two-step homogeneous electrocatalytic reactions in the total catalysis regime. The models developed provide a framework for extracting kinetic information from cyclic voltammograms (CVs) obtained in conditions under which the substrate or cosubstrate is consumed in a multielectron redox process, as is particularly prevalent for very active catalysts that promote energy conversion reactions. Such determination of rate constants in the total catalysis regime is a prerequisite for the rational benchmarking of molecular electrocatalysts that promote multielectron conversions of small-molecule reactants. The present analysis is illustrated with experimental systems encompassing various limiting behaviors.

Voltage-Driven Molecular Catalysis of Electrochemical Reactions

2021 ◽  
Author(s):  
Koushik Barman ◽  
Xiang Wang ◽  
Rui Jia ◽  
Gaukhar Askarova ◽  
Guoxiang Hu ◽  
...  
Keyword(s):  
Electrochemical Reactions ◽  
Molecular Catalysis
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