Esterification of succinic acid using sulfated zirconia supported on SBA‐15

2021 ◽  
Author(s):  
Federico L. Aguzín ◽  
María L. Martínez ◽  
Andrea R. Beltramone ◽  
Cristina L. Padró ◽  
Nora B. Okulik
Keyword(s):  
Succinic Acid ◽  
Sulfated Zirconia

scholarly journals Furfural Oxidation with Hydrogen Peroxide Over ZSM-5 Based Micro-Mesoporous Aluminosilicates

2021 ◽  
Author(s):  
Nataliya D. Shcherban ◽  
Roman Yu. Barakov ◽  
Sergii A. Sergiienko ◽  
Kari Eränen ◽  
Johan Wärnå ◽  
...  
Keyword(s):  
Hydrogen Peroxide ◽  
Kinetic Model ◽  
Succinic Acid ◽  
Sulfated Zirconia ◽  
Template Method ◽  
Reaction Products ◽  
Mesoporous Aluminosilicates ◽  
Dual Functional

AbstractMicro-mesoporous aluminosilicates based on ZSM-5 zeolite, obtained by a dual template method, as well as in the presence of a dual-functional template (i.e. a Gemini-type surfactant), were tested in the oxidation of furfural with hydrogen peroxide. Even substantial changes in acidity and porosity of the catalysts result in minor variations of selectivity towards the desired products. Application of the synthesized zeolite-based materials in the oxidation of furfural with hydrogen peroxide leads to formation of 2(5H)-furanone (yield up to 28.5%) and succinic acid (up to 19.5%) as the main C4 reaction products. The kinetic model developed previously to treat the results for oxidation of furfural over sulfated zirconia was able to describe the data also for micro-mesoporous aluminosilicates. Graphical Abstract

STATE OF ANTIOXIDANT AND IMMUNE SYSTEMS IN FOX AND POLAR FOX IN POSTVACCINAL PERIOD DURING ADDITION OF SUCCINIC ACID TO THEIR FOOD

2012 ◽  
pp. 106-112
Author(s):  
O.Yu. Bespyatykh ◽  
◽  
I.A. Domskii ◽  
Z.N. Bel’tyukova ◽  
A.E. Kokorina ◽  
...  
Keyword(s):  
Succinic Acid ◽  
Immune Systems

Reusability Study of Sulfated Zirconia Functionalized SBA-15 Catalyst for Biolubricant Oil Production from Oleic Acid

2019 ◽  
Vol 1 (1) ◽  
pp. 46
Author(s):  
F R Rangganita ◽  
L Hermida ◽  
A Angraeni ◽  
D Khoirunnisa
Keyword(s):  
Oleic Acid ◽  
Sulfated Zirconia ◽  
Room Temperature ◽  
Oil Production ◽  
Catalyst Reusability

Sulfated zirconia functionalized SBA-15 catalsyt (SZr-SBA-15) was prepared byreacting SBA-15 with Zirkoniumoxychloride and urea at 90oC to form ZrO2-SBA-15. Then, ZrO2-SBA-15 was reacted with H2SO4 at room temperature to produceSZr-SBA-15 catalsyt.. The catalyst was characterized in terms of adsorptiondesorption nitrogen analysis, SEM-EDX and FTIR. Based on SEM-EDX andadsorption-desorption nitrogen analysis results, it was found that Zr had beenincorporated in SBA-15. By using the SZr-SBA-15 catalyst, esterification reactionof oleic acid with TMP to produce biolubricant oil of Trimethylolpropanetrioleatachieved 85% oleic acid conversion and selectivity of 63,7%. Reusability study ofSZr-SBA-15 catalyst was carried out for 3 rounds of reaction. It was found that thecatalyst could be used up to 3 rounds without significant decrease in activityKeywords: biolubricant oil, catalyst reusability, sba-15, sulfated zirconia.

Spectral Investigation on the Growth and Characterization of NLO Crystals of Thiourea Succinic Acid Single Crystal.

2015 ◽  
Vol 2 (2) ◽  
pp. 70-73
Author(s):  
Kannan.P ◽  
Thambidurai.S ◽  
Suresh.N
Keyword(s):  
Single Crystal ◽  
Succinic Acid ◽  
Slow Evaporation Technique ◽  
Absorption Studies ◽  
Dta Analysis ◽  
Evaporation Technique ◽  
Ft Ir ◽  
Ir Spectroscopic ◽  
Thermal Stability Of

Growth of optically transparent single crystals of thiourea succinic acid (TUSA) was grown successfully from aqueous solution by slow evaporation technique. The crystal structure was elucidated using the single crystal XRD. The various functional groups and the modes of vibrations were identified by FT-IR spectroscopic analysis. The optical absorption studies indicate that the optical transparency window is quite wide making its suitable for NLO applications. Thermal stability of the crown crystal carried out by TGA-DTA analysis.

Creation of Plasmidless and Markerless Escherichia coli Succinate Producing Strain and Evaluation of its Biosynthetic Potential during Utilization of Lignocellulosic Sugars

2020 ◽  
Vol 36 (2) ◽  
pp. 3-11
Author(s):  
O.A. Zhuravliova ◽  
Т.А. Voeikova ◽  
A.Yu. Gulevich ◽  
V.G. Debabov
Keyword(s):  
Escherichia Coli ◽  
Succinic Acid ◽  
Plant Biomass ◽  
Anaerobic Fermentation ◽  
Basic Research ◽  
Acid Fermentation ◽  
Mixed Acid ◽  
Gene Coding ◽  
Lignocellulosic Sugars ◽  
Basic Research Project

The plasmidless and markerless Escherichia coli succinate producing strain SGM2.0Pyc-int has been engineered and characterized. The strain has the inactivated main mixed-acid fermentation pathways due to the deletions of ldhA,poxB, ackA,pta, and adhE genes, constitutively expresses the genes of the aceEF-lpdA operon encoding components of pyravate dehydrogenase complex, and possesses the chromosomally integrated Bacillus subtilis pycA gene coding for pyruvate carboxylase. The capacity of the strain to synthesize succinic acid in course of dual-phase aerobic-anaerobic fermentation with lignocellulosic sugars as substrates was studied. The SGM2.0Pyc-int strain synthesized succinic acid from glucose, xylose, and arabinose with a molar yields of 1.41 mol/mol, 1.18 mol/mol, and 1.18 mol/mol, respectively, during the anaerobic production stage. The constructed strain has great potential for developing efficient processes for the succinic acid production from plant biomass-derived sugars. Escherichia coli, fermentation, arabinose, glucose, xylose, succinic acid. The work was supported by a Grant from the Russian Foundation for Basic Research (Project no. 18-29-14005).

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