scholarly journals Selective Hydrogenation of Biomass‐Derived Succinic Acid: Reaction Network and Kinetics

2020 ◽  
Vol 43 (3) ◽  
pp. 484-492
Author(s):  
Carina Heisig ◽  
Jelka Diedenhoven ◽  
Christopher Jensen ◽  
Helmut Gehrke ◽  
Thomas Turek
Author(s):  
Son Dinh Le ◽  
Shun Nishimura

Selective hydrogenation of succinic acid (SA) is not an easy task especially toward γ-butyrolactone (GBL) which readily undergoes further hydrogenation. Herein, poly(N-vinyl-2-pyrrolidone)-capped CuPd catalysts have been studied for the production...


2016 ◽  
Vol 276 ◽  
pp. 55-61 ◽  
Author(s):  
Chi Zhang ◽  
Lifang Chen ◽  
Hongye Cheng ◽  
Xuedong Zhu ◽  
Zhiwen Qi

RSC Advances ◽  
2015 ◽  
Vol 5 (69) ◽  
pp. 55727-55730 ◽  
Author(s):  
Yanfen Fang ◽  
Hongwei Yang ◽  
Wei Zhou ◽  
Yue Li ◽  
David M. Johnson ◽  
...  

BiOBr-photocatalyzed degradation of glutamic acid starts from the direct oxidation of the amino-carboxyl end and leads initially to succinic acid. Both the O-atoms from O2 and H2O incorporate into this product.


1999 ◽  
Vol 5 (S2) ◽  
pp. 142-143
Author(s):  
V. Lordi ◽  
N. Yao ◽  
J. Wei

Supported Pt-metal catalysts are of immense commercial importance for hydrogenation reactions. The fine chemicals industry relies on special catalysts that selectively hydrogenate specific bonds or chemical functions on molecules. The activity, selectivity, lifetime, etc. of a supported hydrogenation catalyst is wellknown to depend strongly on the chosen support, but systematic studies of the role of the support and of support-metal interactions are lacking in the literature. The purpose of this work is to examine in detail the function of single-wall carbon nanotubes (SWNT) as support for a Pt catalyst, in the context of a selective hydrogenation reaction. The test reaction consists of the hydrogenation of the carbonyl group on 3-methyl-2- butenal, a reaction extensively studied on well-characterized Pt surfaces and also unsupported polycrystalline Pt. This reaction, which follows a parallel/consecutive reaction network (Fig. 1), represents a class of selective hydrogenation reactions of α,β-unsaturated aldehydes that are important in the fine chemicals industry for flavorings, fragrances, and some pharmaceuticals.


Catalysts ◽  
2016 ◽  
Vol 6 (7) ◽  
pp. 100 ◽  
Author(s):  
Chi Zhang ◽  
Wenrong Cao ◽  
Hongye Cheng ◽  
Lifang Chen ◽  
Zhiwen Qi

2014 ◽  
Vol 235 ◽  
pp. 127-133 ◽  
Author(s):  
Benoit Tapin ◽  
Florence Epron ◽  
Catherine Especel ◽  
Bao Khanh Ly ◽  
Catherine Pinel ◽  
...  

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