Phosphine‐oxide‐catalyzed Enantioselective Cross‐aldol Reactions of Aldehydes with Trichlorosilane as Lewis Acid Promoter

ChemCatChem ◽  
2020 ◽  
Vol 12 (19) ◽  
pp. 4780-4783
Author(s):  
Shunsuke Kotani ◽  
Takuya Hanamure ◽  
Yoshiki Mori ◽  
Makoto Nakajima
Keyword(s):  
Lewis Acid ◽  
Phosphine Oxide ◽  
Aldol Reactions

Highly Diastereoselective and Irreversible Aldol Reactions of N-Sulfonylimidates

Synthesis ◽  
2016 ◽  
Vol 48 (19) ◽  
pp. 3413-3419 ◽  
Author(s):  
Hannah Bartrum ◽  
Sébastien Carret ◽  
Jean-François Poisson
Keyword(s):  
Lewis Acid ◽  
High Yield ◽  
Aldol Reactions ◽  
Titanium Complex ◽  
Reaction Proceeds

A mild method for the aldolization of N-sulfonylimidates was developed. The reaction proceeds in excellent diastereoselectivity to provide a range of useful β-hydroxyimidates in high yield. The innate reversibility of the reaction is suppressed by the use of a titanium complex as a Lewis acid.

scholarly journals Synthesis, Resolution, and Aldol Reactions of a Planar-Chiral Lewis Acid Complex.

ChemInform ◽  
2006 ◽  
Vol 37 (12) ◽  
Author(s):  
Shih-Yuan Liu ◽  
Ivory D. Hills ◽  
Gregory C. Fu
Keyword(s):  
Lewis Acid ◽  
Aldol Reactions ◽  
Acid Complex ◽  
Chiral Lewis Acid

Chiral dendritic bis(oxazoline) copper(II) complexes as Lewis acid catalysts for enantioselective aldol reactions in aqueous media

2003 ◽  
Vol 44 (17) ◽  
pp. 3535-3538 ◽  
Author(s):  
Bai-Yuan Yang ◽  
Xiao-Min Chen ◽  
Guo-Jun Deng ◽  
Yi-Li Zhang ◽  
Qing-Hua Fan
Keyword(s):  
Lewis Acid ◽  
Aqueous Media ◽  
Aldol Reactions ◽  
Acid Catalysts ◽  
Lewis Acid Catalysts

Synthesis, Resolution, and Aldol Reactions of a Planar-Chiral Lewis Acid Complex

2005 ◽  
Vol 127 (44) ◽  
pp. 15352-15353 ◽  
Author(s):  
Shih-Yuan Liu ◽  
Ivory D. Hills ◽  
Gregory C. Fu
Keyword(s):  
Lewis Acid ◽  
Aldol Reactions ◽  
Acid Complex ◽  
Chiral Lewis Acid
Sign in / Sign up

Export Citation Format

Share Document