Design and Synthesis of Sm, Y, La and Nd‐doped CeO 2 with a broom‐like hierarchical structure: a photocatalyst with enhanced oxidation performance

ChemCatChem ◽  
2020 ◽  
Vol 12 (9) ◽  
pp. 2638-2646 ◽  
Author(s):  
Bin Xu ◽  
Hui Yang ◽  
Qitao Zhang ◽  
Saisai Yuan ◽  
An Xie ◽  
...  
Keyword(s):  
Hierarchical Structure ◽  
Design And Synthesis ◽  
Oxidation Performance ◽  
Enhanced Oxidation

MoO 2 Cocatalytic Fe(II)/Fe(III) for the Activation of Peroxymonosulfate with Enhanced Oxidation Performance

2019 ◽  
Author(s):  
Jiahui Ji ◽  
Rashed M. Aleisa ◽  
Huan Duan ◽  
Jinlong Zhang ◽  
Yadong Yin ◽  
...  
Keyword(s):  
Oxidation Performance ◽  
Enhanced Oxidation

Enhanced oxidation performance of pitch fibers formed from a heterogeneous pitch blend

Carbon ◽  
2014 ◽  
Vol 73 ◽  
pp. 325-332 ◽  
Author(s):  
Yanbo Yao ◽  
Ling Liu ◽  
Jianming Chen ◽  
Yanming Dong ◽  
Anhua Liu
Keyword(s):  
Oxidation Performance ◽  
Enhanced Oxidation

Preparation and enhanced oxidation performance of a Hf-doped single-phase Pt-modified aluminide coating

2016 ◽  
Vol 113 ◽  
pp. 17-25 ◽  
Author(s):  
Y.F. Yang ◽  
C.Y. Jiang ◽  
H.R. Yao ◽  
Z.B. Bao ◽  
S.L. Zhu ◽  
...  
Keyword(s):  
Single Phase ◽  
Aluminide Coating ◽  
Oxidation Performance ◽  
Enhanced Oxidation

Oxidation Performance of High Temperature Mo-Si-B Alloys and Coatings

2008 ◽  
Vol 595-598 ◽  
pp. 1065-1074 ◽  
Author(s):  
John H. Perepezko ◽  
F. Rioult ◽  
R. Sakidja
Keyword(s):  
High Temperature ◽  
Interface Reaction ◽  
Temperature Stability ◽  
Reaction Products ◽  
High Temperature Stability ◽  
Transient Stage ◽  
High Temperature Mechanical Properties ◽  
Oxidation Performance ◽  
Enhanced Oxidation ◽  
And Performance

Mo-Si-B alloys are attractive due to their high temperature mechanical properties and high melting temperature. The oxidation of multiphase alloys develops in two distinct stages. First, there is a transient stage that corresponds to the evaporation of the volatile MoO3 and to an initial high recession rate. The steady state stage of the oxidation begins when the slower forming borosilicate layer becomes continuous and inhibits further rapid oxidation. Then, the oxidation rate is limited by oxygen diffusion through the borosilicate layer. In order to inhibit the transient stage, a coating strategy has been developed to capitalize on the interdiffusion reactions and to employ a kinetic bias to modify interface reaction products in order to maximize the high temperature stability and performance. In order to achieve a compatible interface coating together with enhanced oxidation resistance, a pack cementation process has been adopted to synthesize metal-rich silicide and borosilicide surface layers. The analysis of the enhanced oxidation performance indicates that a strategy based upon the operating principles of interface reactions in multicomponent systems is effective for developing stable and robust coating systems.

Relationships between hierarchical structure and properties in macromolecular systems

1987 ◽  
Vol 45 ◽  
pp. 440-443
Author(s):  
E. Baer
Keyword(s):  
Uniaxial Tension ◽  
Hierarchical Structure ◽  
Inorganic Material ◽  
Hierarchical Structures ◽  
Bone Collagen ◽  
Structure And Properties ◽  
Connective Tissues ◽  
Scale Level ◽  
Fibrous Protein ◽  
Macromolecular Systems

The most advanced macromolecular materials are found in plants and animals, and certainly the connective tissues in mammals are amongst the most advanced macromolecular composites known to mankind. The efficient use of collagen, a fibrous protein, in the design of both soft and hard connective tissues is worthy of comment. Very crudely, in bone collagen serves as a highly efficient binder for the inorganic hydroxyappatite which stiffens the structure. The interactions between the organic fiber of collagen and the inorganic material seem to occur at the nano (scale) level of organization. Epitatic crystallization of the inorganic phase on the fibers has been reported to give a highly anisotropic, stress responsive, structure. Soft connective tissues also have sophisticated oriented hierarchical structures. The collagen fibers are “glued” together by a highly hydrated gel-like proteoglycan matrix. One of the simplest structures of this type is tendon which functions primarily in uniaxial tension as a reinforced elastomeric cable between muscle and bone.

Prostatic Acid Phosphatase (PAP) Differentiated Ultracytochemically from Lysosomal Acid Phosphate in the Rat with a PAP/Specific Substrate, Phosphorylcholine

1975 ◽  
Vol 33 ◽  
pp. 450-451
Author(s):  
W. Allen Shannon ◽  
José A. Serrano ◽  
Hannah L. Wasserkrug ◽  
Anna A. Serrano ◽  
Arnold M. Seligman
Keyword(s):  
Acid Phosphatase ◽  
Phosphate Buffer ◽  
Prostatic Carcinoma ◽  
Prostatic Acid Phosphatase ◽  
Chemotherapeutic Agents ◽  
Specific Substrate ◽  
Acid Phosphate ◽  
Lysosomal Acid ◽  
Design And Synthesis ◽  
New Chemotherapeutic Agents

During the design and synthesis of new chemotherapeutic agents for prostatic carcinoma based on phosphorylated agents which might be enzyme-activated to cytotoxicity, phosphorylcholine, [(CH3)3+NCH2CH2OPO3Ca]Cl-, has been indicated to be a very specific substrate for prostatic acid phosphatase (PAP). This phenomenon has led to the development of specific histochemical and ultracytochemical methods for PAP using modifications of the Gomori lead method for acid phosphatase. Comparative histochemical results in prostate and kidney of the rat have been published earlier with phosphorylcholine (PC) and β-glycerophosphate (βGP). We now report the ultracytochemical results.Minced tissues were fixed in 3% glutaraldehyde-0.1 M phosphate buffered (pH 7.4) for 1.5 hr and rinsed overnight in several changes of 0.05 M phosphate buffer (pH 7.0) containing 7.5% sucrose. Tissues were incubated 30 min to 2 hr in Gomori acid phosphatase medium (2) containing 0.1 M substrate, either PC or βGP.

Tailoring microstructures of materials through biomimetics

1993 ◽  
Vol 51 ◽  
pp. 500-501
Author(s):  
Mehmet Sarikaya ◽  
Ilhan A. Aksay
Keyword(s):  
Chemical Properties ◽  
Design And Synthesis ◽  
Structure Sensitive ◽  
Macro Scale ◽  
Methods Of Synthesis ◽  
Successive Level ◽  
Engineering Materials ◽  
Physical And Chemical ◽  
And Chemical Properties ◽  
Synthesis Of Materials

Biomimetics involves investigation of structure, function, and methods of synthesis of biological composite materials. The goal is to apply this information to the design and synthesis of materials for engineering applications.Properties of engineering materials are structure sensitive through the whole spectrum of dimensions from nanometer to macro scale. The goal in designing and processing of technological materials, therefore, is to control microstructural evolution at each of these dimensions so as to achieve predictable physical and chemical properties. Control at each successive level of dimension, however, is a major challenge as is the retention of integrity between successive levels. Engineering materials are rarely fabricated to achieve more than a few of the desired properties and the synthesis techniques usually involve high temperature or low pressure conditions that are energy inefficient and environmentally damaging.In contrast to human-made materials, organisms synthesize composites whose intricate structures are more controlled at each scale and hierarchical order.

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