scholarly journals Coke Formation during Propane Dehydrogenation over Ga−Rh Supported Catalytically Active Liquid Metal Solutions

ChemCatChem ◽  
2020 ◽  
Vol 12 (4) ◽  
pp. 1085-1094 ◽  
Author(s):  
Moritz Wolf ◽  
Narayanan Raman ◽  
Nicola Taccardi ◽  
Marco Haumann ◽  
Peter Wasserscheid
Keyword(s):  
Liquid Metal ◽  
Coke Formation ◽  
Propane Dehydrogenation ◽  
Catalytically Active ◽  
Active Liquid

scholarly journals Highly Effective Propane Dehydrogenation Using Ga–Rh Supported Catalytically Active Liquid Metal Solutions

ACS Catalysis ◽  
2019 ◽  
Vol 9 (10) ◽  
pp. 9499-9507 ◽  
Author(s):  
Narayanan Raman ◽  
Sven Maisel ◽  
Mathias Grabau ◽  
Nicola Taccardi ◽  
Jonas Debuschewitz ◽  
...  
Keyword(s):  
Liquid Metal ◽  
Propane Dehydrogenation ◽  
Highly Effective ◽  
Catalytically Active ◽  
Active Liquid

scholarly journals Capturing spatially resolved kinetic data and coking of Ga-Pt Supported Catalytically Active Liquid Metal Solutions during propane dehydrogenation in situ

2020 ◽  
Author(s):  
Moritz Wolf ◽  
Narayanan Raman ◽  
Nicola Taccardi ◽  
Raimund Horn ◽  
Marco Haumann ◽  
...  
Keyword(s):  
Heterogeneous Catalysis ◽  
Liquid Phase ◽  
Liquid Metal ◽  
Kinetic Data ◽  
Propane Dehydrogenation ◽  
Spatially Resolved ◽  
Catalytically Active ◽  
Active Liquid ◽  
Supported Liquid Phase

Supported liquid phase catalysis has great potential to unify the advantages from both, homogeneous and heterogeneous catalysis. Recently, we reported Supported Catalytically Active Liquid Metal Solutions (SCALMS) as a new...

scholarly journals GaPt Supported Catalytically Active Liquid Metal Solution Catalysis for Propane Dehydrogenation–Support Influence and Coking Studies

ACS Catalysis ◽  
2021 ◽  
pp. 13423-13433
Author(s):  
Narayanan Raman ◽  
Moritz Wolf ◽  
Martina Heller ◽  
Nina Heene-Würl ◽  
Nicola Taccardi ◽  
...  
Keyword(s):  
Liquid Metal ◽  
Propane Dehydrogenation ◽  
Metal Solution ◽  
Catalytically Active ◽  
Active Liquid ◽  
Liquid Metal Solution

Surface oxidation-induced restructuring of liquid Pd-Ga SCALMS model catalysts

2021 ◽  
Author(s):  
Haiko Wittkaemper ◽  
Sven Maisel ◽  
Michael Moritz ◽  
Mathias Grabau ◽  
Andreas Görling ◽  
...  
Keyword(s):  
Liquid Metal ◽  
Photoelectron Spectroscopy ◽  
Ambient Pressure ◽  
Surface Oxidation ◽  
Model Catalysts ◽  
Model Systems ◽  
X Ray ◽  
Catalytically Active ◽  
Active Liquid

We have examined model systems for the recently reported Pd-Ga Supported Catalytically Active Liquid Metal Solutions (SCALMS) catalysts using near-ambient pressure x-ray photoelectron spectroscopy (NAP-XPS) under oxidizing conditions. Gallium is...

scholarly journals Stable and Selective Dehydrogenation of Methylcyclohexane using Supported Catalytically Active Liquid Metal Solutions – Ga 52 Pt/SiO 2 SCALMS

ChemCatChem ◽  
2020 ◽  
Vol 12 (18) ◽  
pp. 4533-4537
Author(s):  
Oshin Sebastian ◽  
Sharanya Nair ◽  
Nicola Taccardi ◽  
Moritz Wolf ◽  
Alexander Søgaard ◽  
...  
Keyword(s):  
Liquid Metal ◽  
Catalytically Active ◽  
Active Liquid

scholarly journals Ga–Ni supported catalytically active liquid metal solutions (SCALMS) for selective ethylene oligomerization

2021 ◽  
Author(s):  
Alexander Søgaard ◽  
Ana Luíza de Oliveira ◽  
Nicola Taccardi ◽  
Marco Haumann ◽  
Peter Wasserscheid
Keyword(s):  
Liquid Metal ◽  
Precious Metal ◽  
Ethylene Oligomerization ◽  
Catalytically Active ◽  
Active Liquid

Non-precious metal supported catalytically active liquid metal solutions exhibit attractive performance in ethylene oligomerization.

scholarly journals Effect of Boron Promotion on Coke Formation during Propane Dehydrogenation over Pt/γ-Al2O3 Catalysts

ACS Catalysis ◽  
2020 ◽  
Vol 10 (9) ◽  
pp. 5208-5216 ◽  
Author(s):  
Mostafa Aly ◽  
Esteban L. Fornero ◽  
Andres R. Leon-Garzon ◽  
Vladimir V. Galvita ◽  
Mark Saeys
Keyword(s):  
Coke Formation ◽  
Propane Dehydrogenation

Coke Formation on Pt–Sn/Al2O3 Catalyst in Propane Dehydrogenation: Coke Characterization and Kinetic Study

2011 ◽  
Vol 54 (13-15) ◽  
pp. 888-896 ◽  
Author(s):  
Qing Li ◽  
Zhijun Sui ◽  
Xinggui Zhou ◽  
Yian Zhu ◽  
Jinghong Zhou ◽  
...  
Keyword(s):  
Kinetic Study ◽  
Coke Formation ◽  
Propane Dehydrogenation ◽  
Coke Characterization ◽  
Al2o3 Catalyst

scholarly journals Pt-Sn Supported on Beta Zeolite with Enhanced Activity and Stability for Propane Dehydrogenation

Catalysts ◽  
2020 ◽  
Vol 11 (1) ◽  
pp. 25
Author(s):  
Su-Un Lee ◽  
You-Jin Lee ◽  
Soo-Jin Kwon ◽  
Jeong-Rang Kim ◽  
Soon-Yong Jeong
Keyword(s):  
Catalytic Activity ◽  
Surface Area ◽  
High Surface ◽  
Coke Formation ◽  
Propane Dehydrogenation ◽  
Coke Deposition ◽  
Beta Zeolite ◽  
Lower Amount ◽  
Metal Catalyst ◽  
Beta Zeolites

With the growing global propylene demand, propane dehydrogenation (PDH) has attracted great attention for on-purpose propylene production. However, its industrial application is limited because catalysts suffer from rapid deactivation due to coke deposition and metal catalyst sintering. To enhance metal catalyst dispersion and coke resistance, Pt-based catalysts have been widely investigated with various porous supports. In particular, zeolite can benefit from large surface area and acid sites, which favors high metal dispersion and promoting catalytic activity. In this work, we investigated the PDH catalytic properties of Beta zeolites as a support for Pt-Sn based catalysts. In comparison with Pt-Sn supported over θ-Al2O3 and amorphous silica (Q6), Beta zeolite-supported Pt-Sn catalysts exhibited a different reaction trend, achieving the best propylene selectivity after a proper period of reaction time. The different PDH catalytic behavior over Beta zeolite-supported Pt-Sn catalysts has been attributed to their physicochemical properties and reaction mechanism. Although Pt-Sn catalyst supported over Beta zeolite with low acidity showed low Pt dispersion, it formed a relatively lower amount of coke on PDH reaction and maintained a high surface area and active Pt surfaces, resulting in enhanced stability for PDH reaction. This work can provide a better understanding of zeolite-supported Pt-Sn catalysts to improve PDH catalytic activity with high selectivity and low coke formation.

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