scholarly journals Impact of Al Activators on Structure and Catalytic Performance of Cr Catalysts in Homogeneous Ethylene Oligomerization – A Multitechnique in situ/operando Study

ChemCatChem ◽  
2019 ◽  
Vol 12 (4) ◽  
pp. 1025-1035 ◽  
Author(s):  
Reni Grauke ◽  
Rahel Schepper ◽  
Jabor Rabeah ◽  
Roland Schoch ◽  
Ursula Bentrup ◽  
...  
Keyword(s):  
Catalytic Performance ◽  
Ethylene Oligomerization

scholarly journals Impact of Al Activators on Structure and Catalytic Performance of Cr Catalysts in Homogeneous Ethylene Oligomerization – A Multitechnique in situ/operando Study

ChemCatChem ◽  
2020 ◽  
Vol 12 (4) ◽  
pp. 964-964
Author(s):  
Reni Grauke ◽  
Rahel Schepper ◽  
Jabor Rabeah ◽  
Roland Schoch ◽  
Ursula Bentrup ◽  
...  
Keyword(s):  
Catalytic Performance ◽  
Ethylene Oligomerization

scholarly journals Ambient base-free glycerol oxidation over bimetallic PdFe/SiO2 by in situ generated active oxygen species

2021 ◽  
Author(s):  
Ricci Underhill ◽  
Mark Douthwaite ◽  
Richard J. Lewis ◽  
Peter J. Miedziak ◽  
Robert D. Armstrong ◽  
...  
Keyword(s):  
Heterogeneous Catalysts ◽  
Bimetallic Catalyst ◽  
Electron Paramagnetic Resonance Spectroscopy ◽  
Active Oxygen Species ◽  
Catalytic Performance ◽  
Resonance Spectroscopy ◽  
Oxygen Species ◽  
Paramagnetic Resonance ◽  
Temperature Oxidation

AbstractLow temperature oxidation of alcohols over heterogeneous catalysts is exceptionally challenging, particularly under neutral conditions. Herein, we report on an efficient, base-free method to oxidise glycerol over a 0.5%Pd-0.5%Fe/SiO2 catalyst at ambient temperature in the presence of gaseous H2 and O2. The exceptional catalytic performance was attributed to the in situ formation of highly reactive surface-bound oxygenated species, which promote the dehydrogenation on the alcohol. The PdFe bimetallic catalyst was determined to be significantly more active than corresponding monometallic analogues, highlighting the important role both metals have in this oxidative transformation. Fe leaching was confirmed to occur over the course of the reaction but sequestering experiments, involving the addition of bare carbon to the reactions, confirmed that the reaction was predominantly heterogeneous in nature. Investigations with electron paramagnetic resonance spectroscopy suggested that the reactivity in the early stages was mediated by surface-bound reactive oxygen species; no homogeneous radical species were observed in solution. This theory was further evidenced by a direct H2O2 synthesis study, which confirmed that the presence of Fe in the bimetallic catalyst neither improved the synthesis of H2O2 nor promoted its decomposition over the PdFe/SiO2 catalyst.

In situ growth of ultrathin Ni–Fe LDH nanosheets for high performance oxygen evolution reaction

2017 ◽  
Vol 4 (7) ◽  
pp. 1173-1181 ◽  
Author(s):  
Haidong Yang ◽  
Sha Luo ◽  
Yun Bao ◽  
Yutong Luo ◽  
Jun Jin ◽  
...  
Keyword(s):  
Oxygen Evolution ◽  
Oxygen Evolution Reaction ◽  
High Performance ◽  
Copper Foil ◽  
Catalytic Performance ◽  
In Situ Growth ◽  
Ultrathin Nanosheet

The ultrathin Ni70Fe30LDH nanosheets were successfullyin situgrown on anodic polarized copper foil, denoted as u-Ni70Fe30LDHs/a-CF. Benefiting from the ultrathin nanosheet structure, the catalyst exhibits remarkable catalytic performance for OER in 1 M KOH solution.

scholarly journals Ultra-Small Pd(0) Nanoparticles into a Designed Semisynthetic Lipase: An Efficient and Recyclable Heterogeneous Biohybrid Catalyst for the Heck Reaction under Mild Conditions

Molecules ◽  
2018 ◽  
Vol 23 (9) ◽  
pp. 2358 ◽  
Author(s):  
David Lopez-Tejedor ◽  
Blanca de las Rivas ◽  
Jose M. Palomo
Keyword(s):  
Catalytic Activity ◽  
Protein Structure ◽  
Heck Reaction ◽  
Catalytic Performance ◽  
Reducing Agent ◽  
Chemically Modified ◽  
Mild Conditions ◽  
In Situ Formation ◽  
Geobacillus Thermocatenulatus

A novel heterogeneous enzyme-palladium (Pd) (0) nanoparticles (PdNPs) bionanohybrid has been synthesized by an efficient, green, and straightforward methodology. A designed Geobacillus thermocatenulatus lipase (GTL) variant genetically and then chemically modified by the introduction of a tailor-made cysteine-containing complementary peptide- was used as the stabilizing and reducing agent for the in situ formation of ultra-small PdNPs nanoparticles embedded on the protein structure. This bionanohybrid was an excellent catalyst in the synthesis of trans-ethyl cinnamate by Heck reaction at 65 °C. It showed the best catalytic performance in dimethylformamide (DMF) containing 10–25% of water as a solvent but was also able to catalyze the reaction in pure DMF or with a higher amount of water as co-solvent. The recyclability and stability were excellent, maintaining more than 90% of catalytic activity after five cycles of use.

Intermetallic GaPd2Nanoparticles on SiO2for Low-Pressure CO2Hydrogenation to Methanol: Catalytic Performance and In Situ Characterization

ACS Catalysis ◽  
2015 ◽  
Vol 5 (10) ◽  
pp. 5827-5836 ◽  
Author(s):  
Elisabetta M. Fiordaliso ◽  
Irek Sharafutdinov ◽  
Hudson W. P. Carvalho ◽  
Jan-D. Grunwaldt ◽  
Thomas W. Hansen ◽  
...  
Keyword(s):  
Low Pressure ◽  
Catalytic Performance ◽  
In Situ Characterization

Facile synthesis and catalytic performance of Co3O4nanosheets in situ formed on reduced graphene oxide modified Ni foam

2017 ◽  
Vol 46 (40) ◽  
pp. 13845-13853 ◽  
Author(s):  
Congying Song ◽  
Xianzhi Yin ◽  
Biaopeng Li ◽  
Ke Ye ◽  
Kai Zhu ◽  
...  
Keyword(s):  
Graphene Oxide ◽  
Hydrothermal Method ◽  
Reduced Graphene Oxide ◽  
Three Dimensional ◽  
Catalytic Performance ◽  
Ni Foam ◽  
Facile Synthesis ◽  
Reduced Graphene ◽  
Catalyst Electrode

A three-dimensional (3D) catalyst electrode of Co3O4nanosheetsin situformed on reduced graphene oxide modified Ni foam (Co3O4/rGO@Ni foam) for H2O2electroreduction is prepared by a two-step hydrothermal method.

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