Copper‐Coordinated Histidyl Bolaamphiphile Assembly as an Oxidative Catalyst: Coordination Structure and Catalytic Activity in Cyclohexane Oxidation

ChemCatChem ◽  
2019 ◽  
Vol 11 (19) ◽  
pp. 4935-4943 ◽  
Author(s):  
Changjoon Keum ◽  
Junghyun Cho ◽  
Sunggook Park ◽  
Sang‐Yup Lee
Keyword(s):  
Catalytic Activity ◽  
Cyclohexane Oxidation ◽  
Coordination Structure

scholarly journals Aroylhydrazone Cu(II) Complexes in keto Form: Structural Characterization and Catalytic Activity towards Cyclohexane Oxidation

Molecules ◽  
2016 ◽  
Vol 21 (4) ◽  
pp. 425 ◽  
Author(s):  
Manas Sutradhar ◽  
Elisabete Alegria ◽  
M. Guedes da Silva ◽  
Luísa Martins ◽  
Armando Pombeiro
Keyword(s):  
Catalytic Activity ◽  
Structural Characterization ◽  
Cyclohexane Oxidation ◽  
Keto Form

Catalytic activity and stability of a chromium containing silicate in liquid phase cyclohexane oxidation

2001 ◽  
Vol 171 (1-2) ◽  
pp. 251-257 ◽  
Author(s):  
Rosenira Serpa da Cruz ◽  
Juliana Martins de Souza e Silva ◽  
UIrich Arnold ◽  
Ulf Schuchardt
Keyword(s):  
Catalytic Activity ◽  
Liquid Phase ◽  
Cyclohexane Oxidation

α-Zirconium phosphate supported metal–salen complex: synthesis, characterization and catalytic activity for cyclohexane oxidation

2016 ◽  
Vol 24 (4) ◽  
pp. 855-866 ◽  
Author(s):  
Savita Khare ◽  
Priti Shrivastava ◽  
Rajendra Chokhare ◽  
Jagat Singh Kirar ◽  
Swati Parashar
Keyword(s):  
Catalytic Activity ◽  
Zirconium Phosphate ◽  
Cyclohexane Oxidation ◽  
Salen Complex ◽  
Metal Salen Complex ◽  
Supported Metal

Engineering Metal-Organic Framework-Based Nanozymes for Enhanced Biosensing

2021 ◽  
Vol 17 ◽  
Author(s):  
Weiqing Xu ◽  
Yu Wu ◽  
Lei Jiao ◽  
Wenling Gu ◽  
Dan Du ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
Design Strategy ◽  
Good Stability ◽  
Coordination Structure ◽  
Research Directions ◽  
Recent Advances ◽  
Metal Organic ◽  
Catalytic Mechanisms

Background: Nanozymes are a kind of emerging nanomaterials that can mimic the catalytic activity of natural enzymes with good stability. Objective: Benefited by the unique coordination structure and constitution, metal-organic frameworks (MOFs) have been widely exploited as novel nanozymes. Importantly, various MOFs engineered with fascinating functions provide great opportunities to enhance their enzyme-like activity and improve their applied performance, achieving the goal of vividly mimicking natural enzymes. Conclusion: This review summarized recent advances in the fabrication of the MOFs-based nanozymes and their applications in biosensing. First, MOFs-based nanomaterials containing pristine MOFs, functionalized MOFs, MOFs-based composites and MOFs derivatives are introduced, where the design strategy, enzyme-like activity and the catalytic mechanisms are highlighted systematically. Then, their applications in various target assays are summarized. Finally, the challenges and possible research directions for the development and application of MOFs-based nanozymes are provided.

scholarly journals Complexes of copper(ii) with 3-(ortho-substituted phenylhydrazo)pentane-2,4-diones: syntheses, properties and catalytic activity for cyclohexane oxidation

2011 ◽  
Vol 40 (12) ◽  
pp. 2822 ◽  
Author(s):  
Maximilian N. Kopylovich ◽  
Andreia C. C. Nunes ◽  
Kamran T. Mahmudov ◽  
Matti Haukka ◽  
Tatiana C. O. Mac Leod ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Cyclohexane Oxidation

Catalytic Activity of Co-HMS Modified by Organic Groups for Cyclohexane Oxidation

2008 ◽  
Vol 29 (1) ◽  
pp. 4-6 ◽  
Author(s):  
Chen CHEN ◽  
Qiaohong ZHANG ◽  
Hong MA ◽  
Jin GAO ◽  
Zhiqiang SUN ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Cyclohexane Oxidation

scholarly journals New Trendy Magnetic C-Scorpionate Iron Catalyst and Its Performance towards Cyclohexane Oxidation

Catalysts ◽  
2018 ◽  
Vol 8 (2) ◽  
pp. 69 ◽  
Author(s):  
Ana Ribeiro ◽  
Inês Matias ◽  
Elisabete Alegria ◽  
Ana Ferraria ◽  
Ana Botelho do Rego ◽  
...  
Keyword(s):  
Magnetic Field ◽  
Catalytic Activity ◽  
External Magnetic Field ◽  
Microwave Irradiation ◽  
Iron Catalyst ◽  
Cyclohexane Oxidation ◽  
Butyl Hydroperoxide ◽  
Tert Butyl Hydroperoxide ◽  
Synthetic Procedure ◽  
First Time

For the first time, a magnetic C-scorpionate catalyst was prepared from the iron(II) complex [FeCl2{κ3-HC(pz)3}] (pz = pyrazol-1-yl) and ferrite, using the sustainable mechanochemical synthetic procedure. Its catalytic activity for the cyclohexane oxidation with tert-butyl hydroperoxide (TBHP) was evaluated in different conditions, namely under microwave irradiation and under the effect of an external magnetic field. The use of such magnetic conditions significantly shifted the catalyst alcohol/ketone selectivity, thus revealing a promising, easy new protocol for tuning selectivity in important catalytic processes.

Synthesis of FeCoMnAPO-5 Molecular Sieve and Catalytic Activity in Cyclohexane Oxidation by Oxygen

2005 ◽  
Vol 99 (3-4) ◽  
pp. 231-234 ◽  
Author(s):  
Lipeng Zhou ◽  
Jie Xu ◽  
Hong Miao ◽  
Xiaoqiang Li ◽  
Feng Wang
Keyword(s):  
Catalytic Activity ◽  
Molecular Sieve ◽  
Cyclohexane Oxidation
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