General Method for Synthesis Transition‐Metal Phosphide/Nitrogen and Phosphide Doped Carbon Materials with Yolk‐Shell Structure for Oxygen Reduction Reaction

ChemCatChem ◽  
2019 ◽  
Vol 11 (6) ◽  
pp. 1722-1731 ◽  
Author(s):  
Yue Yu ◽  
Jun Ma ◽  
Changli Chen ◽  
Yuanyuan Fu ◽  
Yefei Wang ◽  
...  
Keyword(s):  
Transition Metal ◽  
Oxygen Reduction Reaction ◽  
Oxygen Reduction ◽  
Shell Structure ◽  
Carbon Materials ◽  
Reduction Reaction ◽  
Metal Phosphide ◽  
Transition Metal Phosphide ◽  
General Method

Hybrids based on transition metal phosphide (Mn2P, Co2P, Ni2P) nanoparticles and heteroatom-doped carbon nanotubes for efficient oxygen reduction reaction

RSC Advances ◽  
2015 ◽  
Vol 5 (113) ◽  
pp. 92893-92898 ◽  
Author(s):  
Kuiyong Chen ◽  
Xiaobin Huang ◽  
Chaoying Wan ◽  
Hong Liu
Keyword(s):  
Carbon Nanotubes ◽  
Transition Metal ◽  
Oxygen Reduction Reaction ◽  
Oxygen Reduction ◽  
Alkaline Solution ◽  
Reduction Reaction ◽  
Metal Phosphide ◽  
Transition Metal Phosphide

Hybrids based on transition metal phosphide (Mn2P, Co2P, Ni2P) nanoparticles and heteroatom-doped carbon nanotubes were facilely synthesized, and used as efficient oxygen reduction reaction (ORR) catalysts in alkaline solution.

Enhanced activity of selenocyanate-containing transition metal chalcogenides supported by nitrogen-doped carbon materials for the oxygen reduction reaction

2019 ◽  
Vol 9 (13) ◽  
pp. 3426-3434 ◽  
Author(s):  
Huan-Ping Jhong ◽  
Sun-Tang Chang ◽  
Hsin-Chih Huang ◽  
Kai-Chin Wang ◽  
Jyh-Fu Lee ◽  
...  
Keyword(s):  
Transition Metal ◽  
Oxygen Reduction Reaction ◽  
Oxygen Reduction ◽  
Carbon Materials ◽  
Reduction Reaction ◽  
Metal Chalcogenides ◽  
Nitrogen Doped ◽  
Transition Metal Chalcogenides ◽  
Orr Activity ◽  
Nitrogen Doped Carbon

The SeCN− containing transition metal chalcogenides supported by nitrogen-doped carbon catalyzes the ORR activity.

N and S Co-doped Ordered Mesoporous Carbon: An Efficient Electrocatalyst for Oxygen Reduction Reaction in Microbial Fuel Cells

2020 ◽  
Vol 16 (4) ◽  
pp. 625-638
Author(s):  
Leila Samiee ◽  
Sedigheh Sadegh Hassani
Keyword(s):  
Oxygen Reduction Reaction ◽  
Oxygen Reduction ◽  
Microbial Fuel Cells ◽  
Carbon Materials ◽  
Reduction Reaction ◽  
Carbon Substrate ◽  
Promising Candidate ◽  
X Ray ◽  
Carbon Framework ◽  
Co Doped

Background: Porous carbon materials are promising candidate supports for various applications. In a number of these applications, doping of the carbon framework with heteroatoms provides a facile route to readily tune the carbon properties. The oxygen reduction reaction (ORR), where the reaction can be catalyzed without precious metals is one of the common applications for the heteroatom-doped carbons. Therefore, heteroatom doped catalysts might have a promising potential as a cathode in Microbial fuel cells (MFCs). MFCs have a good potential to produce electricity from biological oxidization of wastes at the anode and chemical reduction at the cathode. To the best of our knowledge, no studies have been yet reported on utilizing Sulfur trioxide pyridine (STP) and CMK-3 for the preparation of (N and S) doped ordered porous carbon materials. The presence of highly ordered mesostructured and the synergistic effect of N and S atoms with specific structures enhance the oxygen adsorption due to improving the electrocatalytic activity. So the optimal catalyst, with significant stability and excellent tolerance of methanol crossover can be a promising candidate for even other storage and conversion devices. Methods: The physico-chemical properties of the prepared samples were determined by Small Angle X-ray Diffraction (SAXRD), N2 sorption-desorption, Transmission Electron Microscopy (TEM), Field Emission Scanning Electron Microscopy (FESEM) and X-ray Photoelectron Spectroscopy (XPS). The prepared samples were further applied for oxygen reduction reaction (ORR) and the optimal cathode was tested with the Microbial Fuel Cell (MFC) system. Furthermore, according to structural analysis, The HRTEM, and SAXRD results confirmed the formation of well-ordered hexagonal (p6mm) arrays of mesopores in the direction of (100). The EDS and XPS approved that N and S were successfully doped into the CMK-3 carbon framework. Results: Among all the studied CMK-3 based catalysts, the catalyst prepared by STP precursor and pyrolysis at 900°C exhibited the highest ORR activity with the onset potential of 1.02 V vs. RHE and 4 electron transfer number per oxygen molecule in 0.1 M KOH. The high catalyst durability and fuel-crossover tolerance led to stable performance of the optimal cathode after 5000 s operation, while the Pt/C cathode-based was considerably degraded. Finally, the MFC system with the optimal cathode displayed 43.9 mW·m-2 peak power density showing even reasonable performance in comparison to a Pt/C 20 wt.%.cathode. Conclusions: The results revealed that the synergistic effect of nitrogen and sulfur co-doped on the carbon substrate structure leads to improvement in catalytic activity. Also, it was clearly observed that the porous structure and order level of the carbon substrate could considerably change the ORR performance.

scholarly journals Probing the activity of transition metal M and heteroatom N4 co-doped in vacancy fullerene (M–N4–C64, M = Fe, Co, and Ni) towards the oxygen reduction reaction by density functional theory

RSC Advances ◽  
2021 ◽  
Vol 11 (5) ◽  
pp. 3174-3182
Author(s):  
Siwei Yang ◽  
Chaoyu Zhao ◽  
Ruxin Qu ◽  
Yaxuan Cheng ◽  
Huiling Liu ◽  
...  
Keyword(s):  
Density Functional Theory ◽  
Transition Metal ◽  
Oxygen Reduction Reaction ◽  
Oxygen Reduction ◽  
Density Functional ◽  
Reduction Reaction ◽  
Functional Theory ◽  
Co Doped

In this study, a novel type oxygen reduction reaction (ORR) electrocatalyst is explored using density functional theory (DFT); the catalyst consists of transition metal M and heteroatom N4 co-doped in vacancy fullerene (M–N4–C64, M = Fe, Co, and Ni).

scholarly journals Highly efficient electrocatalysts with CoO/CoFe2O4 composites embedded within N-doped porous carbon materials prepared by hard-template method for oxygen reduction reaction

RSC Advances ◽  
2017 ◽  
Vol 7 (89) ◽  
pp. 56375-56381 ◽  
Author(s):  
Xinxin Jin ◽  
Yu Jiang ◽  
Qi Hu ◽  
Shaohua Zhang ◽  
Qike Jiang ◽  
...  
Keyword(s):  
Oxygen Reduction Reaction ◽  
Oxygen Reduction ◽  
Alkaline Solution ◽  
Porous Carbon ◽  
Carbon Materials ◽  
Low Cost ◽  
Reduction Reaction ◽  
Template Method ◽  
Hard Template ◽  
Hard Template Method

Low-cost dual transition metal (Fe and Co) based non-noble metal electrocatalysts (NNMEs) with large surface area and porous structure boost oxygen reduction reaction (ORR) performance in alkaline solution.

Oxygen reduction reaction on Pd nanoparticles supported on novel mesoporous carbon materials

2021 ◽  
pp. 139132
Author(s):  
Madis Lüsi ◽  
Heiki Erikson ◽  
Kaido Tammeveski ◽  
Alexey Treshchalov ◽  
Arvo Kikas ◽  
...  
Keyword(s):  
Oxygen Reduction Reaction ◽  
Oxygen Reduction ◽  
Mesoporous Carbon ◽  
Carbon Materials ◽  
Pd Nanoparticles ◽  
Reduction Reaction ◽  
Mesoporous Carbon Materials

Nanostructured tubular carbon materials doped with cobalt as electrocatalyst for efficient oxygen reduction reaction

2021 ◽  
Vol 56 (13) ◽  
pp. 8143-8158
Author(s):  
Zhaoqi Zhu ◽  
Jingxin Han ◽  
Jie Cui ◽  
Peilei Zhou ◽  
Zifeng Yang ◽  
...  
Keyword(s):  
Oxygen Reduction Reaction ◽  
Oxygen Reduction ◽  
Carbon Materials ◽  
Reduction Reaction

Metal-free ovalbumin-derived N-S-co-doped nanoporous carbon materials as efficient electrocatalysts for oxygen reduction reaction

2019 ◽  
Vol 467-468 ◽  
pp. 75-83 ◽  
Author(s):  
André L. Cazetta ◽  
Lucas Spessato ◽  
Karen C. Bedin ◽  
Isis P.F.A. Souza ◽  
Rafael A. Araújo ◽  
...  
Keyword(s):  
Oxygen Reduction Reaction ◽  
Oxygen Reduction ◽  
Carbon Materials ◽  
Nanoporous Carbon ◽  
Reduction Reaction ◽  
Metal Free ◽  
Nanoporous Carbon Materials ◽  
Co Doped
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